The purpose of this study was to investigate the antioxidative effect and quality characteristics of cookies made with Sea tangle powder(STP). The cookies were at 30℃ for 45 days. The 3% STP had higher pH value compared to the other groups and control. As more STP was added, the L-value and b-value decreased, and the a-value increased for the color values. The results of sensory evaluation and acceptance test showed that the cookies with 3% STP was significantly more preferable in overall acceptability than the others. The acid value, peroxide value, and thiobarbituric acid value were lower in cookies with 3% and 6% STP than in those cookies made 9% STP and the control cookies.

The present study is to analyze the thermoelectric properties of thermoelectric materials fabricated by the mechanical grinding process. The powders were prepared by the combination of mechanical milling and reduction treating methods using simply crushed pre-alloyed powder. The mechanical milling was carried out using the tumbler-ball mill and planetary ball mill. The tumbler-ball milling had an effect on the carrier mobility rather than the carrier concentration, whereas, the latter on the carrier concentration. The specific electric resistivity and Seebeck coefficient decreased with increasing the reduction-heat-treatment time. The thermal conductivity continuously increased with increasing the reduction-heat-treatment time. The figure of merit of the sintered body prepared by the mechanical grinding process showed higher value than one of the sintered body of the simply crushed powder.

It is attempted to develop flame retardant polyurethane coatings, which have received significant attention in recent years. It is the purpose of this study to synthesize new reactive polyurethane coatings containing halogen. Lactone based modified polyester polyols, using trichlorobenzoic acid as chlorine moiety (TBAOs) were synthesized. These polyesters were cured with isophorone diisocyanate (IPDI)-isocyanurate at room temperature (TBAPUs). Physical properties of these flame retardant coatings were similar with those of non-flame retardant coatings. The flammability of coatings was strongly dependent on the chlorine contents. We found that the increasing chlorine contents showed better flame retarding properties and that, however, they also resulted in more smog generation during combustion. The detailed results of flammability test using various methods indicated 24~26% in LOI and 3.7~5.3 cm char length in 45˚ Meckel burner method.

Anti-corrosive coatings for steel structures with an alternative anti-corrosive pigment, polyaniline was prepared and anti-corrosive characteristics of the prepared coatings were investigated. The structure of the polyaniline was identified by using FT-IR, UV/Vis. and TGA analysis, and the anti-corrosive properties were analyzed from the results of the salt spray experiment. We found that the anti-corrosion properties of the prepared coatings varied in accordance with the types of primer coating resins as well as with the existence and nonexistence of the top coating. In this condition, the properties of adhesion, chemical resistance, and water resistance were found to be very satisfactory when using the single-packaged urethane resin as the primer coating resin and the urethane resin as the top coating resin.

본 연구는 불소관능기인 perfluorocyclobutane (PFCB), fluorenyl, sulfonyl계 방향족 화합물을 동시에 포함하는 술폰화된 랜덤 고분자 전해질 막의 제조 및 그 특성에 관한 것이다. 이러한 고분자 전해질 막은 세단계의 합성, 즉 trifluorovinyloxy그룹을 양말단에 포함하는 단량체의 합성, 중부가반응 형태의 열중합, 그리고 chlorosulfonic acid를 이용한 후술폰화를 통하여 얻어졌다. 후술폰화 반응은 고분자 내에 포함된 fluorenyl기의 함량에 따라 일정한 몰비의 술폰화제 비율로 고정하여 진행되었으며, 이에 따라 다양한 이온교환 능력(IEC)을 가지는 고분자를 쉽게 합성할 수 있었다. 제조된 단량체 및 고분자들의 구조와 순도는 각각 FT-IR과 NMR 그리고 질량분석기를 통하여 확인되었다. 술폰화된 fluorenyl기가 많아질수록 술폰화도와 이온교환 능력이 증가하는 것을 확인할 수 있었고 그에 따른 함수율도 역시 증가하는 거동을 보였다. 술폰화된 고분자들의 이온전도도를 측정한 결과 술폰화도가 증가할수록 이온 전도도가 증가하는 것을 관찰할 수 있었다, 이렇게 제조된 전해질막 중 S-1과 S-2의 경우 다양한 온도범위(25sim80℃ 수식 이미지)에서 상용 전해질막인 Nafion-115를 능가하는 우수한 이온전도도를 나타냈다.

