Porous W with controlled pore characteristics was fabricated by a freeze-drying process. WO3 powder and camphene were used as the source materials of W and sublimable vehicles, respectively. Camphene slurries with WO3 contents of 10 and 15 vol% were prepared by milling at 50˚C with a small amount of oligomeric polyester dispersant. Freezing of a slurry was done in a Teflon cylinder attached to a copper bottom plate cooled at -25˚C while the growth direction of the camphene was unidirectionally controlled. Pores were generated subsequently by sublimation of the camphene during drying in air for 48 h. The green body was hydrogen-reduced at 800˚C for 30 min and sintered in a furnace at 900˚C for 1 h under a hydrogen atmosphere. Microstructural observation revealed that all of the sintered samples were composed of only W phase and showed large pores which were aligned parallel to the camphene growth direction. The porosity and pore size increased with increasing camphene content. The difference in the pore characteristics depending on the slurry concentration may be explained by the degree of powder rearrangement in the slurry. The results strongly suggest that a porous metal with the required pore characteristics can be successfully fabricated by a freeze-drying process using metal oxide powders.

The goal of the present work was to investigate the development of a geopolymeric ceramic material from a mixture of mine residue, coal fly ash, blast furnace slag, and alkali activator solution by the geopolymer technique. The results showed that the higher compressive strength of geopolymeric ceramic material increased with an increase in active filler (blast furnace slag + coal fly ash) contents and with a reduction of mine residue contents. The geopolymeric ceramic had very high early age strength. The compressive strength of the geopolymeric ceramic depended on the added active filler content. The maximum compressive strength of the geopolymeric ceramic containing 20 wt.% mine residue was 141.2 MPa. The compressive strength of geopolymeric ceramic manufactured by adding mine residue was higher than that of portland cement mortar, which is 60 MPa, when cured for 28 days. SEM observation showed the possibility of having amorphous aluminosilicate gel within geopolymeric ceramic. XRD patterns indicate that the geopolymeric ceramic was composed of amorphous aluminosilicate, calcite, quartz, and muscovite. The Korea Standard Leaching Test (KSLT) was used to determine the leaching potential of the geopolymeric ceramic. The amounts of heavy metals were noticeably reduced after the solidification of mine residue with active filler.

The objective of this study was to examine effect of ethylene glycol for semen cryopreservation in Korean Jeju Black Bull. The semen was cryopreserved with extenders containing cryoprotectants (7% glycerol and 3%, 5%, 7% ethylene glycol) and packed to 0.5 ml straws. The semen straws were located above 3 cm of liquid nitrogen for 5 min, 5 cm for 10 min and 8 cm for 10 min. And then frozen straw was plunged into LN2. Post-thawed sperm motility, viability and membrane integrity were significantly higher in 5% ethylene glycol (72.5±5.00%, 54.88±0.66% and 46.00±2.40%; p<0.05). Motility and viability were similar between 7% glycerol and 5% ethylene glycol. However, the membrane integrity was significantly higher in 5% ethylene glycol (34.69±4.64% vs 46.00±2.40%; p<0.05). The viability and membrane integrity were significantly higher in 5 cm for 10 min and 8 cm for 10 min than 3 cm for 5 min (viability: 55.81±2.94, 55.19±3.34 vs 47.94±3.48%; p<0.05 and membrane integrity: 44.94±3.51, 46.06±2.25 vs 40.38±1.03%; p<0.05). The percentage of capacitated sperm assessed by CTC staining, percentage of F pattern was higher in 7% glycerol, 5% and 7% ethylene glycol, and AR pattern was significantly higher in 3% ethylene glycol. F pattern was significantly increased in 5 cm for 10 min and 8 cm for 10 min (p<0.05), but AR pattern was significantly increased in 3 cm for 5 min (p<0.05).

