Sulfide dissolved in wastewater is a potential source of hydrogen sulfide. Hydrogen sulfide is an odorous substance that causes civil complaints and is a dangerous substance that threatens the corrosion of structures and the safety and health of workers. The removal efficiencies of the chemical oxidant and the coagulants were compared to evaluate the removal of dissolved sulfide. Since the effectiveness may vary depending on the characteristics of the wastewater, water was used as a control, and 5 mg/L of dissolved sulfide was dissolved in water and sewage wastewater. When oxidant was used, the results showed a high sulfide removal rate in sewage wastewater than water, and the removal efficiency was enhanced with increasing oxidant concentration. Sulfide removal efficiencies after one hour after injecting oxidants H2O2, NaOCl, NaClO2 to sewage wastewater were 70%, 90%, and 100%, respectively. After the oxidants were administered four times, the removal was 90%, 100%, and 100%, respectively. In the case of sulfide removal with the oxidizing agent, the removal efficiency was NaClO2, NaOCl, H2O2 (highest - lowest). NaClO2 showed 100% removal efficiency within 10 minutes under all conditions (A condition, B condition), making it the most sewage effective agent in this study. In the case of the coagulants, 100% of the sulfides dissolved in water were removed in the first 10 minutes under all conditions. In sewage wastewater, FeCl2 and FeSO4 also showed 100% removal efficiency under all conditions after one hour, and FeCl3 showed 90% and 99% removal rates under A and B conditions, respectively. That is, the monovalent iron coagulants (FeCl2, FeSO4) were found to be somewhat more effective in the removal of sulfides in sewage wastewater than the divalent iron (FeCl3) coagulants. When the sulfides were removed with coagulants, FeCl2 had the highest removal efficiency followed by FeSO4 and FeCl3. Moreover, it was found that NaClO2 has the best reaction efficiency at the minimum reaction time and the reaction concentration.

The purpose of this study is to examine how cohesion features can be used to distinguish between essays written by Korean and NS college students. A total of 800 essays from the ICNALE (International Corpus Network of Asian Learners of English) corpus were analyzed using the newly-developed automated analysis of cohesion program, TAACO (the Tool for the Automatic Analysis of Cohesion). In order to examine whether there are statistically significant differences between NS and Korean students, a multivariate analysis of variance (MANOVA) was conducted. The multivariate test result showed that the combined cohesion indices were significantly affected by L1, indicating that Korean and NS students differed in terms of various cohesion indices. A stepwise discriminant function analysis was also carried out to characterize the nature of cohesion differences in essays between NS and Korean students. The best two predictors for distinguishing between Korean students’ essays and NS students’ essays are the overlap of function words and the use of demonstratives. Overall, NS students produced a more cohesive writing than Korean students in that they employed overlapping words, demonstratives, and lexical subordinators as a way to connect ideas across sentences. Implications of this study for English writing pedagogy are discussed.

본 연구에서는 시판되고 있는 혈청 내 AChE가 acetylthiocholine과 반응하여 GNP에 aggregation 일으키는 원리를 이용하여 신선채소 농산물 중에 저농도 농약을 신속하고 간편하게 분석할 수 있는 비색-신속 농약 검출법을 개발하는 연구를 수행하였다. 먼저 비색-신속 농약 검출법의 최적화를 위해 GNP 입자의 크기에 따른 응집정도 를 확인하여 15~20 nm 직경의 GNP를 선정하였고, 혈청의 희석배수와 acetylthiocholine의 농도를 확인하여 GNP 응집 차이가 가장 큰 혈청 1000배 희석과 acetylthiocholine 1 mM을 최적화 조건으로 선정하였다. 비색-신속 농약 검출법의 평가를 위해 최적화된 비색농약분석법을 이용하여 유기인계 농약은 dimethyl amine으로 카바메이트계 농약은 carbofuran으로 민감도를 분석한 결과 모두 7.5 ng/mL 까지 검출이 가능한 것으로 확인되었으며 이는 기존의 비색-신속 농약 검출법과 비교했을 때 높은 민감도와 특이성을 나타내었다. 농약 이외에 화학물질인 곰팡이독소 등에 대한 반응성은 확인되지 않아 높은 특이성을 나타내었 다. 또한 상추, 깻잎, 양상추에 대한 시료 전처리법을 확 립하고 임의로 오염시킨 3종(상추, 깻잎, 양상추)의 농산물에 대해서 회수율을 확인한 결과유기인계와 카바메이트계 농약을 83.85~133.16% 정도의 회수율이 확인되었다. 이상의 결과 볼 때 본 연구에서 개발한 비색-신속 농약 검 출법을 이용한다면 시판 농산물의 잔류농약을 신속하고 민감도 높게 검출할 수 있을 것으로 판단된다.

