Multi-walled carbon nanotubes (CNTs) were prepared by thermal chemical vapor deposition (CVD) and microwave plasma chemical vapor deposition (MPCVD) using various combination of binary catalysts with four transition metals such as Fe, Co, Cu, and Ni. In the preparation of CNTs from acetylene precursor by thermal CVD, the CNTs with very high yield of 43.6 % was produced over Fe-Co/Al2O3. The highest yield of CNTs was obtained with the catalyst reduced for 3 hr and the yield was decreased with increasing reduction time to 5 hr, due to the formation of FeAl2O4 metal-aluminate. On the other hand, the CNTs prepared by acethylene plasma CVD had more straight, smaller diameter, and larger aspect ratio(L/D) than those prepared by thermal CVD, although their yield had lower value of 27.7%. The degree of graphitization of CNTs measured by Id/Ig value and thermal degradation temperature were 1.04 and 602℃, respectively.

An aqueous solution of a commercial liquid synthetic detergent for kitchen use was photodecomposed in the presence of titanium dioxides powder under an atmosphere of air at room temperature. Titanium dioxides were prepared by sol-gel method from titanium iso-propoxide at different R ratio(H2O/titanium iso-propoxide) and calcined at 500℃. All titanium dioxides were characterized by XRD, BET surface area analyzer and UV-VIS spectrometer. The surface area of titanium dioxides prepared at R ratio=6 appeared higher volume about 20% than commercial TiO2 catalysts. XRD patterns of titania particles were observed mixing phase together with rutile and anatase type. Titanium dioxides prepared by sol-gel method show higher activity about 6% than commercial TiO2 catalysts on the photocatalytic degradation of a commercial liquid synthetic detergent for kitchen. The concentration of the detergent decreased to about 90% of its initial value at illumination times of 2 hour. Illumination for 30 minutes decreased the concentration of oxygen to about one-fifth of the initial value.

풍향풍속계와 구조 모니터링 시스템을 설치하여 강풍과 거물의 동적 특성을 계측하였다. 계측건물은 속초의 산기슭에 위치하고 있다. 감쇠율과 고유진동수의 진폭 의존성을 분석하였다. 감쇠율의 진폭의존성은 9%로서, 가속도진폭이 증가함에 따라서 감쇠율이 명료하게 증가하는 경향을 보였다. 계측데이터에서 얻은 동적 특성의 경향은 사용성 평가시 건물의 동적 특성을 평가하는데 유용하게 사용되리라 기대된다.

In the capacity spectrum method (CSM), the peak response of an inelastic system under a given earthquake load is estimated transforming the system into the equivalent elastic one. This paper presented estimating the peak inelastic response is evaIuated by the CSM. The equivalent period and damping are calculated using the ATC-40, Gülkan, Kowalsky, and Iwan methods, and the performance points are obtained according the procedure B of ATC-40. Analysis results indicate that the ATC-40 method generaIly underestimates the peak response, while the Gülkan and Kowalsky methods overestimate the responses. The Iwan method produces the values between those by the ATC-40 method and the Gülkan and Kowalsky methods, and estimates the reponses relatively closer to the exact ones. Further, it is found that the Kowalsky method gives the negative equivalent damping ratios depending on the hardening ratios, and thereby can not be used to estimate the responses in some cases.

구조물의 내진 성능을 정확히 평가하기 위해서는 비선형 시각 이력 해석이 필요하지만 실용성과 단순성 측면에서 약산법이 대안이 될 수 있으며, 다층 구조물을 등가 단자유도계로 치환할 때 다층 구조물의 모드벡터는 구조물이 탄성 또는 탄소성 상태에 상관없이 탄성 상태에서의 모드 형상으로 가정되지만, 항복이 발생한 후 증가하는 하중단계에서 구조물은 비탄성으로 되기 때문에 변위 모드 특성들도 변화된다. 본 논문은 항복 이후의 구조물의 모드 변화를 고려한 비선형 변위모드를 이용하여 다자유도계를 등가 단자유도계로 변환하는 방법을 제시하였으며, 변환된 등가 단자유도계의 변위응답을 근거로 추정한 복합 구조물의 최상층 변위와 실제 지진교란을 받는 복합 구조물의 비선형 동적해석에 의한 최상층 변위를 비교함으로서 복합구조물의 지진응답예측을 위한 비선형 변위모드법의 적용성과 신뢰성을 검토하였다.

The articles of food is very important things to human. Since PL Law came into effect in July of the last year(2002) in Korea, many domestic firms have taken great interests in PL. And the purpose of PL Law is to provide a means for those injured by defective products to receive redress. Additionally, enterprises get to place more importance on the safety of the products, which led to improvement in competitiveness and enhancement in quality. Consequently customers can get better products. So, it aims not only to compensate the injured by defective products but also to act an incentive to maker/supliers of food to make their products more safe. Therefore, this study was aiming to analyze the expected risks to articles of food after the enforcement of PL Law, and to establish a defending plan.an.

현 도로교의 내진해석은 구조물이 하중 이상의 강도를 갖도록 하는 하중기반해석법에 근거하고 있다. 본 연구에서는 이러한 하중기반해석의 대안책으로 구조물의 성능평가 대상을 변위로 하는 변위기반해석의 일종인 역량스펙트럼법을 제시하였다. 하중기반해석에서 내진설계가 수행되어진 기존 철근콘크리트 교각에 대하여 역량스펙트럼법에 의한 내진성능을 평가하였다. 그 결과, 역량스펙트럼법은 간편하고 신속하게 구조물의 비탄성 응답을 현실적으로 평가할 수 있었으며 비탄성 응답을 일으키는 다양한 지반운동 수준에 대해 구조물에 발생하는 변위를 평가할 수 있었고, 기존 구조물의 내진성능에 대한 평가나 신설구조물의 성능목표에 대한 설계검증에 효율적으로 적용 가능하였다.