In order to increase the toughness of ZTA(zirconia toughened alumina) ceramics, the present study focused on rearrangement and densification of particles according to the particle size of the parent material. When rough alumina was used for production of ZTA, densification behavior was observed in the specimen sintered at a temperature over 1550˚C. However, it was found that the densification behavior was occurred in the specimen sintered at 1450˚C when fine alumina powder was used. High relative density exceeding 98% was obtained when fine alumina powder was mixed with 15 wt% of 3Y-TZP and sintered at 1600˚C. Also, a hardness of 1820.2 Hv was obtained when a specimen containing 10 wt% of 3Y-TZP was sintered at 1600˚C. In the case of 3Y-TZP containing rough alumina powder that had been sintered the hardness value was around 1720.3 Hv. It was predicted that an improved toughening effect in ZTA could be achieved by using finer alumina powder as the parent material.

Al-based alloys have recently attracted considerable interest as structural materials and light weight materials due to their excellent physical and mechanical properties. For the investigation of the potential of Al-based alloys, a surface porous Al88Cu6Si6 eutectic alloy has been fabricated through a chemical leaching process. The formation and microstructure of the surface porous Al88Cu6Si6 eutectic alloy have been investigated using X-ray diffraction and scanning electron microscopy. The Al88Cu6Si6 eutectic alloy is composed of an α-Al dendrite phase and a single eutectic phase of Al2Cu and α-Al. We intended to remove only the α-Al phase and then the Al2Cu phase would form a porous structure on the surface with open pores. Both acidic and alkaline aqueous chemical solutions were used with various concentrations to modify the influence on the microstructure and the overall chemical reaction was carried out for 24 hr. A homogeneous open porous structure on the surface was revealed via selective chemical leaching with a H2SO4 solution. Only the α-Al phase was successfully leached while the morphology of the Al2Cu phase was maintained. The pore size was in a range of 1~5μm and the dealloying depth was nearly 3μm. However, under an alkaline NaOH, aqueous solution, an inhomogeneous porous structure on the surface was formed with a 5 wt% NaOH solution and the morphology of the Al2Cu phase was not preserved. In addition, the sample that was leached by using a 7 wt% NaOH solution crumbled. Al extracted from the Al2Cu phase as α-Al phase was dealloyed, and increasing concentration of NaOH strongly influenced the morphology of the Al2Cu phase and sample statement.

The purpose of this study was to determine the optimal mixing conditions for two different amounts of turmeric (Curcuma longa L.) powder and olive oil for the processing of chicken sausage. The experiment was designed according to the central composite design of response surface methodology, with ten experimental points, including two replicates for turmeric powder and olive oil. The physicochemical and mechanical analysis of each sample, including water holding capacity, moisture content, lightness, redness, yellowness, hardness, chewiness, gumminess, and cohesiveness, showed significant differences. The results from sensory evaluations also showed very significant differences in color, flavor, tenderness, chewiness, and overall quality. The optimal formulation, calculated by numerical and graphical methods, was 1.89 g of turmeric powder and 9.77 g of olive oil. Under these conditions, the model predicted pH-6.01, salinity-0.20, WHC-94.88, L* value-61.13, b* value-37.45, hardness-36.66×102 (N), springiness-8.70 (mm), chewiness-26.88×103 (N×mm).

Polyacrylonitrile (PAN) 기질고분자를 용매인 dimethylformamide (DMF)에 녹인 후 전기방사법을 이용하여 polyacrylonitrile nanofibers membrane (PAM)을 제조하였으며, 정밀여과(microfiltration) 적용을 위해, 제조된 PAM 샘플들의 layer 수를 변화시켜, 기공크기를 조절하였다. 또한, 순수투과도(water-flux) 향상을 위해 poly (ethylene glycol) methyl ether methacrylate와 azobisisobutylronitrile (AIBN)을 이용하여 자유 라디칼 중합(free radical polymerization)을 통해 합성된 AN‐ PEGMA 공중합체를 PAN과 3:1의 비율로 혼합한 후 위와 같은 방법으로 다공성 막(PAM/APM)을 제조하였으며, FT-IR과 E.D.S 분석을 통해 PAM 샘플과 비교⋅분석하였다. Scanning Electron Microscope (SEM) 분석과 기공크기, 기공도 실험을 통해 균일한 직경(400∼600 nm)과 균일한 기공특성(0.5∼0.4 μm)을 가진 다공성 막이 제조되었음을 확인할 수 있었다. 순수 투과도 측정을 통해 정밀여과용 막으로의 활용가능성을 조사하였으며, AN‐PEGMA 공중합체가 도입된 PAM/APM의 경우 상 용막인 polyvinylidenefluoride (PVdF)에 비해 순수투과도가 상대적으로 높은 값을 나타내었다. 위의 결과로부터 전기방사법으로 제조된 PAN 나노섬유막들은 정밀여과용 막으로서 충분한 활용가능성이 있다고 판단된다.

