밭농업의 일관화를 위해 개발된 복합작업기의 효율적인 운영전략은 연료절감의 목표와 함께 저속 로터리작업의 품질에도 중점을 두어야 한다. 본 연구는 둥근 두둑 복합작업기의 작업품질을 유지하는 적정조건에서 동력과 연료소비를 계상하고 비교하여 집약적 밭농업에서의 효율적인 작업기 운용전략을 제안하려 하였다. PTO 표준 시험성적을 이용한 Kim 모델은 임의의 부분 부하 상태에서 연료소비량(FC), 비체적 연료소비율(SVFC) 및 단위면적당 연료소비율(FCA)를 구하고 셀선도(shell diagram)를 얻을 수 있다. 따라서 개발된 복합작업기에 적용할 카테고리 1 트랙터(DK450)와 카테고리 2 트랙터(PX800)를 선정하고 적정운용 조건에서의 연료소비 특성을 비교하였다. 이전 연구를 바탕으로 이론적인 목표 작업속도는 3.0<SPDth<4.0km/h와 로터리 피치(p)가 35<p<47cm/rev인 범위를 적정한 작업 기준(criteria)으로 하여 운용조건을 선택하였다. 각 트랙터에서 적정한 운용조건의 사례들을 비교하면 작은 트랙터(DK 450)를 사용함으로써 얻을 수 있는 연료소비 절약율은 FC가 19.4%, SVFC가 21.1% 그리고 FCA가 29.9% 정도로 평가된다.

The pitch-based activated carbon fibers (ACFs) were prepared from ethylene tar-derived pitches containing nickelocene (CNi) or nickel nitrate (NiN). The effects of different anions and contents of metal salts on the microstructure and surface chemical properties of fibers were investigated. The results revealed that Ni2+ from CNi mainly remained its pristine molecule in the organometal salt-derived pitch (OP-xCNi), while Ni2+ from NiN occurred complexation reaction with polycyclic aromatic hydrocarbons (PAHs) in the inorganic metal salt-derived pitch (IP-xNiN) due to the weaker binding ability between anions and Ni2+ of CNi than CNi. The XRD and SEM results confirmed that IP-3NiN-ACF contained Ni, NiO, Ni2O3 nanoparticles with different size distributions, while OP-3CNi-ACF only contained more uniformly distributed Ni nanoparticles with small size. Furthermore, OP-3.0CNi-ACF presented higher specific surface area of 1862 m2/ g and a pore volume of 1.69 cm3/ g than those of IP-3.0NiN-ACF due to the formation of pore structure during the in-situ catalytic activation of different metal nanoparticles. Therefore, this work further pointed out that the desired pore structure and surface chemistry of pitch-based ACFs could be obtained through regulating and controlling the interaction of anion species, metal cations and PAHs during the synthesis of pitch precursors.

A conventional porous carbon is still a very promising material for the removal of gaseous pollutants because of its abundant surface functional groups and a high specific surface area. Here, we prepared an environment-friendly uniform N-rich narrow micropore activated carbon, for the removal of formaldehyde, based on steam activation and N-rich with chitin as the starting material. A sample carbonized at 500 °C and steam activated at 800 °C (CAC800) showed a reasonable yield (55%) with uniform and narrow micropores without mesopores but having a balanced nitrogen functionality. CAC800 possesses outstanding formaldehyde removal capabilities under both dry and wet (humidity 45%) conditions. In addition, when compared with commercial activated carbon materials, we clearly demonstrated that the existence of high nitrogen content with uniform and narrow micropores simultaneously removed formaldehyde, effectively.

바이오산업의 발전으로 의약품, 식품 등의 생산 과정의 분리/정제 공정에 사용되어 왔던 기존의 컬럼 크로마토그 래피를 대체하여 더 높은 처리효율을 갖는 막 크로마토그래피가 부상하고 있다. 본 연구에서는 서로 다른 기공 크기의 두 가 지 상용 셀룰로오스 아세테이트(Cellulose acetate, CA) 분리막을 탈아세틸화 과정을 통해, 리간드의 개질이 용이한 다공성 재 생 셀룰로오스 지지체를(Regenerated cellulose, RC) 제조하였다. 음이온 교환능을 부여하고자 grafting을 수행하였으며, 구체 적으로는 UV 중합법을 통해 4차 암모늄을 포함하는 음이온 교환 리간드(MAPTAC)를 부착하여 음이온 교환용 흡착막을 제 조하였다. 단백질 흡착 용량은 정적 흡착 용량(Static binding capacity, SBC)시험을 통해 총 단백질 흡착 용량을 측정했고, 동 적 흡착 용량(Dynamic binding capacity, DBC)을 측정하여 상용막과 비교 평가하였다. 성능 평가 결과 단백질 흡착량은 넓은 표면적에 의해 리간드 밀도가 높은, 기공 크기가 작은 순서로 높게 측정되었고, 상용 CA분리막을 탈아세틸화하고 리간드를 부착시킨 분리막(RC 0.8 + MAPTAC 43.69 mg/ml, RC 3.0 + MAPTAC 36.33 mg/ml)이 상용 막 크로마토그래피 제품(28.38 mg/ml) 대비 높은 흡착 용량을 보였다.

