Hybrid nanocomposites of aluminium (NHAMMCs) made from AA5052 are fabricated via stir casting route by reinforcing 12 wt% Si3N4 and 0.5 wt% of graphene for usage in aeronautical and automotive applications due to the lower density and higher strength to weight proportion. The wear characteristics of the NHAMMCs are evaluated for different axial load, rotational speed, sliding distance and sliding time based on Box-Behnken design (BBD) of response surface methodology (RSM). Orowan strengthening mechanism is identified from optical image which improves the strength of the composite. Outcomes show that with higher axial load and rotational speed, there is substantial increase in wear loss whereas with increased sliding distance and sliding time there is no considerable increase in wear loss due to the lubricating nature of the reinforced graphene particles since it has higher surface area to volume ratio. Besides, artificial intelligence approach of neuro-fuzzy (ANFIS) model is developed to predict the output responses and the results are compared with the regression model predictions. Prediction from ANFIS outplays the regression model prediction.
In this study, the elastic properties of aluminium nanocomposite representative volumetric element (RVE) reinforced with GNP have been analysed. Pure aluminium is lightweight and has low strength which is not suitable for various aerospace applications. Adding graphene to aluminium gives a highly strengthened nano-matrix. A 3D multiscale finite element (FE) representative volumetric element (RVE) has been developed to estimate the mechanical behaviour of GNP-reinforced aluminium graphene nanocomposite (AGNC). The factors influencing the behaviour of AGNC have been investigated with different weight fractions (wt%), sizes and orientations of GNP. The Young’s modulus of AGNC is enhanced by increasing the wt% of GNP and reducing the size of GNP in the aluminium matrix. The Young’s modulus of AGNC with 1% wt% has been enhanced two times and yield strength by five times than pure Al matrix. In the case of different sizes of GNP, the strength of 15-nm-diameter GNP AGNC enhanced two times and medium-sized GNP, i.e. 30 nm has shown a great combination of strength and ductility. After that different orientations have also influenced the mechanical properties and enhancement shown in layered orientation compared to different angles of GNP.
YAG phosphor powders were fabricated by the atmospheric plasma spraying method with the spray-dried spherical YAG precursor. The YAG precursor slurry for the spray drying process was prepared by the PVA solution chemical processing utilizing a domestic easy-sintered aluminum oxide (Al2O3) powder as a seed. The homogenous and viscous slurry resulted in dense granules, not hollow or porous particles. The synthesized phosphor powders demonstrated a stable YAG phase, and excellent fluorescence properties of approximately 115% compared with commercial YAG:Ce3+ powder. The microstructure of the phosphor powder had a perfect spherical shape and an average particle s ize of a pprox imately 30 μm. As a r esult of t he PKG t est of t he YAG p hosphor p owder, t he s ynthesized phosphor powders exhibited an outstanding luminous intensity, and a peak wavelength was observed at 531 nm.
To improve the safety of nuclear fuel, research on the advanced nuclear fuel (UO2) by adding various trace elements is being conducted. For example, the addition of metals such as Mo, Cr can improve the thermal conductivity of nuclear fuel, minimizing the diffusion of fission products. Trace metal oxide additives (SiO2, Cr2O3, Al2O3, etc.) can suppress the release of fission gases. In general, complete dissolution of the fuel sample is required for chemical analysis to determine its elemental compositions. Among widely used metal oxide additives, aluminum oxide is difficult to dissolve in nitric acid due to its excellent thermal and chemical stability. In this study, we investigated on different chemical dissolution methods by applying a microwave digestion system under various acid solutions. We confirmed the validity of the digestion method by carrying out trace element analysis using an Inductively-Coupled Plasma Atomic Emission Spectrometer (ICP-AES).
Vertically Aligned Carbon Nanotubes (VACNTs)-coated flexible aluminium (Al) foil is studied as an electrode for supercapacitor applications. VACNTs are grown on Al foil inside thermal Chemical Vapor Deposition (CVD) reactor. 20 nm thick layer of Fe is used as a catalyst while Ar, H2 and C2H2 are used as precursor gases. The effect of growth temperature on the structure of CNTs is studied by varying the temperature of CVD reactor from 550 °C to 625 °C. Better alignment of VACNTs arrays on Al foil is recorded at 600 °C growth temperature in comparison to other processing temperatures. Cyclic voltammetry results shows that VACNTs-coated Al foil has a specific capacitance of ~ 3.01 F/g at a scan rate of 50 mV/s. The direct growth of VACNT array results in better contact with Al foil and thus low ESR values observed in impedance spectroscopy analysis. This leads to a fast charge–discharge cycle as well as a very high value of power density (187.79 kW/ kg) suitable for high power applications. Moreover, wettability study shows that the fabricated VACNT electrode has a contact angle of more than 152° which signifies that it is a superhydrophobic surface and hence shows lower specific capacitance in comparison to reported values for VACNT array. Therefore, it is necessary to develop suitable post-processing strategies to make VACNTs hydrophilic to realize their full potential in supercapacitor applications.
