음이온 교환막은 수전해 시스템에서 매우 중요한 역할을 하며, 생성된 수소와 산소 기체를 물리적으로 분리할 뿐 만 아니라 전극 사이에서 수산화 이온의 선택적인 전달을 용이하게 한다. 음이온 교환막에 요구되는 특성은 수산화 이온에 대한 높은 전도도와 알칼리 환경에서의 화학적/기계적 안정성 등이 있다. 본 연구에서는 셀룰로오스 나노 크리스탈이 포함된 poly(terphenyl piperidinium) (qPTP/CNC) 복합매질분리막을 제조하였다. 고분자 매질로 사용된 poly(terphenyl piperidinium) 은 super-acid 중합법을 통해 제조되었으며 이온전도성과 알칼라인 내구성이 뛰어난 소재로 알려져 있다. qPTP/CNC 분리막 의 구조는 고분자와 나노 입자 계면의 공극이나 큰 응집체가 없는 조밀하고 균일한 형태를 나타냈다. CNC 나노 입자가 2 wt% 첨가된 qPTP/CNC 분리막은 높은 이온교환용량(1.90 mmol/g)과 낮은 함수율(9.09%) 및 팽윤도(5.56%)를 보였다. 또한, 복합막은 수전해 작동 환경인 50°C 1 M KOH에서 상용 FAA-3-50 분리막에 비해 월등히 낮은 저항과 우수한 알칼라인 내구 성(384시간)을 달성했다. 이러한 결과는 친수성 첨가제인 CNC가 음이온 교환막의 이온 전도 특성과 알칼라인 내구성 향상에 기여할 수 있음을 보고하였다.

작물의 스트레스 조기 진단은 농업에 있어 빠른 대응을 가능하게 해 피해를 경감시킬 수 있어 중요한 기술이다. 기존의 스트레스 진단이 가진 파괴적인 형식의 시료 채집과 양분 분석에 많은 노동력을 필요로 한다는 단점 극복을 위해 새로운 기술 개발이 필요하다. 미래에는 대단위 영상을 이용한 생육 진단 기술에 대한 수요가 높아질 것으로 예상되어 이를 이용한 연구를 진행하였다. 본 연구는 2023년 경상남도 밀양시에 위치한 국립식량과학원 실험 포장에서 수행되었으며, 무인항공기(UAV)를 이용하여 양분 결핍 처리(관행시비, 질소 결핍, 인 결핍, 칼륨 결핍, 무비)에 따른 벼의 생육을 조사했다. UAV를 이용해 생육 기간 중 총 6회에 걸쳐 포장을 촬영하였고, 영상을 기반으로 11개의 식생 지수를 산출하여 기계학습을 통해 양분 결핍을 진단하는 모델을 구축하여 평가했다. 연구 결과에 따르면, 엽록소 함량과 관련된 지수인 NDRE (Normalized Difference Red Edge)가 가장 높은 중요도를 나타내어 벼의 양분 상태를 효과적으로 진단하는 데 유용하다는 것을 확인하였다. 6개의 각 단계별로 모델을 평가하였을 때 모든 단계에서 accuracy가 0.7 이상으로 나타났다. 조기 진단을 위해 첫 촬영 날짜인 7월 5일의 자료로 모델을 만들어 다른 회차에 적용하여 모델의 성능을 평가한 결과, 5개의 모든 단계에서 0.9 이상의 accuracy를 얻었다. 종합적으로, UAV 영상 기반의 식생 지수를 활용한 양분 결핍 진단은 벼의 생육을 조기에 예측하는 데 효과적이며, 이는 정밀 농업 분야에서 시간과 노동을 절감하고 양분 관리를 개선하는 데 도움이 될 것으로 기대된다.