The recycling of solid waste materials to fabricate carbon-based electrode materials is of great interest for low-cost green supercapacitors. In this study, porous carbon foam (PCF) was prepared from waste floral foam (WFF) as an electrode material for supercapacitors. WFF was directly carbonized at various temperatures of 600, 800, and 1,000 oC under an inert atmosphere. The WFF-derived PCF (C-WFF) was found to have a specific surface area of 458.99 m2/g with multi-modal pore structures. The supercapacitive behavior of the prepared C-WFF was evaluated using a three-electrode system in a 6 M KOH aqueous electrolyte. As a result, the prepared C-WFF as an active material showed a high specific capacitance of 206 F/g at 1 A/g, a rate capability of 36.4 % at 20 A/g, a specific power density of 2,500 W/kg at an energy density of 2.68 Wh/kg, and a cycle stability of 99.96 % at 20 A/g after 10,000 cycles. These results indicate that the C-WFF prepared from WFF could be a promising candidate as an electrode material for high-performance green supercapacitors.

Pentachlorophenol (PCP), as one of the common pesticide and preservatives, is easily accumulated in living organisms. Considering the high toxicity of PCP, the development of an effective and sensitive inspection method to determine the residual trace amounts of PCP continues to be a significant challenge. Herein, a convenient and sensitive electrochemical sensor is constructed by modifying glassy carbon electrode with cerium dioxide ( CeO2) nanoparticles anchored graphene ( CeO2-GR) to detect trace PCP. Benefiting from the two-dimensional lamellar structural advantages, the extraordinary electron-transfer properties, as well as the intensive coupling effect between CeO2 nanoparticles and graphene, the afforded CeO2- GR electrode nanomaterial possesses excellent electrocatalytic activity for the oxidation of PCP. Under the optimum synthetic conditions, the PCP oxidation peak currents of developed CeO2– GR sample exhibit a wide linear range of 5–150 μM. Moreover, the corresponding detection limit of PCP on the CeO2– GR electrode is as low as 0.5 μM. Apart from providing a promising electrochemical sensor, this work, most importantly, promotes an efficient route for the construction of highly active sensing electrode materials.

A composite photocatalyst of zinc oxide (ZnO) nanoparticles decorated with different content of reduced graphene oxide (rGO) was prepared via a simple and facile one-step method in this paper. X-ray diffraction (XRD), scanning electron microscopy (SEM), transmission electron microscopy (TEM), Raman spectra, and UV–Vis diffuse reflection spectroscopy (UV–Vis DRS) were used to characterize the crystal structure, morphology and optical properties of the rGO–ZnO composite photocatalyst. The photocatalytic properties of the composites were investigated using methyl orange (MO), a typical orange compound, as a test pollutant. The results showed that rGO–ZnO composites displayed significantly enhanced photocatalytic activity in MO degradation than pure ZnO, and the pseudo-first-order kinetic constant on the optimal rGO–ZnO composite was 14 times as great as that on pure ZnO. The enhanced photocatalytic ability of the rGO-ZnO composites was mainly benefited from the high specific surface area and high conductivity of rGO, which facilitated efficient charge separation in the rGO-ZnO nanocomposite.

