Recently, due to high theoretical capacitance and excellent ion diffusion rate caused by the 2D layered crystal structure, transition metal hydroxides (TMHs) have generated considerable attention as active materials in supercapacitors (or electrochemical capacitors). However, TMHs should be designed using morphological or structural modification if they are to be used as active materials in supercapacitors, because they have insulation properties that induce low charge transfer rate. This study aims to modify the morphological structure for high cycling stability and fast charge storage kinetics of TMHs through the use of nickel cobalt hydroxide [NiCo(OH)2] decorated on nickel foam. Among the samples used, needle-like NiCo(OH)2 decorated on nickel foam offers a high specific capacitance (1110.9 F/g at current density of 0.5 A/g) with good rate capability (1110.9 - 746.7 F/g at current densities of 0.5 - 10.0 A/g). Moreover, at a high current density (10.0 A/g), a remarkable capacitance (713.8 F/g) and capacitance retention of 95.6% after 5000 cycles are noted. These results are attributed to high charge storage sites of needle-like NiCo(OH)2 and uniformly grown NiCo(OH)2 on nickel foam surface.

The (Ga1-xZnx)(N1-xOx) solid solution is attracting extensive attention for photocatalytic water splitting and wastewater treatment owing to its narrow and controllable band gap. To optimize the photocatalytic performance of the solid solution, the key points are to decrease its band gap and recombination rate. In this study, (Ga1-xZnx)(N1-xOx) nanofibers with various Zn fractions are prepared by electrospinning followed by calcination and nitridation. The effect of the composition and crystallinity of electrospun oxide nanofibers on the morphology and optical properties of the obtained solid-solution nanofibers are systematically investigated. The results show that the final shape of the (Ga1-xZnx) (N1-xOx) material is greatly affected by the crystallinity of the oxide nanofibers before nitridation. The photocatalytic properties of (Ga1-xZnx)(N1-xOx) with different Ga:Zn atomic ratios are investigated by studying the degradation of rhodamine B under visible light irradiation.

We investigate the effects of Yb2O3 and calcium aluminosilicate (CAS) glass as sintering additives on the sintering behavior of AlN. The AlN specimens are sintered at temperatures between 1700oC and 1900oC for 2 h in a nitrogen atmosphere. When the Yb2O3 content is low (within 3 wt.%), an isolated shape of secondary phase is observed at the AlN grain boundary. In contrast, when 3 wt.% Yb2O3 and 1 wt.% CAS glass are added, a continuous secondary phase is formed at the AlN grain boundary. The thermal conductivity decreases when the CAS glass is added, but the sintering density does not decrease. In particular, when 10 wt.% Yb2O3 and 1 wt.% CAS glass are added to AlN, the flexural strength is the highest, at 463 MPa. These results are considered to be influenced by changes in the microstructure of the secondary phase of AlN.

본 연구에서는 DVR 내부 공기유동을 직접 제어하여 CPU의 온도를 낮추기 위한 유동제어 구조물을 제안하였다. 제안된 구조물은 세 개의 얇은 판의 형태로 구성되었으며, DVR 내부의 공기 유동을 포괄적으로 제어하여 CPU의 효율적인 방열을 유도하고자 하였다. DOE와 RSM을 이용한 매개변수 연구기법을 통해 유동제어 구조물의 형상을 최적화하였으며, 해석에는 유한체적방법을 이용한 유체역학 분석 패키지인 FlowVision을 사용하였다. 실제 DVR 기기에서의 실험을 통해 해석 결과를 검증한 결과 CPU의 온도가 16.1℃ 낮아짐을 확인하였다

Gd2O3:Eu3+ red phosphors were prepared by template method from crystalline cellulose impregnated by metal salt. The crystallite size and photoluminescence(PL) property of Gd2O3:Eu3+ red phosphors were controlled by varying the calcination temperature and Eu3+ mol ratio. The nano dispersion of Gd2O3:Eu3+ was also conducted with a bead mill wet process. Dependent on the time of bead milling, Gd2O3:Eu3+ nanosol of around 100 nm (median particle size : D50) was produced. As the bead milling process proceeded, the luminescent efficiency decreased due to the low crystallinity of the Gd2O3:Eu3+ nanoparticles. In spite of the low PL property of Gd2O3:Eu3+ nanosol, it was observed that the photoluminescent property was recovered after re-calcination. In addition, in the dispersed nanosol treated at 85 oC, a self assembly phenomenon between particles appeared, and the particles changed from spherical to rod-shaped. These results indicate that particle growth occurs due to mutual assembly of Gd(OH)3 particles, which is the hydration of Gd2O3 particles, in aqueous solvent at 85 oC.