PURPOSES : Pavement surface friction depends significantly on pavement surface texture characteristics. The mean texture depth (MTD), which is an index representing pavement surface texture characteristics, is typically used to predict pavement surface friction. However, the MTD may not be sufficient to represent the texture characteristics to predict friction. To enhance the prediction of pavement surface friction, one must select additional variables that can explain complex pavement surface textures. METHODS : In this study, pavement surface texture characteristics that affect pavement surface friction were analyzed based on the friction mechanism. The wavelength, pavement surface texture shape, and pavement texture depth were hypothesized to significantly affect the surface friction of pavement. To verify this, the effects of the three abovementioned pavement surface texture characteristics on pavement surface friction must be investigated. However, because the surface texture of actual pavements is irregular, examining the individual effects of these characteristics is difficult. To achieve this goal, the selected pavement surface texture characteristics were formed quantitatively, and the irregularities of the actual pavement surface texture were improved by artificially forming the pavement surface texture using threedimensionally printed specimens. To reflect the pavement surface texture characteristics in the specimen, the MTD was set as the pavement surface texture depth, and the exposed aggregate number (EAN) was set as a variable. Additionally, the aggregate shape was controlled to reflect the characteristics of the pavement surface texture of the specimen. Subsequently, a shape index was proposed and implemented in a statistical analysis to investigate its effect on pavement friction. The pavement surface friction was measured via the British pendulum test, which enables measurement to be performed in narrow areas, considering the limited size of the three-dimensionally printed specimens. On wet pavement surfaces, the pavement surface friction reduced significantly because of the water film, which intensified the effect of the pavement surface texture. Therefore, the pavement surface friction was measured under wet conditions. Accordingly, a BPN (wet) prediction model was proposed by statistically analyzing the relationship among the MTD, EAN, aggregate shape, and BPN (wet). RESULTS : Pavement surface friction is affected by adhesion and hysteresis, with hysteresis being the predominant factor under wet conditions. Because hysteresis is caused by the deformation of rubber, pavement surface friction can be secured through the formation of a pavement surface texture that causes rubber deformation. Hysteresis occurs through the function of macro-textures among pavement surface textures, and the effects of macro-texture factors such as the EAN, MTD, and aggregate shape on the BPN (wet) are as follows: 1) The MTD ranges set in this study are 0.8, 1.0, and 1.2, and under the experimental conditions, the BPN (wet) increases linearly with the MTD. 2) An optimum EAN is indicated when the BPN (wet) is the maximum, and the BPN decreases after its maximum value is attained. This may be because when the EAN increases excessively, the space for the rubber to penetrate decreases, thereby reducing the hysteresis. 3) The shape of the aggregate is closely related to the EAN; meanwhile, the maximum value of the pavement surface friction and the optimum EAN change depending on the aggregate shape. This is believed to be due to changes in the rubber penetration volume based on the aggregate shape. Based on the results above, a statistical prediction model for the BPN (wet) is proposed using the MTD, EAN, and shape index as variables. CONCLUSIONS : The EAN, MTD, and aggregate shape are crucial factors in predicting skid resistance. Notably, the EAN and aggregate shape, which are not incorporated into existing pavement surface friction prediction models, affect the pavement surface friction. However, the texture of the specimen created via three-dimensional printing differs significantly from the actual pavement surface texture. Therefore, the pavement surface friction prediction model proposed in this study should be supplemented with comparisons with actual pavement surface data in the future.

PURPOSES : Concrete, which is a construction material, is the most widely used compression material; however, unlike steel, it exhibits nonlinear material characteristics. Therefore, to examine the behavior of structures under the nonlinear conditions of concrete materials, one must select an appropriate numerical-analysis technique and a reasonable material model. When performing the nonlinear numerical analysis of a structure using general-purpose structural analysis software, the stress–strain curve or the Mohr–Coulomb failure criterion is typically employed to consider the nonlinear material characteristics. In this study, an efficient nonlinear numerical analysis is conducted by defining the stress–strain curves and Mohr–Coulomb parameters applicable to Strand7 to examine and design the stability of reinforced concrete structures. METHODS : This study was conducted by improving existing data. Based on the tensile region of the concrete stress–strain curve presented in a simple shape and the results of the splitting test, the proposed Mohr–Coulomb parameter was improved based on regulations stipulated in the design standards of concrete structures. The characteristics and usability of the improved material models were examined using concrete splitting tensile and bending models. RESULTS : A yield area distribution similar to that of the reference data is obtained when the Mohr–Coulomb material model is used in the numerical analysis of the concrete splitting tension, thus confirming the validity of the model. In the Mohr–Coulomb material model, nonlinear resistance continues even after the maximum reaction force occurs. However, when the stress–strain curve material model is applied, at the moment the maximum reaction force occurs, the material yields and begins to be damaged. In addition, by applying the Mohr–Coulomb material model to the bending numerical-analysis model, the magnitude of stress in the tensile region from the initial stage exceeds the yield stress defined in the stress–strain curve. CONCLUSIONS : Based on a series of examples, the usability of the proposed concrete stress–strain curve and Mohr–Coulomb parameters is confirmed. However, to obtain numerical-analysis results that are consistent with the nonlinear behavior of actual structures, nonlinear testing of reinforced concrete structures shall be conducted and material models shall be improved.