본 연구는 졸업학년 간호대학생의 성장마인드셋과 셀프리더십이 진로준비행동에 미치는 영향을 규명하고자 시도된 서술적 조사연구이다. 자료수집 기간은 2021년 11월 1일부터 30일까지이며, 연구대상 은 G시와 J도에 소재한 3개 대학교 간호대학생 173명이다. 자료 분석은 SPSS 26.0 프로그램을 이용하여 t-test, ANOVA, 기술분석, Pearson‘s correlation, 통제회귀분석을 실시하였다. 연구결과, 성장마인드셋은 셀프리더십(r=.343, p<.001) 및 진로준비행동(r=.373, p<.001)과 정적상관을 보였으며, 셀프리더십과 진로 준비행동도(r=.515, p<.001) 정적상관을 보였다. 또한, 셀프리더십(β=.435, p<.001)과 성장마인드셋(β =.193, p=.005)은 진로준비행동에 정적영향을 미치며, 진로준비행동을 32.0% 설명하였다. 이에 졸업학년 간호대학생의 진로준비행동을 촉진하기 위한 방안으로 셀프리더십과 성장마인드셋의 함양을 위한 실제적 인 전략이 필요함을 시사한다.

The purpose of this study was to investigate the preparation and cooking processes used to prepare Eungi in cookbooks published from the 1700s to the 1900s. ‘Eungi’ is a thin gruel made of starch powder. Fourteen historical cookbooks were included and investigated for the preparation of ingredients and processing methods. Fourteen types of eungi were identified. Arrowroot eui and kuseonwangdogo eui were found in 『Kyuhapchongseo』 written in the early 1800s, and many types of eungi (i.e. job’s tears eungi, arrowroot eungi, sorghum eungi, lotus root eungi) were mentioned in 『Kunhakhoedeung』, but unfortunately, ingredients and cooking methods were not included. ‘Eungi’ was made by boiling starch powder prepared using the ‘subi method’, that is, dried after grinding main ingredients such as job’s tears using a millstone followed by soaking and settling. Eungi boiled with water or omija water were seasoned with the sugar or honey, and salt. These eungis were used for stomach complaints and hangovers and to promote longevity.

멤브레인은 분리 기술 및 다양한 사용처에 따라서 유기물, 액체, 용질, 증기, 기체, 이온 또는 전자 등 다양한 물질 을 선택적으로 분리할 수 있다. 멤브레인은 크게 대칭막과 비대칭막으로 나누며, 기공의 유무에 따라 다공성과 비다공성으로 분류된다. 또한 멤브레인의 계면은 분자적으로 균일하거나, 또는 화학적으로 또는 물리적으로 불균일할 수 있다. 제조기술로 는 용융 압출 제조법, 연신법, 템플레이트 침출법, 트랙-에치법, 용액 캐스팅법, 상전이법 및 용액 코팅법 등이 있다. 제조된 멤브레인은 정밀여과, 한외여과, 나노여과, 역삼투, 기체분리 및 에너지 분야와 같은 다양한 응용 분야에 적용될 수 있다. 본 총설에서는 멤브레인의 분류 및 종류에 따른 제조 방법에 대한 튜토리얼을 제공한다.

This experiment was conducted to establish the technology for artificial hay preparation in Korea. Using far-infrared heater, a device that can control temperature, airflow, and far-infrared radiation was produced and conducted on the fourth harvested alfalfa. The drying conditions were carried out by selecting a total of four conditions. For each condition, the radiation rate was set to around 40% (33-42%), and the temperature was set at 58~65℃, and the speed of the airflow was fixed at 60m/s. The overall drying time was set to 30 min in the single and 60 min (30-30 min) and 90 min (30-30-30 min) in the complex condition, and the radiation rate and temperature were changed by time period. In the case of drying condition 1, the final dry matter (DM) content was 46.26%, which did not reach a DM suitable for hay. However, all of the alfalfa corresponding to the remaining drying conditions 2 to 7 showed a DM content of 80% or more, resulting in optimal alfalfa hay production. In power consumption according to the drying conditions, the second drying condition showed the lowest at 4.7 KW, and the remaining drying conditions were as high as 6.5 to 7.1 KW. The crude protein content was found to be high at an average of 25.91% and it showed the highest content in the 5th drying condition (26.93%) and the lowest value in the 6th drying condition (25.16%). The digestibility showed a high value with an average of 84.90%, and there was no significant difference among treatments (p>0.05). Considering the above results, it was judged that drying condition 2 was the most advantageous.