For this study, Korean-type Koumiss was made by the fermentation of mixed cultures, in which yeast, Kuyveromyces, and microflora, Streptococcus thermophiles and Lactobacillus bulgaricus, were inoculated into 10% skimmed milk with added whey powder(control: A, 2%: B, 4%: C, 6%: D, and 8%: E). Fat, protein, lactose, titratable acidity, pH, the number of lactic acid bacteria, the number of yeast, alcohol content, volatile fatty acids, volatile free amino acids and minerals were measured in the products. The results were as follows: As the dosage of whey powder increased, fat increased from 0.74% in the control to 2.30% in sample E, protein increased from 2.95% in the control to 4.39% in sample E and lactose increased from 3.10% in the control to 7.43% in sample E. Titratable acidity and pH increased gradually. The number of lactic acid bacteria increased from 10(9) cfu/㎖ in the control to 3.8×10(9) cfu/㎖ in sample E, and the number of yeast increased from 6.1×10(7) cfu/㎖ in the control to 1.65×10(8) cfu/㎖ in sample E, according to the increase of whey powder content. For alcohol content, the average values were 0.863%, 0.967%, 0.890%, 1.290%, and 1.313% for the control and samples B, C, D, and E, respectively. As the dosage of whey powder increased, alcohol content showed a tendency to gradually increase. The average alcohol content of E was 1.313 and this was higher than the alcohol content of Kazahstana-type Koumiss with 1.08%. Sixteen types of free amino acids were detected. Glycine was the lowest in the control at 0.38 ㎎/㎖ and sample E contained 0.64 ㎎/㎖. Histidine was also low in the control at 0.42 ㎎/㎖ and sample E contained 0.65 ㎎/㎖. On the other hand, glutamic acid was highest at 4.13 ㎎/㎖ in the control whereas sample E had 6.96 ㎎/㎖. Proline was also high in the control at 1.71 ㎎/㎖ in control, but E contained 2.80 ㎎/㎖. Aspartic acid and leucine were greater in sample E than in the control. For volatile free fatty acids, content generally had a tendency to increase in the control, and samples B, C, D, and E. Content of acetic acid gradually increased from 12, 661 ㎍/100 ㎖ in the control to 37, 140 ㎍/㎖ in sample E. Butyric acid was not detected in the control and was measured as 1, 950 ㎍/100 ㎖ in sample E. Caproic acid content was 177 ㎍/100 ㎖ in the control and 812 ㎍/100 ㎖ in sample E, and it increased according to the increase of whey powder content. Valeric acid was measured in a small amount in the control as 22 ㎍/100 ㎖, but it was not detected in any other case. Mineral contents of Ca, P, and Mg increased from 1, 042.38 ppm, 863.61 ppm, and 101.28 ppm in the control to 1, 535.12 ppm, 1, 336.71 ppm, and 162.44 ppm in sample E, respectively. Na content was increased from 447.19 ppm in the control to 1, 001.57 ppm in sample E. The content of K was increased from 1, 266.39 ppm in the control to 2, 613.93 ppm in E. Mineral content also increased with whey powder content. In sensory evaluations, the scores increased as whey powder content increased. Flavor was lowest in the control with 6.3 points and highest in E with 8.2 points. Body and texture were highest at 4.2 points in the control, which did not have added whey powder. In the case of appearance, there were no great differences among the samples.

Alloys of nylon(PA6) and ethylene-propylene-diene polymer, modified with maleic anhydride(MEPDM) were prepared using a melt kneading process. This study focuses on the effects of the content of MEPDM in PA6 blend on the mechanical and thermal properties of such blends where MEPDM is the dispersed phase. Mechanical properties were examined by stress-strain measurements and impact strength test. Both impact strength of PA6/MEPDM at room temperature and at -20℃ were improved up to 400-550% with the amounts of MEPDM. However, PA6/MEPDM containing 3-5 wt% of MEPDM showed the about 700kgf/m2 of the maximum tensile strength but 8.5 % of the lowest elongation. For certain compositions of PA6 with rubbery MEPDM, the interesting reduction of elongation is caused by the reaction of the polyamide amine end groups with maleic anhydride portion in MEPDM, that provided a reinforcement in the PA6 matrix. In addition, the introduction of antistatic agent on the surface of alloys causes significant reduction of their surface electrostatic resistance.

본 연구는 고내구성을 가진 고분자 전해질 막을 제조하는 것으로 연료전지에 적용하기 위하여 poly(vinyl alcohol)를 주쇄부로 하여 poly(styrene sulfonic acid-co-maleic acid) (PSSA-MA)와 3-(trihydroxysilyl)-1-propanesulfonic acid (THS-PSA)를 polyethylene막에 함침시켜 막을 제조하였다. 제조된 막을 함수율, 접촉각, FT-IR, 수소이온전도도, 탄성계수 등의 측정을 통해 친수성 고분자가 함침된 막의 특성평가를 실시하였다. FT-IR 분석과 접촉각 측정을 통해 PE막에 함친된 막에서 친수성기의 유무를 확인하였다. 수소이온전도도를 측정한 결과 30% THS-PSA의 막이 55℃에서 1.27×10 ­1S/㎝의 값을 나타내어 우수한 수소이온전도도를 나타내었으며, 탄성계수의 측정을 통해 polyethylene막에 비하여 THS-PSA가 함침된 막의 기계적 강도가 15%까지는 최대 7배까지 향상되어 막의 내구성이 향상되었음을 확인하였다.