중심합성계획에 따라 마늘의 첨가량(1.5~10.45%)과 추출시간(52.8~300 min)을 독립변수로 하고, 고형분 함량, ABTs 라디칼 소거활성, ALDH 및 15% 에탄올에 대한 ADH 활성을 종속변수로 하여 다슬기와 마늘 혼합물의 최적 추출조건 설정을 위한 반응표면분석을 실시하였다. 고형분의 함량에 대해 예측된 정상점에서 최대값은 0.49 Brix%였고, 이때의 추출조건은 마늘 첨가량 6.17%, 추출시간 191분이었다. ABTs 라디칼 소거활성은 마늘 첨가량 7.95%, 추출시간 194분에서 최대값 96.68%를 나타내는 것으로 예측되었다. ALDH의 활성은 마늘 첨가량 5.64%, 추출시간 172분에서 142.18%의 최대값을 가지며, ADH 활성이 최대화되는 정상점에서 최대값은 214.89%였고, 이때 최적 추출조건은 마늘첨가량 8.53%, 추출시간 184분이었다. 네 가지 종속변수의 최대값을 얻기 위한 최적 추출조건의 범위는 마늘첨가농도 5.64~8.53%, 추출시간 172~194분이었다.

(Y123) powders for the fabrication of bulk superconductors were synthesized by the powder reaction method using (99.9% purity), (99.75%) and CuO (99.9%) powders. The raw powders were weighed to the cation ratio of Y:Ba:Cu=1:2:3, mixed and calcined at in air with intermediate repeated crushing steps. It was found that the formation of Y123 powder was more sensitive to reaction temperature than reaction time. The calcined Y123 powder and a mixture of (Y123 + 0.25 mole + 1 wt.% , (Y1.5)) were used as raw powders for the fabrication of poly-grain or single grain superconductors. The superconducting transition temperature () of the sintered Y123 sample was 91 K and the transition width was as large as 11 K, whereas the of the melt-grown Y1.5 sample was 90.5 K and the transition width was 3.5 K. The critical current density () at 77 K and 0 T of the sintered Y123 was 700 , whereas the of the top-seeded melt growth (TSMG) processed Y1.5 sample was . The magnetic flux density (H) at 77 K of the TSMG-processed Y123 and Y1.5 sample showed the 0.53 kG and 2.45 kG, respectively, which are 15% and 71% of the applied magnetic field of 3.5 kG. The high H value of the TSMG-processed Y1.5 sample is attributed to the formation of the larger superconducting grain with fine Y211 dispersion.

The quartz glasses were prepared by fumed silica powders sintering method at , , in air and the effect of sintering temperature on their properties were investigated. The X-ray diffraction pattern, the OH concentration, the light transmittance, the apparent porosity and the density were analyzed. The transparent quartz glass were obtained above . The OH-group and macroscopic pores were removed above and highest density and light transmittance were obtained at .

