Iron oxide (Fe2O3) nanoclusters exhibit significant potential in the biomedical and pharmaceutical fields due to their strong magnetic properties, stability in solutions, and compatibility with living systems. They excel in magnetic separation processes, displaying high responsiveness to external magnetic fields. In contrast to conventional Fe2O3 nanoparticles that can aggregate in aqueous solutions due to their ferrimagnetic properties, these nanoclusters, composed of multiple nanoparticles, maintain their magnetic traits even when scaled to hundreds of nanometers. In this study, we develop a simple method using solvothermal synthesis to precisely control the size of nanoclusters. By adjusting precursor materials and reducing agents, we successfully control the particle sizes within the range of 90 to 420 nm. Our study not only enhances the understanding of nanocluster creation but also offers ways to improve their properties for applications such as magnetic separation. This is supported by our experimental results highlighting their size-dependent magnetic response in water. This study has the potential to advance both the knowledge and practical utilization of Fe2O3 nanoclusters in various applications.

본 논문은 교정보호체계 내 대상자 수 적정화 필요성과 그 방향에 대해 다룬다. 범 죄자의 실효적 재범방지를 위해서는 증거기반 정책의 수립과 집행체계의 전문성 강화 등 다양한 이슈가 논의 될 수 있다. 다만, 이러한 정책들이 성공하기 위해서는 정책의 집행대상을 명확히 하여 밀도 높은 교정교화 활동을 실시 할 필요가 있다. 이러한 관 점에서, 우리 교정보호체계가 가진 큰 문제점은 교정과 보호체계 모두 필요 이상의 많 은 범죄자들을 관리감독하고 있다는 점에 있다. 교정시설의 과밀수용현상과 보호관찰 소의 만성적 인력부족 현상은 이러한 현상의 단면을 잘 보여준다. 우리 교정보호체계 는 이러한 문제점을 시설과 인력의 확충이라는 방법을 통해서 해결하려 해왔다. 그러 나 교정보호체계가 각자의 몸집을 불려가는 망의 확장 현상은 귀중한 형사사법 자원 의 낭비를 초래할 뿐 아니라, 최근 가장 설득력 있는 교정이론 중 하나인 RNR이론에 따르면 재범률 감소에 긍정적 영향을 주지 못한다. 교정과 보호 두 기관은 지역사회안전을 해치지 않는 범위내에서 대상자의 수를 감소시킴으로써 근본적인 문제를 해결 해야 한다. 시설내 교정체계는 지금 보다 많은 수용자를 탈 시설화(decarceration) 하여야 하고, 사회내 처우체계도 재범위험성이 낮은 범죄자를 조기해방(early release) 시켜줘야 한다. 본 논문은 한국의 교정보호체계가 전체 교정보호 대상자 총량의 감소 를 통해 스마트한 교정보호체계로 거듭날 수 있도록, 실효적 정책대안과 향후 제언을 제시하였다.

본 연구에서는 후처리 기능화를 통해 아민이 함유된 ZIF-8-A를 제조하고, 이를 이산화탄소 흡착제로 적용하였다. 첨가한 3-amino-1,2,4-triazole의 함량에 따라 15, 37, 61, 그리고 74 %의 아민기를 포함한 ZIF-8-A를 제조하였으며, 다양한 분석을 통해 이들의 물성특성을 조사하였다. 그 결과, 아민 함량에 따라 ZIF-8-A의 게이트 크기 조절되고 가스 투과도 및 선택도에 영향을 미치는 것을 확인하였다. ZIF-8-A61%는 기존 ZIF-8 대비 CO2/N2 및 CO2/CH4에 대한 선택도가 3.4 및 4.7배 증가하였으며, 이는 구조내 가스 투과를 위한 게이트 사이즈의 조절 및 아민과 이산화탄소의 상호작용에 기인한 것으로 판단하였다.

본 연구에서는 막 증류법에 사용되는 PVDF 분리막을 나노입자로 개질하여 젖음 현상에 미치는 영향을 확인하였다. 나노입자를 분리막에 적용하기 위하여 널리 사용되는 dip-coating 방법의 경우, 나노입자에 의한 기공 막힘 현상과 나노입자와 표면과의 부착력이 약하다는 문제점이 있다. 이를 해결하기 위하여, plasma 전처리를 통해 분리막 표면의 기공 크기를 키워주었으며, Fenton 반응을 통해 분리막 표면에 SiO2의 성장 작용기인 OH기를 생성시켜 주었다. 이로부터 SiO2를 성장시켜 준 뒤, fluoroalkylsilanes (FAS)를 이용하여 SiO2 표면의 소수성 처리를 통해 막을 준비하였다. 상기 방법을 통해 준비된 분리막과 처리 전분리막의 젖음 정도를 막증류 법으로 비교하였다.