본 연구는 사일리지 수확시기별 조제방법에 따른 수수수수 교잡종 사일리지의 품질에 미치는 영향을 구명하기 위하여 천안에 위치한 국립축산과학원 자원개발부에서 수행되었다. 수수수수 교잡종 SS405를 이용하여 숙기별 2회(출수기 및 완숙기)에 걸쳐 수확을 하여 사일리지로 조제하였다. 수수수수 교잡종 소포장 및 톤백 사일리지는 수확시기가 늦어짐에 따라 조단백질 함량은 증가하는 경향을 보였으나 섬유소인 ADF 및 NDF 함량은 감소하는 경향을 보였다. 그리고 젖

기질 고분자인 sulfonated PEEK (sPEEK)와 가교제(cross-linking reagent) 4,4'-ethyldianiline (EdAn), 그래프트제(grafting reagent) 2-phenylethylamine (PEA)을 용매 dimethylacetamide (DMAc)에 녹여 용매증발법을 이용하여 제막하였다. 이민화 반응(imination)과 술폰화(sulfonation) 과정을 거쳐 최종 이온교환막인 cross-linked and grafted sPEEK (CG-sPEEK)막을 제조하였다. FT-IR 분석을 통해 술폰화 및 이민화 반응여부를 확인할 수 있었다. Proton conductivity와 water uptake, volume change를 측정하여 상용화된 Nafion115와 비교함으로써 이온교환막으로서의 활용가능성을 평가하였다. 제조된 CG-sPEEK막의 proton conductivity (0.17 S/cm) 값이 Nafion115 (0.10 S/cm) 보다 우수하게 나타나 이온교환막으로서의 적용가능성을 보여주었다. 다만 높은 water uptake (130%)는 CG-sPEEK의 치수안정성을 위해서 저감시킬 필요가 있다.

본 연구에서는 메조기공 티타니아/알루미나 막을 솔-젤법을 이용하여 제조하였다. 티타니아/알루미나 막의 기공구조 및 결정상은 하소 온도에 따라 조절될 수 있었다. 티타니아에 알루미나를 첨가하는 것은 티타니아 결정상이 아나타제상에서 루타일상으로 상변화 되는 것을 지연시켜 기공구조의 열적 안정화를 가져왔다. 5번 딥코팅하여 제조된 막의 두께는 10.3mum였으며, 평균 기공크기는 5 nm이었다. 기체 투과 실험 결과는 수소와 질소의 permeance는 각각 17.1×10 -7mol/㎡·s·Pa 및 4.7×10 -7mol/㎡·s·Pa이었다. 이 결과는 Knudsen 확산에 의해 설명될 수 있었다.

Poly(vinyl chloride)-g-poly(oxyethylene methacrylate) (PVC-g-POEM) 가지형 공중합체를 원자전달라디칼 중합을 통해 합성하여 전기변색소자의 전해질에 적용하였다. 가소화된 고분자 전해질은 가소제로서 propylene carbonate (PC)/ethylene carbonate (EC) 혼합물을 도입하여 제조하였으며, Lithium tetrafluoroborate (LiBF4), lithium perchlorate (LiCIO4), lithium iodide (LiI) and lithium bistrifluoromethanesulfonimide (LiTFSI)를 사용하여 염의 종류에 따른 영향을 조사하였다. 광각 x-선 산란(WAXS)과 시차주사 열량법(DSC) 측정 결과 고분자 전해질의 구조와 유리전이온도(Tg)가 변하였고, 이는 POEM 내의 에테르의 산소와 리튬염 사이의 상호작용으로 인해 변했다는 것을 FT-IR 분광법을 통하여 확인하였다. 투과전자현미경(TEM) 측정 결과 PVC-g-POEM 가지형 공중합체의 미세상분리 구조가 PC/EC와 리튬염의 도입에도 변하지 않는 것을 관찰하였다. 가소화된 고분자 전해질은 poly(3-hexylthiophene) (P3HT) 전도성 고분자를 이용한 전기변색소자에 적용되었다.