Geopolymer, also known as alkali aluminum silicate, is used as a substitute for Portland cement, and it is also used as a binder because of its good adhesive properties and heat resistance. Since Davidovits developed Geopolymer matrix composites (GMCs) based on the binder properties of geopolymer, they have been utilized as flame exhaust ducts and aircraft fire protection materials. Geopolymer structures are formed through hydrolysis and dehydration reactions, and their physical properties can be influenced by reaction conditions such as concentration, reaction time, and temperature. The aim of this study is to examine the effects of silica size and aging time on the mechanical properties of composites. Commercial water glass and kaolin were used to synthesize geopolymers, and two types of silica powder were added to increase the silicon content. Using carbon fiber mats, a fiber-reinforced composite material was fabricated using the hand lay-up method. Spectroscopy was used to confirm polymerization, aging effects, and heat treatment, and composite materials were used to measure flexural strength. As a result, it was confirmed that the longer time aging and use of nano-sized silica particles were helpful in improving the mechanical properties of the geopolymer matrix composite.

In the event of an emergency such as facility shutdown during process operation, the by-product gas must be urgently discharged to the vent stack to prevent leakage, fire, and explosion. At this time, the explosion drop value of the released by-product gas is calculated using ISO 10156 formula, which is 27.7 vol%. Therefore, it does not correspond to flammable gas because it is less than 13% of the explosion drop value, which is the standard for flammable gas defined by the Occupational Safety and Health Act, and since the explosion drop value is high, it can be seen that the risk of fire explosion is low even if it is discharged urgently with the vent stock. As a result of calculating the range of explosion hazard sites for hydrogen gas discharged to the Bent Stack according to KS C IEC 60079-10-1, 23 meters were calculated. Since hydrogen is lighter than air, electromechanical devices should not be installed within 23 meters of the upper portion of the Bent Stack, and if it is not possible, an explosion-proof electromechanical device suitable for type 1 of dangerous place should be installed. In addition, the height of the stack should be at least 5 meters so that the diffusion of by-product gas is facilitated in case of emergency discharge, and it should be installed so that there are no obstacles around it.

Code-compliant seismic design should be essentially applied to realize the so-called emulative performance of precast concrete (PC) lateral force-resisting systems, and this study developed simple procedures to design precast industrial buildings with intermediate precast bearing wall systems considering both the effect of seismic and blast loads. Seismic design provisions specified in ACI 318 and ASCE 7 can be directly adopted, for which the so-called 1.5S y condition is addressed in PC wall-to-wall and wall-to-base connections. Various coupling options were considered and addressed in the seismic design of wall-to-wall connections for the longitudinal and transverse design directions to secure optimized performance and better economic feasibility. On the other hand, two possible methods were adopted in blast analysis: 1) Equivalent static analysis (ESA) based on the simplified graphic method and 2) Incremental dynamic time-history analysis (IDTHA). The ESA is physically austere to use in practice for a typical industrial PC-bearing wall system. Still, it showed an overestimating trend in terms of the lateral deformation. The coupling action between precast wall segments appears to be inevitably required due to substantially large blast loads compared to seismic loads with increasing blast risk levels. Even with the coupled-precast shear walls, the design outcome obtained from the ESA method might not be entirely satisfactory to the drift criteria presented by the ASCE Blast Design Manual. This drawback can be overcome by addressing the IDTHA method, where all the design criteria were fully satisfied with precast shear walls’ non-coupling and group-coupling strength, where each individual or grouped shear fence was designed to possess 1.5S y for the seismic design.