The objective of this study was to assess the effects of gypsum application on dry matter yield (DMY), mineral content of alfalfa (Medicago sativa L.), and soil properties in reclaimed tidal land in South Korea. The experiment was conducted in Seokmun, located on the west coast of South Korea, which is reclaimed with approximately 70 cm depth of degraded island soil. Treatments consisted of a control with no gypsum application (G0), 2 ton ha-1 (G2), and 4 ton ha-1 (G4) of gypsum application. The first harvest was carried out when the alfalfa reached 10% flowering, and subsequent harvests were conducted at 35-day intervals. Over the three-year experimental periods (2019-2021), the total DMY of G2 treatment was significantly higher than those of G0 and G4 (p<0.05). Although both G2 and G4 gypsum application treatments lowered soil pH, the G4 treatment increased the electrical conductivity (EC) content of the soil. Additionally, gypsum application affected the mineral contents of alfalfa, resulting in reduced concentration of sodium (Na) and Magnesium (Mg). Therefore, this present study suggests that a gypsum application rate of 2 ton ha-1 is optimal for improving alfalfa dry matter yield and mineral balance, as well as enhancing soil chemical properties in reclaimed tidal land in South Korea.
This study evaluated the effects of solid and water-soluble extracts derived from torrefied Pinus densiflora on lettuce (Lactuca sativa) germination and growth, as well as the cultivation efficiency of torrefied materials combined with plant nutrient solutions. Torrefied samples were prepared under various conditions (200°C, 220°C, 240°C for 20–80 minutes) and mixed with sand at ratios from 20% to 100%. Liquid extracts were formulated with macronutrients (N, P, K, Mg) and micronutrients (Mn, B, Fe, Cu) and applied to leafy and root vegetables. Germination tests showed that 60% and 80% torrefied treatments had the highest and most consistent rates, with torrefied samples promoting more rapid and stable germination than controls. A two-way ANOVA indicated a significant interaction between treatment and concentration (p = 0.043), suggesting concentration-specific effects. While shoot length showed no significant difference, root growth was marginally significant (p = 0.064), with washed torrefied material producing the longest roots. Physical analysis revealed that torrefied materials improved soil thermal retention and moisture-holding capacity. However, increasing torrefied content reduced porosity, likely due to fine particles filling soil pores. In conclusion, torrefied P. densiflora materials exhibit strong potential to enhance germination, root development, and soil condition. Optimal results were achieved with 40–60% solid mixtures for germination and 60–80% diluted extracts for rapid and consistent seedling growth. When optimally applied, they may serve as effective, sustainable amendments in cultivation systems.
In this paper, the uniaxial tensile mechanical characteristics after synchronous biaxial pre-tension analysis are investigated on a ETFE film crown model. After the biaxial pre-stretching is completed, the rectangular specimens are cut along the MD and TD directions of the biaxially pre-stretched ETFE film to conduct the uniaxial stretching test. The uniaxial tensile mechanical properties of the ETFE film after biaxial pre-stretching are investigated, the specific uniaxial tensile mechanical property parameters of the biaxially pre-stretched film are determined, and the influence of biaxial pre-stretching on the uniaxial tensile mechanical properties of the ETFE film is analyzed.
This study investigated the impact of various soil environmental factors on the growth and yield of Actinidia arguta (A. arguta) in Suwon, South Korea. By employing Pearson correlation analysis, we explored the relationships between soil properties such as pH, electrical conductivity (EC), organic matter content, available phosphorus, available silicon, soil moisture, and soil temperature with A. arguta growth and yield. The results revealed that soil temperature and EC had the strongest positive correlations with A. arguta growth, while organic matter content exhibited a strong negative correlation with fruit yield. The high levels of available phosphorus emerged as a potential adverse factor affecting yield. These findings suggest that managing soil temperature, EC, and phosphorus levels is crucial for optimizing A. arguta productivity. Future research should focus on fine-tuning phosphorus levels and further investigating the interactions between soil factors to enhance A. arguta yield and sustainability.