We report on an all-solution-processed hydrothermal method to control the morphology of ZnO nanostructures on Si substrates from three-dimensional hemispherical structures to two-dimensional thin film layers, by controlling the seed layer and the molar contents of surfactants during their primary growth. The size and the density of the seed layer, which is composed of ZnO nanodots, change with variation in the solute concentration. The ZnO nanodots act as heterogeneous nucleation sites for the main ZnO nanostructures. When the seed layer concentration is increased, the ZnO nanostructures change from a hemispherical shape to a thin film structure, formed by densely packed ZnO hemispheres. In addition, the morphology of the ZnO layer is systematically controlled by using trisodium citrate, which acts as a surfactant to enhance the lateral growth of ZnO crystals rather than a preferential one-dimensional growth along the c-direction. X-ray diffraction and energy dispersive X-ray spectroscopy results reveal that the ZnO structure is wurtzite and did not incorporate any impurities from the surfactants used in this study.

Flower-like nickel oxide (NiO) catalysts were coated on NiCrAl alloy foam using a hydrothermal method. The structural, morphological, and chemical bonding properties of the NiO catalysts coated on the NiCrAl alloy foam were investigated by field-emission scanning electron microscopy, scanning electron microscopy-energy dispersive spectroscopy, Xray diffraction, and X-ray photoelectron spectroscopy, respectively. To obtain flower-like morphology of NiO catalysts on the NiCrAl alloy foam, we prepared three different levels of pH of the hydrothermal solution: pH-7.0, pH-10.0, and pH-11.5. The NiO morphology of the pH-7.0 and pH-10.0 samples exhibited a large size plate owing to the slow reaction of the hydroxide (OH−) and nickel ions (Ni+) in lower pH than pH-11.5. Flower-like NiO catalysts (~4.7 μm-6.6 μm) were formed owing to the fast reaction of OH− and Ni2+ by increased OH− concentration at high pH. Thus, the flower-like morphology of NiO catalysts on NiCrAl alloy foam depends strongly on the pH of the hydrothermal solution.

Anodic aluminum oxide (AAO) has been widely used for the development and fabrication of nano-powder with various morphologies such as particle, wire, rod, and tube. So far, many researchers have reported about shape control and fabrication of AAO films. However, they have reported on the shape control with different diameter and length of anodic aluminum oxide mainly. We present a combined mild-hard (or hard-mild) anodization to prepare shape-controlled AAO films. Two main parameters which are combination mild-hard (or hard-mild) anodization and run-time of voltage control are applied in this work. The voltages of mild and hard anodization are respectively 40 and 80 V. Anodization was conducted on the aluminum sheet in 0.3 mole oxalic acid at 4oC. AAO films with morphologies of varying interpore distance, branch-shaped pore, diameter-modulated pore and long funnel-shaped pore were fabricated. Those shapes will be able to apply to fabricate novel nano-materials with potential application which is especially a support to prevent volume expansion of inserted active materials, such as metal silicon or tin powder, in lithium ion battery. The silicon powder electrode using an AAO as a support shows outstanding cycle performance as 1003 mAh/g up to 200 cycles.

Diameter-controlled tin oxide nanofibers have been successfully prepared using electrospinning and a subsequent calcination process; their diameters, morphologies, and crystal structures have been characterized. The diameters of the as-spun nanofibers can be decreased by lowering the concentration of a polymer and a tin precursor in the electrospinning solution because of the decrease in the solution viscosity. The crystal structure of the nanofibers calcined at various temperatures from 200˚C to 800˚C has been proved to be the tetragonal rutile of tin oxide; crystallinity is improved by increasing the temperature. However, nanofibers with lower concentrations of tin precursor do not maintain their fibrous structures after calcination at high temperatures. In this study, the effect of the relationship between the precursor concentration and the calcination temperature on the diameter and the morphology of the tin oxide nanofiber has been systematically investigated and discussed.