In this study, the electrochemical behavior of Sm on the binary liquid Al-Ga cathode in the LiCl-KCl molten salt system is investigated. First, the co-reduction process of Sm(III)-Al(III), Sm(III)-Ga(III), and Sm(III)-Ga(III)-Al(III) on the W electrode (inert) were studied using cyclic voltammetry (CV), square-wave voltammetry (SWV) and open circuit potential (OCP) methods, respectively. It was identified that Sm(III) can be co-reduced with Al(III) or Ga(III) to form AlzSmy or GaxSmy intermetallic compounds. Subsequently, the under-potential deposition of Sm(III) at the Al, Ga, and Al-Ga active cathode was performed to confirm the formation of Sm-based intermetallic compounds. The X-ray diffraction (XRD) and scanning electron microscopy-energy dispersive spectroscopy (SEM-EDS) analyses indicated that Ga3Sm and Ga6Sm intermetallic compounds were formed on the Mo grid electrode (inert) during the potentiostatic electrolysis in LiCl-KCl-SmCl3-AlCl3- GaCl3 melt, while only Ga6Sm intermetallic compound was generated on the Al-Ga alloy electrode during the galvanostatic electrolysis in LiCl-KCl-SmCl3 melt. The electrolysis results revealed that the interaction between Sm and Ga was predominant in the Al-Ga alloy electrode, with Al only acting as an additive to lower the melting point.
Processing and characterization of graphene (Gr)-reinforced aluminium alloy 7075 (AA7075) microcomposites and nanocomposites are reported in this work. Composites are fabricated by mechanical alloying process at wet conditions. The bulk composites are prepared by uniaxial die pressing to get higher densification and sintered in an inert atmosphere. Density of the nanocomposites is higher than the microcomposites due to the reduction of grain size by increased milling time. X-ray diffraction (XRD) analysis confirms graphene interaction with the AA7075 matrix lattice spaces. The effective distribution of graphene with aluminium alloy is further confirmed by the Transmission Electron Microscopy (TEM) analysis. The hardness of the composites proportionally increases with the graphene addition owing to grain refinement. Wear morphology is characterized using Scanning Electron Microscopy (SEM) and Atomic Force Microscopy (AFM). Microcomposites reveal abrasive and ploughing wear mechanism of material removal from the surface. Nanocomposites show adhesive wear with delamination and particle pull-out from the material surface.
There are many disadvantages to existing silencers used in power plants. Recently, high-performance silencers are required in society, so it is necessary to develop silencers accordingly. Therefore, in this study, to develop the flow silencer by taking advantage of the foamed aluminum, the property values such as loss coefficient and porosity were obtained through experiments, based on the Forchheimer's law. CFD analysis was performed by applying a porous modeling technique to foamed aluminum and the results were compared with experimental values. The error rate between the results of the experiment and the flow analysis is within about 2.79%, so the results of the experiment and the analysis agree relatively well. When the foamed aluminum was installed, the flow noise was reduced by about 5.14dB.
본 논문에서는 해양플랜트에 주로 사용되는 알루미늄 사다리의 독자 모델을 개발하기 위하여, 개량형 알루미늄 합금(6082-T6) 을 적용하고 국제 기준에 부합한 구조강도 설계를 하였다. 국제기준은 ISO, NORSOK, Austria Standard를 참고하였으며, 모든 조건이 만족할 수 있도록 하중 조합을 하였다. 설계된 모델은 유한요소법 [Finite elements method]을 근간으로 하는 해양플랜트 전용 해석프로그램인 SACS를 사용하여 구조 안전성을 검증하여 응력 및 처짐이 모두 허용기준 이내에 만족함을 확인하였다. 개발모델은 모든 허용기준을 만족하면서도 가볍고, 생산성이 향상되어 향후 많은 분야에서 사용이 될 것으로 기대해본다.
Natural gas is the most realistic fuel among eco-friendly fuels. Natural gas production is limited, and in Korea, it is supplied and utilized in the form of liquefied natural gas (LNG). In the case of LNG, the vaporization point is 163 degrees below zero, so ordinary metal cannot be used due to its brittleness. The International Maritime Organization (IMO) defines metals that can be used in the IGC Code, and is used for storage containers, transportation containers, etc. based on the metals. Welding is essential in the manufacture of large structures such as LNG storage tanks. In this study, weldability studies related to cryogenic materials were conducted. In Part I of this study, high-manganese steel and part II were studied for two types of stainless steel (STS304L, STS316L), and in Part III, aluminum (AL5083). During laser welding, the shape of the Bead on Plate (BOP) was analyzed, and a total of nine cases were analyzed using laser power and welding speed as variables. It was confirmed that the penetration and the width of the welding width were linearly proportional to the amount of heat input. Based on this study, it is possible to conduct a follow-up study to find the optimal welding conditions for butt welding and fillet welding.