This study was carried out to establish most suitable freezing condition, to evaluate the different glycerol concentration of freezing and thawing rates on motility, viability, membrane integrity and acrosome intecrity of frozen Korean Jeju Black Bull spermatozoa, Semen was collected from a Korean Jeju Black Bull using an artificial vagina and transported to the laboratory. The semen was extended gradually 1:5 then cooled slowly for 2 hrs to 4. The semen was diluted 1:1 with cryoprotectant extenders (3%, 5% and 7% glycerol) and equilibrated for 2 hrs at cold chamber and packed to 0.5 ml straws. The semen straws were located above 3 cm of liquid nitrogen for 5 minutes, above 5 cm for 10 min and above 8 cm for 10 min. And then the frozen straw was plunged into LN. The presented straws were examined the viability and motility after thawed at 37 water bath. The viability and membrane integrity immediately post-thawing were significantly higher in samples frozen in 7% glycerol than 3% and 5% glycerol (p<0.05). After CTC staining to assess acrosome integrity, F pattern was significantly increased, but B pattern was significantly decreased in 7% glycerol (p<0.05). Freezing distance of 5 cm from liquid nitrogen and pre-cooling for 10 min yield better survival and membrane integrity, but not significant difference. However, AR pattern according to CTC staining was significantly decreased in 3 cm for 5 min.

It seems required to determine what might affect the technological innovation activities of manufacturing companies and what kind of role they could play for them to carry out technological innovation activities in an effective way. The objective of the present study is thus to conduct a depth empirical analysis of the structural relations among business environment, technological innovation activities and performance of manufacturing companies. From the analysis, following outcomes could be drawn: First, with regard to the relationship between business environment and technological innovation activities of manufacturing companies, it has become clear that the external environment is a factor that can influence technological innovation activities such as management of technical property, technological innovation system as well as technical network, while it exercises no impact upon adaptation of manufacturers to new technologies. The internal environment, on the other hand, turns out to have influence on such overall factors of technological innovation activities as management of technical property, technological innovation system, adaptation to new technologies and technical network; and Second, as for the relationship between technological innovation activities and their performance, it has been obvious that management of technical property and technological innovation system, both factors of technological innovation activities, affect the performance of product development and financial achievements of manufacturing companies. Their adaptation to new technologies will also affect their performance of product development as well as financial achievements. These findings suggest that it is important for manufacturing companies to set up an operating system that may be able to upgrade the practical applicability of their technological development activities in an attempt to promote performance of their technological innovation activities.

The critical role played by manufacturing performance measurement systems in achieving competitive success is increasingly recognized. Developing an integrated performance measurement model is significant for strategic management. This study consist of se

[ LaMeO3 ](Me = Cr, Co) powders were prepared using the polymeric precursor method. The effects of the chelating agent and the polymeric additive on the synthesis of the LaMeO3 perovskite were studied. The samples were synthesized using ethylene glycol (EG) as the solvent, acetyl acetone (AcAc) as the chelating agent, and polyvinylpyrrolidone (PVP) as the polymer additive. The thermal decomposition behavior of the precursor powder was characterized using a thermal analysis (TG-DTA). The crystallization and particle sizes of the LaMeO3 powders were investigated via powder X-ray diffraction (XRD), field emission scanning electron microscopy (FE-SEM), and particle size analyzer, respectively. The as-prepared precursor primarily has LaMeO3 at the optimum condition, i.e. for a molar ratio of both metal-source (a : a) : EG (80a : 80a) : AcAc (8a) inclusive of 1 wt% PVP. When the as-prepared precursor was calcined at 700˚C, only a single phase was observed to correspond with the orthorhombic structure of LaCrO3 and the rhombohedral structure of LaCoO3. A solid-electrolyte impedance-metric sensor device composed of Li1.5Al0.5Ti1.5(PO4)3 as a transducer and LaMeO3 as a receptor has been systematically investigated for the detection of NOx in the range of 20 to 250 ppm at 400˚C. The sensor responses were able to divide the component between resistance and capacitance. The impedance-metric sensor for the NO showed higher sensitivity compared with NO2. The responses of the impedance-metric sensor device showed dependence on each value of the NOx concentration.

Nano-sized Y2O3 powders were prepared via a sol-gel method starting with Y(NO3)3·6H2O (Yttrium(III) nitrate hexahydrate) and water with ethanol as a cosolvent. Y2O3 is an important rare earth oxide and has been considered for use in nuclear applications, such as ceramic materials, due to its excellent optical and refractory characteristics. It has been used as a chemically stable substrate, a crucible material for melting reactive metals, and a nozzle material for jet casting molten rare earth-iron magnetic alloys. Oxalic acid (C2H2O4) has been adopted as a chelating agent in order to control the rate of hydrolysis and polycondensation, and ammonia was added in order to adjust the base condition. The synthesized Y2O3 powder was characterized using TG/DTA, XRD, FE-SEM, BET and Impedance Analyzer analyses. The powder changed its properties in accordance with the pH conditions of the catalyst. As the pH increases according to the FE-SEM, the grain grew and it showed that the pore size decreased while confirming the effect of the grain size. The nano-material Y2O3 powders demonstrated that the surface area was improved with the addition of oxalic acid with ammonium hydroxide.