The researches related to active control systems utilizing superelastic shape memory alloys (SMA) have been recently conducted to reduce critical damage due to lateral deformation after severe earthquakes. Although Superelastic SMAs undergo considerable inelastic deformation, they can return to original conditions without heat treatment only after stress removal. We can expect the mitigation of residual deformation owing to inherent recentering characteristics when these smart materials are installed at the part where large deformation is likely to occur. Therefore, the primary purpose of this research is to develop concentrically braced frames (CBFs) with superelastic SMA bracing systems and to evaluate the seismic performance of such frame structures. In order to investigate the inter-story drift response of CBF structures, 3- and 6-story buildings were design according to current design specifications, and then nonlinear time-history analyses were performed on numerical 2D frame models. Based on the numerical analysis results, it can be comparatively verified that the CBFs with superelastic SMA bracing systems have more structural advantages in terms of energy dissipation and recentering behavior than those with conventional steel bracing systems.

has the characteristic is controlling the inhibition or promotion of particle growth by adsorbing onto specific facets of platinum nanoparticles. Therefore, in this study, was added to control the shape of platinum nanoparticles during the liquid phase reduction process. Consequently, platinum cubes were synthesized when of 1.1 mol% (with respect to the Pt concentration) was added into the solution. Platinum octahedrons were synthesized when 32 mol% (with respect to the Pt concentration) was added into the solution. These results demonstrate that the metal salt , effectively controlled the relative growth rates of each facet of Pt nano particles.

가변단면 압출기술은 사용하는 금형의 조합에 의해 다양한 가공이 가능한 성형공법으로, 압출시에 금형의 움직임에 의하여 제품의 단면형상을 변화시키거나, 치수와 두께를 동시에 변화시킬 수 있다. 압출공정에서 압출속도, 압출압력, 압출온도는 압출품의 표면결함이나 내부품질에 있어 중요한 영향인자이다. 그중 일정한 압출속도는 균일한 메탈 플로를 형성하여 성형품질에 있어서 고른 상태를 유지하게 만드는 요소이다. 기존의 압출 성형에서 펌프토출양의 변화에 의한 추출속도변동 문제는 램 속도의 변화를 계측하고 토출 양을 조정함으로써 압출속도를 제어하는 방법으로 해결한다. 그러나 가변단면 압출공정에서는 제품의 단면형상의 변화에 따라 압출비가 변하므로 이에 따른 램 속도 제어가 있어야만 한다. 본 연구에서는 가변단면 압출공정에서 가공형상에 따른 제어 알고리즘을 제시하여 가변 형상에 따른 램의 이동 속도 및 위치를 제공하려 한다.

본 논문은 형상기억합금 바의 휨 거동 특성 파악하기 위하여 여러 가지의 휨 거동 실험을 수행하였으며, 형상기억합금 바의 휨 거동분석을 통하여 지진 시에 적용 가능성을 규명하는데 목적이 있다. 이를 위해 단순 휨 및 이중 휨 실험을 재하속도 및 최대변위를 변수로 수행하였다. 힘-변위 곡선에서 추정한 재하 및 제하 시의 강성이 추정되었으며, 등가의 감쇠비도 각 실험결과에서 추정되었다. 단순 휨에서 형상기억합금 바는 32 mm 변위 이후에 강성증가현상을 나타냈으며, 이것은 SIM(Stress-Induced-Martensite) 현상에 의해서 발생하는 것으로 추정된다. 재하속도의 증가는 형상기억합금 휨 강성 증가에 영향을 주지 않는 것으로 나타났다. 이중 휨 거동에서 형상기억합금 바는 단순 휨에 비해 강성이 약 5배정도 크게 나타났으며, 감쇠비는 유사하게 나타났다. 휨 거동의 형상기억합금 바를 지진 변위 제어장치로 사용하여 3경간 단순지지 교량에 적용하여 지진해석을 수행하였다. 이러한 지진변위 제어장치는 매우 효과적인 것으로 나타났으며, 실용적인 것으로 판단된다. 본 논문의 의미는 형상기억합금 바의 휨 거동에 대한 기초 지식을 제공하는데 있다.

A cable structures have the advantage that cover a large space without column but it is very sensitive to deal with shape control because of its flexibility. Especially, location of control member and needed elongation of member are important things. Therefore, the purpose of this paper is studied on displacement control technique for pre-stressed cable structures by force method considering order of control.