이 연구는 핸드볼선수가 지각한 지도자의 변혁적 리더십과 집단응집력 및 인지된 경기력의 관계를 실증적으로 구명하는데 목적이 있었다. 연구목적을 달성하기 위해 대한체육회에 등록된 핸드볼선수 291명을 대상으로 설문조사를 하였으며 자료 분석은 IBM SPSS Statistics 21 프로그램을 이용하였다. 분석과정은 연구대상의 인구통계학적 특성을 분석하기 위한 빈도분석 조사도구의 구인타당도와 내적 일관성을 검증하기 위한 탐색적 요인분석과 신뢰도 분석 연구변인들의 관계를 검증하기 위한 상관관계분석과 표준중다회귀분석을 실시하였다. 이상의 자료 분석을 토대로 도출된 결과는 다음과 같다. 첫째 핸드볼선수가 지각한 지도자의 변혁적 리더십은 집단응집력에 유의한 영향을 미친다. 둘째 핸드볼선수가 지각한 지도자의 변혁적 리더십은 인지된 경기력에 유의한 영향을 미친다. 셋째 핸드볼선수의 집단응집력은 인지된 경기력에 영향을 미친다.

Large amounts of oily wastewater discharged from various industrial operations (petroleum refining, machinery industries and chemical industries) cause serious pollution in the aquatic environment. Although dissolved air flotation (DAF) separating oil pollutants using microbubbles represents current practice, bubble size cannot be selectively controlled, and lots of power is required to generate microbubbles. Therefore, to investigate performance of the DAF process, this study examined the distribution of different sizes of microbubbles resulting from changes in physical shear force via modifying shapes of a slit-nozzle without an additional power supply. Three types of slit-nozzles (different angle, shape and length of the slit-nozzle) were used to analyze the distribution of bubble size. At a slit angle of 60°, shear force was 4.29 times higher than a conventional slit, and particle size distribution (PSD) in the range between 2 and 20 μm more than doubled. Treatment efficiency of synthetic oily wastewater through the coagulation-DAF process achieved 90% removal of COD by injecting FeCl3 and PACl of 250 mg/L and 100 mg/L, respectively, and the same performance resulted using FeCl3 of 200 mg/L and PACl of 80 mg/L employing a slit-nozzle angle of 60°. This study shows that a coagulation-DAF process using a modified slit-nozzle can improve the pre-treatment of oily wastewater.

본 연구에서는 굴곡 계면을 따른 균열 진전을 응집 요소를 사용하여 유한요소 해석을 수행하였고 균열 선단에서 복합 모 드 하중을 고려하기 위하여 BK 법칙을 적용하였다. 정현파 굴곡 계면을 갖는 이중 외팔보에 하중을 부여하고 복합 모드 응 집 법칙에서 응집 강도와 응집 에너지에 따른 하중-변위 선도의 변화를 알아 보았다. 응집 강도가 커지면 응집 영역 크기가 상대적으로 작아지고 균열 진전에 따른 하중-변위 선도에 굴곡이 나타나는 것을 보여 주었으며 인장과 전단 응집에너지 비율에 따라 하중의 증가와 하중-변위 선도에 굴곡이 나타나는 것을 보여 주었다. 또한 굴곡 계면의 형상에 따른 균열 진전 거동의 영향을 분석하였는데 균열의 형상비가 커지면 균열 진전을 위한 더 큰 균열 분리 에너지가 요구되는 것을 보여 주었다. 굴곡 계면의 형상과 응집 법칙을 변화시켜 파괴 인성을 크게 향상시킬 수 있으며 균열 진전 거동을 변화시킬 수 있게 된다.

2012년부터 강화된 총인의 농도를 준수하기 위해서는 응집에 의한 물리화학적 처리가 필수적인 후단공정이 되었으며, 현재 국내 하수처리시설 중 약 60%의 처리시설에서 총인처리시설이 설치되었다. 하지만 총인처리시설 운전에 따른 응집제 사용량이 증가하게 되었고, 이에 따라 약품 비용 및 슬러지 처리비 증가 등의 운영비가 상승하였다. 특히 분리막 공법(MBR)의 경우 막 투과수의 응집액 부족으로 인한 응집효율 저하 및 응집제의 과다 주입으로 인한 처리수질 악화 등의 문제가 발생하는 경우도 있다. 본 연구에서는 MBR 공법내에서 별도의 총인처리시설 필요 없이 생물학적 인제거를 극대화 하는 동시에 응집제 사용량을 최소화하면서 처리수의 인농도를 0.2 mg/L 이하로 유지할 수 있는 방안을 도출하고자 하였다.