The industrial manufacturing of YSZ products can be summarized as a three step process: a) hydrolysis of zirconyl chloride and mixing of other solutions, b) precipitation, and c) calcination. The addition of ammonia or OH- is essential in the precipitation process. However, a strong agglomeration was observed in the results of an ammonia or OH- addition. Thus, it is necessary to disperse the powders smoothly in order to improve the mechanical strength of YSZ. In this study, YSZ was synthesized using the urea stabilizer and hydrothermal method. YSZ powders were synthesized using a hydrothermal method with Teflon Vessels at 180˚C for 24 h. The mole ratio of urea to Zr was 0, 0.5, 1, and 2. The crystal phase, particle size, and morphologies were analyzed. Rectangular specimens (33 mm×8 mm×1±0.5 mm) for three-point bend tests were used in the mechanical properties evaluation. The crystalline of YSZ powders observed a tetragonal phase in the sample with a ratio of Zr:urea = 1:2 addition and a hydrothermal reaction time of 24 h. The average primary particle size of YSZ was measured to be 9 nm to 11 nm. The agglomerated particle size was measured from 15 nm to 30 nm. The three-point bending strength of the YSZ samples was 142.47 MPa, which is the highest value obtained for the Zr:urea = 1:2 ratio addition YSZ sample.

본 연구에서는 자연분해재 펠릿과 polyethylene들을 이용해 LDPE와 신장율과 인장강도가 유사한 생붕괴성 플라스틱 필름들을 제조하였다. 식품 포장재로서의 안전성, 광분해성, 열분해성 및 곰팡이 생분해성을 평가한 결과 제작된 생붕괴성 플라스틱 필름들은 식품 포장재로 사용하기에 안전하고 LDPE 필름에 비해 상대적으로 우수한 분해 특성을 나타내어 환경친화적인 식품 포장 소재로 사용될 가능성을 보여주었다.

쌀단백질을 효소분해하여 제조한 배양액으로 천연조미소재로 사용할 효모추출물을 제조하기 위한 최적 공정조건을 조사하였다. 쌀단백질(5%, w/w)을 단백분해효소인 Delvolase®로 효소분해한 상등분획에 3%(w/w) 수준으로 포도당을 첨가한 배지 조건이 가장 적절하였으며 이 조건에서 2.3 g/L의 효모를 회수하였다. 회수한 효모에는 RNA가 188.1 mg/g수준으로 함유되어 있었으며 GMP 및 IMP는 각각 650.33±48 μg/g, 69±21 μg/g 함유되어 있었다. 이와 같은 효모추출물에 효모배양액의 제조 후 남은 쌀단백질 잔사의 효소분해물(Rrh)을 혼합하면 감칠맛이 상승하였는데 미각센서 분석기로 측정한 결과 효모추출물의 감칠맛이 4.88에서 Rrh의 첨가 후에는 9.25로 증가하였으며 관능검사에서도 감칠맛의 증가를 확인할 수 있었다. 이와 같이 효모추출물에 쌀단백질 잔사의 효소분해물이 추가되면 효소분해 과정 중 생성된 다양한 맛 성분으로 인해 감칠맛이 상승되어 전체적인 기호도가 높아지므로 천연조미소재로서의 활용이 가능함을 알 수 있었다.

In this research, the indium dissolution properties of the waste LCD panel powders were investigated as a function of milling time fabricated by high-energy ball milling (HEBM) process. The particle morphology of waste LCD panel powders changed from sharp and irregular shape of initial cullet to spherical shape with an increase in milling time. The particle size quickly decreased to 15 until the first minute, then decreased gradually about 6 with presence of agglomerated particles after 5 minutes, which increased gradually reaching a uniform size of 13 consist of agglomerated particles after 30 minutes. The glass recovery, after dissolution, was over 99% at initial cullet, which decreased to 90.1 and 78.6% with increasing milling time of 1 and 30 minute respectively, due to a loss in remaining powder of the surface ball and jar, as well as the filter paper. The dissolution amount of indium out of the initial cullet was 208 ppm before milling, turning into 223 ppm for the mechanically milled powder after 1 minute, and nearly 146~125 ppm with further increase in milling time because of the reaction surface decrease of powders due to agglomeration. With this process, maximum dissolving indium amount (223 ppm) could be achieved at a particle size of 15 with 1 minute of milling.