This study is carried out to develop the new process for the fabrication of ultra-fine electrodes on the flexible substrates using superhydrophobic effect. A facile method was developed to form the ultra-fine trenches on the flexible substrates treated by plasma etching and to print the fine metal electrodes using conductive nano-ink. Various plasma etching conditions were investigated for the hydrophobic surface treatment of flexible polyimide (PI) films. The micro-trench on the hydrophobic PI film fabricated under optimized conditions was obtained by mechanical scratching, which gave the hydrophilic property only to the trench area. Finally, the patterning by selective deposition of ink materials was performed using the conductive silver nano-ink. The interface between the conductive nanoparticles and the flexible substrates were characterized by scanning electron microscope. The increase of the sintering temperature and metal concentration of ink caused the reduction of electrical resistance. The sintering temperature lower than resulted in good interfacial bonding between Ag electrode and PI film substrate.

제조공정에서 사용되어 지는 SPC(Statistical Process Control)관리 기법은 가피원인을 탐지하여 변동을 감소시키는 통계적 공정관리 시스템이다. SPC의 대표적인 관리 기법으로는 Shewhart관리도, Cusum관리도, EWMA관리도가 있으며 이러한 관리 기법들은 공정을 보다 안정적으로 관리 할 수 있도록 유지 및 예측하는데 사용 되어 진다. 하지만 제조 공정의 유형에 따라 샘플링 방법, 관리한계선 등을 다양하게 설정하여 보다 효율적인 관리를 모색하고 있다. 공정 형태에 따라 다양한 관리 방법과 분석 결과가 나타난다. 일반적으로 Xbar-R 관리도와 같은 Shewhart 관리도를 사용하지만 Batch 단위의 공정, 연속 공정의 라인에서 사용되기에는 부분적인 한계를 보이고 있다. 본 논문에서는 일반적인 관리도와 공정 변화에 민감하게 반응 할 수 있는 누적합 관리도와 지수가중치이동평균 관리도를 비교해 보고 작은 변동에 대한 탐지 능력이 우수한 지수가중치이동평균 관리도에 대한 연구동향과 사례를 분석하여 제조 공정에 적합한 관리 방법을 모색하고자 한다.

본 연구는 여러 해조류 소재 중에서 국내 생산량이 많고 연소가 뛰어나 수율이 높은 해초액 화합물을 대량생산 실용화가 가능한 것을 목표로 하며, 해조류인 미역 다시마 톳 기타 김 등을 이용하는 것으로서 주로 원료확보는 폐자원 해조류 등을 이용하여 고온에서 Poly step trap식 건류 공정 적용인 탄화공정을 수반함으로서 생성된 해초 액을 개발하는 연구다. 이를 분리 정제하는 기술적 공정을 개발하고 나아가 시제품을 개발하여 농업, 식품, 비료, 의약품 대체화를 추진함과 동시에 제일 문제시 되고 있는 식품 첨가제를 해결함으로서 고 부가치성 창출과 바이오 생물약제 원료로 개발하고자 하였다. 그래서 해초 액을 추출 분리 및 정제연구를 실시하여 화합물 분석실험을 추진하였다. 그리고 목초액과 성분비교 우위성 입증실험을 성분비교실험을 통해서 비교 검증실험을 추진하였다.

폴리글리세롤에스터 유화제를 이용한 에멀젼의 입자상태 및 시간의 변화에 따른 안정성을 여러 가지 오일을 이용하여 실험을 실시하였다. 실험결과 오일의 종류에 따라 입자크기 및 안정성에 있어서 다소의 차이가 있는 것을 확인하였다. 폴리글리세롤 에스터로 유화된 가장 안정한 오일은 polar 오일인 실리콘계열과 지방산에스터 오일이고, 탄화수소계열의 nonpolar오일(Mineral oil, squalane, polydecene) 등이 유화에 있어서 가장 불안한 상태를 보였다. 식물성오일도 폴리글리세릴 에스터 유화제와는 안정한 형태의 입자형성을 보였다.