This study aimed to investigate the feasibility of improving dewaterability and settleability of sewage sludge using coagulation sludge. When mixed with sewage sludge and coagulation sludge at 1:1 ratio, capillary suction time(CST) and specific resistance to filtration(SRF) decreased by about 56% and 68%, respectively. It is found that total solids(TS) and volatile solids(VS) of mixing sludge are increased by about 59% and 53%, respectively. Also, the turbidity of the mixing sludge supernatant was reduced from 99 to 16 NTU. It is observed that the mixing of sewage sludge and coagulation sludge at 1:1 showed better effect than using poly-aluminum chloride(PAC) coagulant at 25 mg/L.

원전사고 및 시설보수 과정에서 방출되는 방사성물질 중 137Cs은 토양의 주 오염원 중 하나이다. 세슘으로 인한 토양오염은 주민의 거주 및 공업용지로의 재사용을 위해 제염이 불가피하다. 본 연구에서는 다양한 토양복원 기술 중 국내·외에서 실 제 방사성물질로 오염된 토양에 적용한 사례가 있는 토양세척 기술을 선정하였다. 토양세척 공정은 세척제를 사용하여 토양 과 세슘의 표면장력을 약화시켜 토양과 세슘을 분리하는 원리이다. 이러한 토양세척 공정의 세척수 재사용을 통해 공정효율 을 높이고자 세척수에 응집제를 적용하여 미세토양 및 세슘의 제거 성능 실험을 수행하였다. ICP-OES를 통해 세슘 수용액 에 토양을 첨가하여 세슘을 흡착시킨 후 응집제를 첨가하여 세슘의 농도를 측정하였으며 응집제 적용시 최대 세슘 제거율은 약 88%, 최소는 67%였다. Visual MINTEQ Code를 통한 세슘과 토양과의 종결합을 예측하였으며 탁도 측정을 통해 응집제 투여 후 탁도를 측정하여 세척수의 재사용 여부 및 미세토양 제거율을 분석하였다.

This study investigated phosphorus removal from secondary treated effluent using coagulation-membrane separation hybrid treatment to satisfy strict regulation in wastewater treatment. The membrane separation process was used to remove suspended phosphorus particles after coagulation/settlement. Membrane separation with 0.2 μm pore size of micro filtration membrane could reduce phosphorus concentration to 0.02 mg P/L after coagulation with 1 mg Al/L dose of polyaluminum chloride (PACl). Regardless of coagulant, the residual concentration of phosphorus decreased as the dose increased from 1.5 to 3.5 mg Al/L, while the target concentration of 0.05 mg P/L or less was achieved at 2.5 mg Al/L for the aluminum sulfate (Alum) and 3.5 mg Al/L for PACl. Moreover, alum showed better membrane flux as make bigger particles than PACl. Alum showed a 40% of flux decrease at 2.5 mg Al/L dose, while PACl indicated a 50% decrease of membrane flux even with a higher dose of 3.5 mg Al/L. Thus, alum was more effective coagulant than PACl considering phosphorus removal and membrane flux as well as its dose. Consequently, the coagulation-membrane separation hybrid treatment could be mitigate regulation on phosphorus removal as unsettleable phosphorus particles were effectively removed by membrane after coagulation.