본 연구는 아민화 셀룰로오스 나노섬유(CNF)를 시멘트 복합체에 적용하여 기계적 및 미세구조적 성능 향상을 도모하고자 하였다. CNF는 (3-aminopropyl) triethoxysilane (APTES)를 활용해 화학적으로 개질하였으며, 이는 시멘트 수화 생성물과의 계면 결합력 및 분산성을 향상시키기 위한 목적이다. 표면 개질의 성공 여부는 주사전자현미경(SEM)과 X-선 회절 분석(XRD)을 통해 확인 하였다. 다양한 함량의 개질 및 비개질 CNF를 혼입한 모르타르를 제작하여 압축강도 및 휨강도를 평가하였다. 그 결과, 아민화 CNF는 0.2% 혼입 시 압축강도 향상 효과가 가장 두드러졌으며, 휨강도는 0.3%에서 가장 우수한 성능을 나타내었다. 미세구조 분석을 통해, 아민화 CNF가 시멘트 수화물과의 상호작용을 통해 내부 조직을 치밀하게 형성하고 공극률을 저감시키는 것으로 확인되었다. 본 연구는 화학적으로 개질된 CNF가 지속가능하고 고성능인 시멘트 복합재료 개발에 있어 유효한 기능성 첨가제로 활용될 수 있음을 시사한다.
전 세계 이산화탄소 배출량이 지속적으로 증가하면서, 환경 개선 및 탄소 격리를 위한 다양한 연구들이 진행되고 있 다. 건설 산업에서도 탄소를 줄이기 위한 연구로 바이오차를 건설 자재에 사용하여, 탄소 격리를 위한 방법으로 진행되고 있다. 바이오차는 바이오매스를 열분해하여 생성한 숯으로, 높은 탄소 함량과 다공성 구조가 특징이며, 탄소 격리를 위한 물질로 떠오 르고 있다. 본 연구에서는 시멘트 사용량을 줄이고 바이오차를 혼입한 콘크리트를 건설 자재로써 가능성을 확인하고자 하였다. 이를 위해 시멘트의 일부를 바이오차로 치환하여 혼입한 콘크리트의 역학적 특성(슬럼프, 공기량, 압축강도)과 질량 기반 특성 (흡수율, 밀도, 공극률)을 평가하였다. 바이오차의 시멘트 치환율은 0%, 5%, 10%로 설정하였다. 바이오차의 수분 흡수 및 보유 력에 따라 바이오차의 시멘트 치환율이 증가할수록 슬럼프는 감소하였다. 바이오차의 다공성 구조를 SEM 실험으로 확인하였으 며, 이에 따라 콘크리트에서의 공극 형성으로 바이오차의 시멘트 치환율이 증가할수록 공기량과 흡수율이 증가하였다. 바이오차 의 시멘트 치환율 5%에서 압축강도와 비강도가 가장 높은 값으로 나타났으며, 탄소 격리를 위한 방법으로 건설 자재 활용의 가능성을 확인하였다.
Sodium sulfate, as a commonly used early strengthening agent, has been widely used in different areas. Because of its sulfonic acid group, sodium sulfate is also used as a cement capillary crystal waterproof material. However, temperature has a significant effect on concrete mixed with sodium sulfate. The effect of sodium sulfate on the early hydration rate at different temperatures was studied by conducting a time and hydration thermal analysis. The effects of sodium sulfate on the mechanical properties of concrete at different temperatures were studied through compressive strength experiments. Impermeability at different temperatures was studied by testing resistance to chloride ion penetration and resistance to water penetration. The effect of resistance to sulfate attack was also experimentally. The hydration products were analyzed by electron microscopy (SEM) and energy dispersive spectroscopy (EDS). The experimental results showed that at low temperature, sodium sulfate can accelerate the early hydration reaction rate, and the effect becomes weaker with increasing temperature. At low temperature, the addition of sodium sulfate can effectively improve the degree of hydration, and enhance the permeability resistance and ion erosion resistance of the matrix.