광전기화학 성능을 향상시키기 위해 각 ZnO, ZnSe과 g-C3N4 소재의 장점을 살리도록 3성분계 적층 구조를 디자 인했다. 용액공정으로 FTO 기판위에서 ZnO 나노로드 어레이가 성장하도록 한 후 ZnO표면에 Se을 부착시켜 ZnO표면에 서 ZnSe층이 형성 되도록 이온 치환법을 도입하였다. ZnO/ZnSe 나노로드 위에 g-C3N4 층을 스핀코팅 한 후 각 층이 화 학적 접합이 되도록 질소 분위기 하에서 열처리를 하였다. AM 1.5G, 0.5 V 외부전압하에서 각 적층구조별로 광전기화학 적 전류밀도를 측정하였고 비교 결과 ZnO/ZnSe/g-C3N4 나노로드가 ZnO 및 ZnO/ZnSe 나노로드에 비하여 보다 높은 광 전류 밀도가 측정되었다. 수직 정렬된 ZnO 육각 프리즘형태는 큰 비표면적과 축 방향을 따라 전자 흐름을 원활히 하고, ZnSe 층은 비표면적과 광흡수 범위를 더욱 넗히는 효과를 가져왔다. 이로 인하여 ZnO/ZnSe/g-C3N4 삼원 접합 전극의 향상된 성능은 가시광선 흡수범위 확장, 전하 분리 강화 및 전자 전도도 향상으로 인한 시너지 효과에 기인되는 것으로 판단된다.

Hypercrosslinked polymers HCPs have been widely used as precursors to prepare porous carbon materials because of their highly ordered porous structure and large specific surface area. In this paper, we used a solvothermal method to prepare a hypercrosslinked polymer, and the HCPC-700-A was prepared using an activation method with the hypercrosslinked polymer as the precursor. The effects of different carbon–alkali ratios on the microstructure, composition and electrochemical properties of porous carbon HCP were studied. The results show that the surface of porous carbon HCPC-700-A presents a relatively regular geometric shape, and a large number of pore structures are mainly micro- and mesopores. The specific surface area is 2074.53 m2 g− 1, and the average pore size is between 1.29 and 1.93 nm. Porous carbon HCPC-700-1:2 has excellent electrochemical performance in 1 M H2SO4, and the specific capacitance is up to 464.4 F g− 1 at a current density of 1 A g− 1. The specific capacitance decay rate is 29.72% when the current density is increased from 1 A g− 1 to 8 A g− 1. After 5000 cycles, the capacitance retention rate is 91.16% at a current density of 2 A g− 1, showing excellent electrochemical performance, good cycle stability and perfect energy storage performance. This research provides new experimental ideas for HCPs in the electrochemical energy storage field.

Korea Research Reactor 1&2 (KRR-1&2), Korea’s first research reactor, began dismantling in 1997. As of 2022, the demolition of general areas such as offices has been completed, and contaminated areas such as reactor rooms remain. On the other hand, construction waste generated in contaminated areas of nuclear facilities cannot be disposed of as general industrial waste. It is predicted that about 5,000 tons of construction waste will be generated if the contaminated area of KRR-1&2 is demolished. In this study, the application plan for the demolition of contaminated area of KRR-1&2 was reviewed through a review of laws and cases related to domestic and overseas disposal. The only method for disposing of construction waste in contaminated areas that can be applied in Korea is clearance in accordance with Nuclear Safety Commission Notice No. 2020-06. In addition, there has been no case of demolishing large-scale nuclear facilities in Korea. Therefore, there are limitations in domestic laws and standards to be applied to the dismantling of contaminated areas of KRR-1&2. The IAEA and the United States specify comprehensive matters such as optimization of radiation protection and minimization of waste products. The EU recommends demolition after decontamination by removing contaminated areas before demolition of buildings. It also presents three options for reuse, recycling, and disposal of buildings and building waste. In particular, in the case of Germany, detailed radioactivity measurement methods for deregulation of buildings and building waste are presented in accordance with the EU’s guidelines. As a result of synthesizing this, it is judged that the EU and Germany building clearance plan will be suitable for domestic application.

In this study, lenses are fabricated using various nanomaterials as additives to a silicone polymer made with an optimum mixing ratio and short polymerization time. In addition, PVP is added at a ratio of 1% to investigate the physical properties according to the degree of dispersion, and the compatibility with hydrophobic silicone and the possibility of application as a functional lens material are confirmed. The main materials are SIU as a silicone monomer, DMA, a hydrophilic copolymer, EGDMA as a crosslinking agent, and 2H2M as a photoinitiator. Holmium (III) oxide, Europium (III) oxide, aluminum oxide, and PVP are used. When Holmium (III) oxide and Europium (III) oxide are added based on the Ref sample, the characteristics of the lens tend to be similar overall, and the aluminum oxide shows a tendency slightly different from the previous two oxides. This material can be used as a silicone lens material with various nano oxides and polyvinylpyrrolidone (PVP) acting as a dispersant.