In this study, it is estimated that ceramic membrane process which can operate stably in harsh conditions replacing existing organic membrane connected with coagulation, sedimentation etc. . Jar-test was conducted by using artificial raw water containing kaolin and humic acid. It was observed that coagulant (A-PAC, 10.6%) 4mg/l is the optimal dose. As a results of evaluation of membrane single filtration process (A), coagulation-membrane filtration process (B) and coagulation-sedimentation-membrane filtration process (C), TMP variation is stable regardless of in Flux 2 m3/m2･day. But in Flux 5 m3/m2･day, it show change of 1-89.3 kpa by process. TMP of process (B) and (C) is increased 11.8, 0.6 kpa each. But, the (A) showed the greatest change of TMP. When evaluate (A) and (C) in Flux 10 m3/m2･day, TMP of (A) stopped operation being exceeded 120 kpa in 20 minutes. On the other hand, TMP of (C) is increased only 3 kpa in 120 minutes. Through this, membrane filtration process can be operated stably by using the linkage between the pretreatment process and the ceramic membrane filtration process. Turbidity of treated water remained under 0.1 NTU regardless of flux condition and DOC and UV254 showed a removal rate of 65-85%, 95% more each at process connected with pretreatment. Physical cleaning was carried out using water and air of 500kpa to show the recovery of pollutants formed on membrane surface by filtration. In (A) process, TMP has increased rapidly and decreased the recovery by physical cleaning as the flux rises. This means that contamination on membrane surface is irreversible fouling difficult to recover by using physical cleaning. Process (B) and (C) are observed high recovery rate of 60% more in high flux and especially recovery rate of process (B) is the highest at 95.8%. This can be judged that the coagulation flocs in the raw water formed cake layer with irreversible fouling and are favorable to physical cleaning. As a result of estimation, observe that ceramic membrane filtration connected with pretreatment improves efficiency of filtration and recovery rate of physical cleaning. And ceramic membrane which is possible to operate in the higher flux than organic membrane can be reduce the area of water purification facilities and secure a stable quantity of water by connecting the ceramic membrane with pretreatment process.

With the concerns of global climate change, the significant changes in rainfall patterns have aggravated the occurrence of pollutants from agricultural uplands. Heavy and intensive rainfalls have rinsed a variety of pollutants off the land, sending them into the neighboring water environments which further causes water pollution problems. Recently, the application of PAM(Polyacrylamide) in agricultural lands has gotten much attention for soil conditioning. Therefore, this study aimed to develop the automatic control system applying the chemical flocculant, liquid PAM in order to flocculate the suspended solids and deposit at the bottom of farmland water channel, so eventually minimize the amount of non-point pollutants discharged into receiving water. The optimum feed rate for liquid PAM was calculated through the experiment in artificial water channel and applied to the control system. As the results of the performance test of the automatic turbid water control system installed in the sloped field, the range of turbidity reduction rate was 25 to 33% with the average turbidity of 292 to 498 NTU in water channel.

The fruiting bodies of Sanghwang mushrooms, Phellinus linteus HN1009K (PLH) and Phellinus linteus (Korea Sanghwang, PLK), and Phellinus baumii (Jangsu Sangwhang, PB), were extracted with 70% methanol. The methanolic extracts of different concentrations (5–200 μg/ml) showed inhibitory effects of 20–95% on plated aggregation induced by collagen (2.5 ug/ml), ADP (10 uM), and thrombin (0.1 U/ml). The PLH, PLK, and PB extracts (200 ug/ml) reduced ATP release from ADP-activated platelets by 50¬60%. These results suggest that the methanolic extracts from Sanghwang mushrooms inhibit platelet aggregation.

Recently EC-MBR (Elctrocoagulation - Membrane Bio Reactor) has been suggested as one of alternative processes to overcome membrane fouling problems. Most important operational parameters in the EC-MBR are known to current density and contact time. Their effect on membrane filtration performances has been reported well, however, quantitative interrelationship between both parameters not been investigated yet. The purpose of this study is to give a kinetic model suggesting the current density and the contact time required to reduce the membrane fouling. The 4 different set of current densities (2.5, 6, 12 and 24 A/m2) and contact times (0, 2, 6 and 12 hr) were selected as operational parameters. After each electro-coagulation under the 16 different conditions, a series of membrane filtration was carried out. The membrane fouling decreased as the current density and contact time increased, Total fouling resistances under different conditions, Rt(=Rc+Rf) were calculated and compared to those of the controls (R0), which were calculated from the data of experiments without electro-coagulation. A kinetic approach for the fouling reduction rate (Rt / R0) was carried out and the equation ρi0.46t=7.0 was obtained, which means that the product of current density and the contact time needed to reduce the fouling in certain amounts (in this study, 10% of fouling reduction) is always constant.