In this study, the porous ceramic filter was developed to be able to remove both dust and hazardous gas contained in fuel gas at high temperature. The porous ceramic filters were fabricated and used as a catalyst support. And the effects have been investigated such as the mean particle size, organic content and addition of foaming agent on the porosity, compressive strength and pressure drop of ceramic filters. With the increase of mean powder size and the organic content for the cordierite filter, the porosity was increased, but the compressive strength and pressure drop were decreased. From the results of the research, the optimum condition for the fabrication of ceramic filters could be acquired and they had the porosity of 58%, the compressive strength of 13.4 MPa and the pressure drop of 250 Pa. It was expected that this ceramic filter was able to be applied to the glass melting furnace, combustor, and dust/toxic gas removal filter.

We demonstrated size control of Au nanoparticles by heat treatment and their use as a catalyst for single-walled carbon nanotube (SWNTs) growth with narrow size distribution. We used uniformly sized Au nanoparticles from commercial Au colloid, and intentionally decreased their size through heat treatment at 800 oC under atmospheric Ar ambient. ST-cut quartz wafers were used as growth substrates to achieve parallel alignment of the SWNTs and to investigate the size relationship between Au nanoparticles and SWNTs. After the SWNTs were grown via chemical vapor deposition using methane gas, it was found that a high degree of horizontal alignment can be obtained when the particle density is low enough to produce individual SWNTs. The diameter of the Au nanoparticles gradually decreased from 3.8 to 2.9 nm, and the mean diameter of the SWNTs also changed from 1.6 to 1.2 nm for without and 60 min heat treatment, respectively. Raman results reconfirmed that the prolonged heat treatment of nanoparticles yields thinner tubes with narrower size distribution. This work demonstrated that heat treatment can be a straightforward and reliable method to control the size of catalytic nanoparticles and SWNT diameter.

ZnO nanoparticles in the size range from 5 to 15 nm were prepared by zinc-lithium-acetate system. The morphologies and structures of ZnO were characterized by TEM, XRD and FT-IR spectra. UV-visible results shows that the absorption of ZnO nanoparticles is blue shifted with decrease in particles size. Furthermore, photoluminescence spectra of the ZnO nanoparticles were also investigated. The ZnO nanoparticles have strong visible-emission intensity and their intensities depend upon size of ZnO nanoparticles.

In this study, we fabricated Nd2Fe14B hard magnetic powders with various sizes via spray drying combined with reduction-diffusion process. Spray drying is widely used to produce nearly spherical particles that are relatively homogeneous. Thus, the precursor particles were prepared by spray drying using the aqueous solution containing Nd salts, Fe salts and boric acid with the target stoichiometric composition of Nd2Fe14B. The mean particle sizes of the spray-dried powders are in the range from one to seven micrometer, which are adjusted by controlling the concentra- tions of precursor solutions. After debinding the as-prepared precursor particles, ball milling was also conducted to con- trol the particle sizes of Nd-Fe-B oxide powders. The resulting particles with different sizes were subjected to subsequent treatments including hydrogen reduction, Ca reduction and washing for CaO removal. The size effect of Nd-Fe-B oxide particles on the formation of Nd2Fe14B phase and magnetic properties was investigated.

The size and the physical properties of graphene oxide sheets were controlled by changing the oxidation temperature of graphite. Graphite oxide (GO) samples were prepared at different oxidation temperatures of 20℃, 27℃ and 35℃ using a modified Hummers' method. The carbon-to-oxygen (C/O) ratio and the average size of the GO sheets varied according to the oxidation temperature: 1.26 and 12.4 μm at 20℃, 1.24 and 10.5 μm at 27℃, and 1.18 and 8.5 μm at 35℃. This indicates that the C/O ratio and the average size of the graphene oxide sheets respectively increase as the oxidation temperature decreases. Moreover, it was observed that the surface charge and optical properties of the graphene oxide sheets could be tuned by changing the temperature. This study demonstrates the tunability of the physical properties of graphene oxide sheets and shows that the properties depend on the functional groups generated during the oxidation process.

소입경 골재노출콘크리트포장은 콘크리트 포장 시공 시 포장표면에 적정 응결지연제를 분사한 후 표면 모르타르를 제거하여 굵은 골재를 노출시킴으로서 표면조직을 형성하는 공법으로써 기존 콘크리트 포장의 소음문제를 해결할 수 있는 저소음 공법이다. 소입경 골재노출 콘크리트 포장은 강도를 크게 개선할 뿐만 아니라 소음저감 효과 및 우수한 미끄럼 저항성을 확보하여 도로이용자의 안정성을 확보할 수 있는 공법이다. 현재 국외 도로 선진국의 경우 골재노출 포장의 상용화가 이루어진 상태이지만 국내의 경우는 실용화 초기단계이기 때문에 현장적용을 위해서는 국내 여건에 맞는 합리적인 관리 기준이 필요하다. 이를 위하여 소입경 골재노출 콘크리트 포장의 최적배합 및 노출기법 연구, 굵은 골재의 선정 및 입도 설계, 환경하중 저항성 평가 등 실내시험을 수행하였으며, 소입경 골재노출 콘크리트 포장의 시공을 위한 시공 장비를 제작하였다. 따라서 본 연구에서는 시험시공을 통해 도출된 결과와 기존 실내시험에서 도출된 결과를 비교 분석하였으며, 시험시공 분석을 통하여 골재 탈리 방지, 강도 및 내구성 확보를 위한 표준배합을 제시하였다. 환경 및 시공조건이 상이한 3차례 시험시공 구간을 선정하여 시공현장여건에 유동성으로 대처할 수 있는 시공 기술 및 시공 기준을 제시하였다. 또한 장 단기 공용성 평가를 통하여 도로 포장의 기능성 측면에서 우수한 소음저감 및 미끄럼 저항성을 확보할 수 있는 노면조직의 품질관리 기준을 제시하였다.