Eu-doped SrAl2O4 is a promising thermoluminescent and mechanoluminescent material with high brightness and stability, making it suitable for various luminescent devices. In this study, SrAl2O4:Eu was synthesized using a solid-state reaction method, and the effects of reducing atmosphere and high-temperature synthesis conditions on its luminescence properties were systematically analyzed. The luminescence characteristics of SrAl2O4:Eu were found to be highly sensitive to synthesis temperature, atmosphere, and Eu doping concentration, and optimal conditions were determined. A comparison of SrAl2O4:Eu synthesized at 1,300 °C under air and reducing atmospheres revealed that the reducing atmosphere plays a critical role in stabilizing Eu2+ ions, forming a single-phase SrAl2O4, and establishing luminescence centers. Notably, SrAl2O4:Eu synthesized at 1,600 °C in a reducing atmosphere achieved a photoluminescence quantum yield (PLQY) of 43 % and a maximum luminance of 2,030 Cd/m2, showing significant improvement in luminescence efficiency compared to samples synthesized at 1,300 °C. When Eu doping concentrations were adjusted from 1 % to 20 %, the highest luminescence performance was observed at 10 % doping, while excessive doping (20 %) increased non-radiative recombination pathways, and no further improvement in luminescence efficiency was observed. X-ray Diffraction (XRD) and Photoluminescence (PL) analyses elucidated the effects of synthesis conditions on the structural stability and luminescence properties of SrAl2O4:Eu, and the optimal reducing atmosphere and high-temperature synthesis conditions are proposed. This study provides a synthesis strategy for enhancing the luminescence properties of Eu-doped SrAl2O4 and lays the groundwork for the development of highperformance thermoluminescent and mechanoluminescent materials.
In this paper, the changes of the uniaxial tensile mechanical properties of the ETFE film after the uniaxial pre-stretching stress exceeds the first yield stress and the second yield stress was investigated. The ETFE film is first pre-stretched uniaxially along the MD direction or TD direction. After the pre-stretching loading stress exceeds the first yield stress and the second yield stress to cause the ETFE film to undergo plastic deformation, rectangular uniaxial tensile specimens are cut from the pre-stretched film along the MD direction and the TD direction for subsequent uniaxial tensile tests, thereby determining the uniaxial tensile mechanical property parameters of the ETFE film after uniaxial pre-stretching, including yield stress, tensile strength and elongation at break, and discussing the changes in its uniaxial tensile mechanical properties.
아스팔트는 아스팔텐(Asphaltene)과 레진(Resin), 포화분(Saturates), 방향족화합물(Aromatics)로 구성되어 있고, 레 진, 포화분, 방향족화합물의 혼합물을 말텐(Malten)이라 하며, 아스팔텐이 말텐에 분산되어 있는 형태를 가진 콜로이 드 상태의 혼합물이다. 아스팔트를 조성하고 있는 조성물의 조성비, 온도 변화에 따라 결합 상태 및 내부 구조가 변 화하고, 아스팔트의 물성과 상태 등에 영향을 주어, 아스팔트 혼합물이 고온에서 소성변형(Rutting), 저온에서의 균열 (Crack)등의 파손에 영향을 미친다. 이러한 아스팔트 혼합물의 파손을 방지하기 위하여 SBS(Styrene-Butadiene- Styrene Block Copolymer)와 같은 폴리머를 혼합하여 아스팔트의 점탄성을 향상시키고, 오일류와 같은 첨가제를 활 용하여 저온에서 탄성과 유연성을 증가시킨다. 이와 같이 고온과 저온의 성능을 용도에 맞게 개선한 아스팔트를 개질 아스팔트(Polymer Modified Asphalt)라고 하며, 도로의 품질 및 내구성 향상을 위해 개질아스팔트 포장의 수요가 점 차 증가하는 추세로 아스팔트혼합물의 성능 향상을 위해 오일류를 활용한 폴리머 아스팔트의 물성 변화에 대한 연구 가 필요하다고 판단된다.