본 연구에서는 정밀여과 및 나노여과 분리막 시스템을 활용하여 염료 제조 시 필요한 탈염/정제/농축처리 기술을 개발하고 그에 따른 염료의 품질과 품질의 안정성을 향상시키며, 기존공정의 단수를 축소하여 생산성 향상, 인력저감 및 원재료의 비용을 감소하고자 하였다. 염료의 탈염/정제/농축처리시 염료의 다양한 농도에 적합한 분리막의 제조 및 가압식 막 element를 제작하고, 가압식 분리막 시스템에 맞는 막 모듈의 설계와 pilot-scale 시스템을 통해 염료의 처리수질 분석 및 운전인자를 도출하였다.

Y2-xGdxO3:Eu, phosphors for plasma display panel(PDP), were prepared by Pechini method which use yttriun chloride, gadolinium chloride, and europium oxide as starting materials. This method is a different way to the synthesis of europium(Eu)-doped phosphors, and it consists of the formation of a polymeric resin obtained by polyesterification between metal chelate compounds and a polyfunctional alcohol. This needs lower temperature than solid-state synthetic method. The prepared Y2-xGdxO3:Eu phosphor particles had spherical shape and coherence. The luminescence intensity of Y2-xGdxO3:Eu phosphor particles increased according to the increase of gadolinium(Gd) content(to 0.8mol%), and Y1.2Gd0.8O3:Eu phosphors had the highest luminescence intensity under vacuum ultra violet(VUV) excitation. The optimum concentration of Eu in the phosphor and optimum calcination temperature was 3wt% and 1100℃. The prepared phosphors were consist of particle, and its size was between 100nm and 150nm. Among the different polyfunctional alcohols, diethylene glycol(DEG) improved the luminescence intensities of phosphors more than other additives. The Pechini method proved that it is demonstrated to be suitable for the synthesis of phosphors used in PDP.

To provide an aqueous rust inhibitor for metalworking lubricant having low toxicity and excellent rust resistance, we synthesized diester of malonic acid by three consecutive esterifications with over 98% of conversion. This substituted malonic diester could be used as an additive to mineral oil based metalworking lubricant. These metalworking lubricant compositions were showed excellent rust resistance and suitable for various metals and different metalworking processes including hot rolling and cold rolling of aluminum and aluminum alloys.

The VOCs discharge characteristics of miscellaneous assembly metal manufacture & metal processing industries, in the SihwaㆍBanwol Industrial Complex, were analyzed according to detailed categories per industry, as based on the Korea Standard Industrial Classification, by comparing the conditions before and after the installation of process and prevention facilities. The average concentration of benzene was highest in the metal heat treatment industry (28921) whereas that of toluene was highest in the painting & membrane treatment industry (28923). In addition, with respect to prevention facilities, our evaluation proved that the decreased efficiency was worse for the discharge facilities of pollutants from the plating industry (28922) and painting & miscellaneous membrane treatment industry (28923), with some exceptions, while most facilities showed no decreased efficiency. Therefore, it is believed that an accurate survey of the conditions of administration/operation facilities will need to be conducted, and the decreased efficiency will also need to be evaluated so that adequate prevention facilities can be reviewed and selected.

  The purpose of this study is to propose guidelines for introducing the JIT(Just-In-Time) purchasing to enhance the competitiveness of Korean manufacturing companies. This study employed an extensive survey on the use of the JIT purchasing systems among

The purpose of this study is to explore the correspondence level to product Liability in the enterprises. The results of this study are to offer basic information for a planned manufacturing system for safety products. Especially important things are build up the foundation of system and abide by it for safety products. The producer and supplier(distributors) of the products should satisfy the increasing consumer safety needs. This survey show us that manufacturing the safety products is important factors for korean enterprise management. But, in the reverse, neglect to take appropriate measures promptly.

Spherical Ag powder was prepared in the system of by wet chemical reduction method. The size of Ag powder was increased as the reaction temperature and the concentration of reducing agent was decreased in the constant concentration of dispersion agent. Optimum conditions of producing Ag powder having of D50 was 1M of , 0.5M of , 1.5g of Gelatine in the room temperature.

[ ] oxide layer on the surface of each W(tungsten) nanopowder produced by the electric explosion of wire(EEW) process were formed during the 1vol.% air passivation process. The oxide layer hindered sintering densification of compacts during SPS process. The oxide phase was reduced to the pure W phase during SPS. The W nanopowder's compacts treated by the hydrogen reduction showed high sintered density of 94.5%. after SPS process at .