In the present work, bismuth nanopowders with various particle size distributions were synthesized by controlling argon (Ar) gas flow rate and chamber pressure of a gas condensation (GC) apparatus. From the analyses of transmission electron microscopy (TEM) images and nitrogen gas adsorption results, it was found that as Ar gas flow rate increased, the specific surface area of bismuth increased and the average particles size decreased. On the other hand, as the chamber pressure increased, the specific surface area of bismuth decreased and the average particles size increased. The optimum gas flow rate and chamber pressure for the maximized electrochemical active surface area were determined to be 8 L/min and 50 torr, respectively. The bismuth nanopowders synthesized at the above condition exhibit 13.47 of specific surface area and 45.6 nm of average particles diameter.

To increase pot life in the formulation mixed with bisphenol F epoxy resin, anhydride-based curing agent, and imidazole-based curing accelerator powders as a paste material for high-speed RFID chip bonding, size variation of the imidazole-based powders and a coating method of the powders were adopted in this study. In experiment with regard to the size variation, the pot life was not outstandingly increased. Through the idea using the coating method, however, the pot life was increased up to 4.25 times in comparison with the addition of initial imidazole-based powders. Consequently, successive bonding of RFID chip could be performed with very short time of 5sec using the suggested formulation having improved pot life.

The amorphous alloy strip was pulverized to get a flake-shaped powder after annealing at for 90 min and subsequently ground to obtain finer flake-shaped powder by using a ball mill. The powder was mixed with polyimide-based binder of , and then the mixture was cold compacted to make a toroidal powder core. After crystallization treatment for 1 hour at , the powder was transformed from amorphous to nanocrystalline with the grain size of . Soft magnetic characteristics of the powder core was optimized at with the insulating binder of 3wt%. As a result, the powder core showed the outstanding magnetic properties in terms of core loss and permeability, which were originated from the optimization of the grain size and distribution of the insulating binder.

The W/O emulsion was formed by mixing hydrophobic nonion surfactants of span 80 and tween 60 with kerosine, and by adding sodium silicate aqueous solution. Precipitating the W/O emulsion by sodium bicarbonate resulted in spherical silica particles. Shape and size distribution of silica particles were observed. The particles were spherical and they have narrow size distribution. Particle sizes were 9.29, 7.39 and 5.73 μm at homogenizer speed of 2500, 3000, and 3500 rpm, respectively. The particle size was decreased by increasing agitation speed due to the formation of emulsion droplet. At fixed agitation speed, absorbed paraffin oil weight were measured and the SiO2/Na2O mole ratio effects on particle size were investigated. Particle size was decreased by increasing the mole ratio of SiO2/Na2O.

Nickel powders were synthesized by the hydrazine reduction of nickel chloride solution containing ammonia in DEA solutions. The size distribution of nickel powders were investigated as a function of ammonia concentration, hydrazine concentration and the mixed composition ratio of diethanolammine (DEA) and triethanolammine (TEA). Nickel powders with the size in submicron range were obtained at for 45 minutes by hydrazine reduction of nickel chloride solution in DEA solutions. The hydrazine concentrations showed significant effects on the particle size and shape distribution of nickel powders under molar ratio of 2.0 condition. As the mixed volume ratio of TEA and DEA increased, nickel powders with relatively larger particle size and low agglomeration were obtained. Nickel powders with particle size in the ranged from 0.4 to were obtained at the 50 of TEA.

PDP용 녹색 형광체의 발광특성을 개선시키기 위해 고안된 액상의 화학적 합성법을 사용하여 조성식이 Zn2-x SiO4:xMn(x=0.05, 0.08)인 형광체를 입자크기가 0.5~2μm로 조절하여 제조하였다. 제조된 형광체 입자는 구상이며 잘 분산된 형상을 봉주었고, 고상반응법에 비해 상대적으로 낮은 1080˚C에서 willemite구조의 단일상을 얻을 수 있었다. 또한 진공 자외선 영역의 147 nm의 여기원을 사용하여 광발광 특성을 조사하였다. 입자의 크기가 1μm이고 Mn의 도핑양이 8mole%일 때, 상용 형광체와 비교하여 발광세기는 약 40% 향상되었고 색좌표는 x=0.24, y=0.69로 거의 일치하는 결과를 얻을 수 있었다. 측정된 형광체의 잔광시간은 7.8ms이었다.