In this study, a high speed Rigid Inflatable Boat(RIB) with about 10 meters length is developed. Design speed of the boat is 30 knots (15.43 m/s) using 250 hp twin engines and main material is aluminum. Resistance performance related to the free running attitude as trim and sinkage are discussed and wave patterns are observed to make clear the relationship between the performance and wave characteristics using model test and CFD analysis. The results show that not only wave patterns but also free running attitude of the boat have a strong influence on resistance performance. CFD results including free surface give good relative tendency for effective power and the attitude comparing model test results. CFD analysis used in this study can be used at initial ship design stage of high speed boat.
Spherical monosized pure aluminum (Al) particles are successfully fabricated by the pulsated orifice ejection method (POEM). The surface reaction between Al and the graphite crucible is investigated by analysing the microstructure and chemical composition of the materials. No significant chemical reaction occurs between Al and the graphite owing to the crystalline Al oxide (γ-Al2O3) layer generated in the initial state. The γ-Al2O3 layer is clearly observed in all regions between the Al particles and graphite via transmission electron microscopy and confirmed by the selected area diffraction pattern. The morphology of the γ-Al2O3 layer perfectly follows the surface morphology of the graphite crucible, which showed nanoscale roughness. This implies that molten Al could not directly contact graphite even though the surface of the crucible became rough to some extent. However, this passivation phenomenon allowed the successful fabrication of monosized pure Al particles. Therefore, POEM is a useful process at least to manufacture monosized pure Al particles.
An electroless deposition method was used to modify the surface properties of rice husk ceramic particles (RHC) by depositing nano-nickel on the surface of the RHC (Ni-RHC). The dry tribological performances of aluminum matrix composite adobes containing different contents of RHC and Ni-RHC particles have been investigated using a micro-tribometer. Results showed that the Ni–RHC particles substantially improved both the friction and wear properties of the Ni-RHC/aluminum matrix adobes. The optimal concentration was determined to be 15 wt% for both the RHC and Ni–RHC particles. The improvements in the tribological properties of aluminum adobes including the Ni-RHC were ascribed to frictioninduced peeling off of Ni coating and formation of protection layer on the wear zone, both of which led to low friction and wear volume.
An aluminum with the light weight has been used at the automotive car body. As the aluminum is applied to the automotive seat, the optimum design becomes important by investigating the mechanical properties. This study aims at suggesting the basic data for the optimum design of automotive seat frame. In this study, the mechanical properties are investigated through the simulation analysis on the entire structure of seat frame. Two study models using the real commercial vehicles are designed with CATIA program and analyzed with ANSYS program. The harsh condition during the driving state is supposed by using the analyses of natural frequencies and harmonic responses. As the real frequency ranges in this study are set by selecting the natural frequencies through modal analysis. The critical frequencies are analyzed by harmonic response on which the driver is seated. The values of maximum equivalent stresses at models 1 and 2 are shown to be 18.073MPa and 2259.2MPa respectively. The critical frequency at models 1 and 2 are also shown to be 77 Hz and 206 Hz. The maximum stress at model 1 becomes far bigger than model 2. By comparing two models, model 1 has more critical condition than model 2. At the design of automotive seat frame at the dynamic vibration condition, the material of design with the durability and safety can be secured through this study result.
본 논문에서는 교량, 선박 등에 사용하고 해양환경을 고려한 알루미늄 합금(A6082-T-6) 플레이트 거더의 물리적 관계를 살펴보고자 한다. 플레이트 거더는 제품수명주기에 이동하중, 적재하중 등 같은 패치로딩을 경험하게 된다. 이 하중을 받는 알루미늄합금 플레이트 거더의 최종강도에 대해 다수 수치모형을 적용하여 탄소성 대변형 시리즈 해석을 수행하고 회귀분석을 통해 예측식을 제안하였다. 예측식은 최종강도와 세장변수의 상관관계로 나타냈으며 세장변수가 낮을 경우(0-2.3) 약 9 % 정도 오차가 발생하며 높을 경우(2.3-4.0) 약 1-2 % 정도 오차가 발생하였다. 따라서 제안 예측식 적정성은 합리적으로 평가할 수 있는 것으로 확인되었다.