현 국제해사기구(IMO)에서의 선박엔진에서 발생되는 NOx와 SOx 등의 연소 가스 배출에 대한 규제 강화에 따라, 발트 해 연안을 지나는 모든 선박들은 배출되는 연소가스 저감장치를 장착해야 된다. 국내에서도 IMO의 규제에 따른 NOx와 SOx를 저감장치를 개발하고 있으며, 그중에 대표적인 장 치인 Scrubber는 세정액으로 암모니아수와 요소수를 사용하게 되고 사용된 폐 세정액에는 NOx와 SOx 와 반응한 질산암모늄과 황산암모늄이 포함되어 있다. 본 연구에서는 폐 세정액이 포함하고 있는 유용한 부산물을 유기용매를 사용하는 염석법을 적용하여 회수하였다. 질산암모늄과 황산암모늄의 회수방법과 질안석회를 추출 후 회수된 부산물의 정성분석을 위하여, FT-IR 분석을 통하여 물질의 정성적 특성과 화학적 조성을 평가해 보았다. 한편 응집제를 투입하여 질안석회를 침전시켜 비료상의 물질로 회수하였 다. FeSO4 응집제와 CaCl2를 응집보조제로 사용하고 입자의 크기를 키우기 위해 CaCO3를 사용하였다.

목적: 비침습적 혈당 분석은 환자의 편의와 감염에 대한 안전성을 위하여 요구된다. 본 연구에서는 금 나노입자의 합성과 응집반응을 활용하여 누액 내 글루코오스의 농도를 정량적으로 분석하고, 이를 종이 미세유체 장치에서 구현하고자 하였다. 방법: 종이 미세유체 장치는 얇은 필터 종이 위에 3mm 직경의 친수성 영역을 형성하는 왁스패턴을 인쇄하여 제작되었다. 완성된 종이 미세유체 장치 위에 염화금 용액 4μl과 누액의 생리적 농도의 글루코오스 용액 5μl를 차례로 떨어뜨려 건조시켰다. 글루코오스 용액이 건조 되면, 개시제(Sodium hydroxide, 60mM)와 발색강화제(Sodium chloride, 100mM)가 포함된 용액 5μl을 떨어뜨려 테스트 영역을 발색시켰다. 테스트 영역의 색상 값은 붉은 색과 노란색의 비율로 환산하여 분석하였다. 결과: 테스트 영역은 글루코오스 농도가 증가함에 따라서 옅은 노란색에서 분홍색으로 변하였다. 또한 농도가 증가함에 따라, 비색분석의 R/Y 비율 값은 선형으로 증가하였다. 이는 글루코오스에 의하여 금 이온이 금 나노입자로 환원됨을 의미한다. 글루코오스의 각 농도에 대한 SEM 이미지를 보면, 글루코오스 농도가 증가함에 따라 종이 표면에 더 많은 금 나노 입자가 흡착된 것을 볼 수 있다. 흡착된 금 나노입자는 20–50nm 직경의 붉은색을 띄는 형태로 형성되었다. 카오트로픽 이온의 첨가는 금 나노입자의 응집을 촉진하여, 보다 진한 발 색양상을 나타내었다. 카오트로픽 이온이 적용된 글루코오스의 분석은 높은 신뢰도 (R² >0.95)를 나타내었다. 결론: 본 연구는 글루코오스와 이온성 요인들에 의해서 금 나노입자가 합성, 응집되는 원리를 이용하여 누액 내에 존재하는 글루코오스의 양을 판정하였다. 이 글루코오스 정량 검출 방법은 기존의 검출 기법과는 다른 새로운 검출 전략으로, 현재 바이오센서 분야에서 각광 받고 있는 금속 나노입자가 활용되었다. 또한 적은 양의 체액을 대상으로 하기 때문에 경제 적인 비색분석으로 활용될 수 있다.

Microfiltration (MF) and Ultrafiltration (UF) membrane processes capable of producing highly purified water have been extensively applied as a pretreatment process in the wastewater reuse field with the improvement of membrane properties and resistance, development of operating protocols, and improvement of technologies of backwashing and physicochemical cleaning, and improvement of scale and antifoulants. However, despite of the development of membrane production and process technologies, fouling still remains unresolved. This study confirmed that foulants such as polysaccharides, proteins and humic substances existed in final treated effluent (secondary effluent) by fluorescence excitation emission matrix (FEEM) and fourier transform infrared spectroscopy (FTIR) analysis. In addition, when constructing ozone oxidation and coagulation processes as a hybrid process, the removal efficiency was 5.8%, 6.9%, 5.9%, and 28.2% higher than that of the single process using coagulation in turbidity, color, dissolved organic carbon (DOC), and UV254, respectively. The reversible and irreversible resistances in applying the hybrid process consisting of ozone oxidation and coagulation processes were lower than those in applying ozone oxidation and coagulation processes separately in UF membrane process. Therefore, it is considered possible to apply ozonation/coagulation as a pretreatment process for stable wastewater reuse by and then contributing to the reduction of fouling when calculating the optimal conditions for ozone oxidation and coagulation and then to applying them to membrane processes.