목적 : 본 연구는 제조업에 종사하는 근로자들에게 상지의 동작수행능력을 평가하는 Quick DASH 설문지 검사를 실시하여, 일반적 특성에 따른 점수의 차이와 검사도구의 특성과 민감도, 특이도에 대해서 알아보고자 하였다. 연구방법 : 2010년 12월부터 2011년 3월까지 경기도에 위치한 일개 전자 부품제조업의 생산직근로자 2,190명을 대상으로 자가 기입식 설문조사를 통하여 진행하였다. 측정도구로 근골격계 자각증상호소율을 알아보기 위해 근골격계자각증상 설문지(KOSHA code H-30-2008)와 상지의 기능적 동작을 수행하는 능력을 알아보기 위해 한국형QuickDASH 설문지를 사용하여 측정하였다. 결과 : QuickDASH 설문결과, 상지기능과 관련된 목 부위(29.08점), 어깨 부위(28.31점), 팔/팔꿈치 부위(32.47점), 손/손가락/손목 부위(28.79점)별로 각각 통증을 호소하는 군에서 통계적으로 유의하게 QuickDASH 점수의 차이가 있는 것으로 나타났다. 또한 근골격계 통증자를 기준으로 QuickDASH 설문지의 민감도 및 특이도를 신체부위별로 알아 본 결과 목 부위는 임계값을 24.9점으로 하였을 때 민감도는 66.9%, 특이도는 57.0%로 나타났다. 어깨부위는 임계값을 21.4점으로 하였을 때 민감도는 74.1%, 특이도는 51.4%로 나타났다. 팔/팔꿈치부위는 임계값을 25.1점으로 하였을 때 민감도는 74.3%, 특이도는 64.2%로 나타났다. 손/손가락부위는 임계값을 21.4점으로 하였을 때 민감도는 77.9%, 특이도는 48.7%로 나타났으며, 신체부위별로 구분하지 않고 어느 한 부위라도 양성에 해당하는 경우를 보면, 민감도 는 77.0%, 특이도는 63.5%, 임계값은 24.9점으로 나타났으며, AUC(Area Under the Curve)가 .78로 나타났다 결론 : 본 연구는 제조업에 종사하는 근로자들에게 상지의 동작수행능력을 평가하는 QuickDASH 설문지 검사가 특정 관절에 대한 통증보다는 전반적인 상지의 통증과 기능장애에 대해서 높은 민감도와 특이도를 보이는 것으로 나타났다.

To reproduce the brewing process of Hongkuk-ju and to identify the functional properties of it, Hongkuk-ju was brewed using different additions of Hongkuk (100%, 90%, 70%, 50%) and Nuruk (0%, 10%, 30%, 50%). The quality elements, including pH, total acidity, reducing sugar content, alcohol content and pigments (yellow, red, monacolin K and citrinin), were measured. The pH values of Hongkuk-ju showed a slight difference (pH 4.08～4.58) right after the 1st stage mash; further, the pH on all groups (H1, H2, H3 and H4) in the terminal of the 2nd stage mash (9 days in fermentation) were similar, ranging approximately at pH 3.70. The total acidity change did not show a difference directly the 1st stage mash (nearby 0.2 %); however, it began to show a slight difference at the terminal of the 2nd stage mash between the range of 0.69～0.76%. The residual reducing sugar of the content was decreased with the increased Nuruk content. The alcohol concentrations of the treatment brew with Nuruk ranging from 12.3% to 13.7% were higher than Hongkuk on its own. The yellow and red pigment contents of Hongkuk-ju ranged from 7.2～8.8 O.D. units (yellow pigment) and from 4.4～5.1 O.D. units (red pigment). The production of monacolin K and citrinin was the highest (9.48 ㎎/㎏ and 10.14 ㎎/㎏) when the treatment solely brewed Hongkuk. The concentration of Nuruk and the preparation of the seed mash from it were critical factors compared to the treatment of rice in brewing Hongkuk-ju

Several different depreciation systems may be used for group depreciation. The vintage group procedure treats the same type of property placed in service during the same year as a distinct group for depreciation purposes; therefore an estimate of the probable average service life and net salvage ratio(s) of each individual vintage is necessary. The vintage group procedure calculates an accrual rate for each vintage and the accrual rate for an account for specific calendar year is the weighted average vintage accrual rate for that calendar year. A further refinement would be to divide each vintage into groups such that all of the dollars in a group have the same estimated life-an equal life group (ELG). Then each ELG is depreciated over its estimated life. The effect is to recover each dollar over the estimated number of years it is in service. Each vintage is divided into several equal life groups (ELGs) such that all the property in a specific ELG has the same estimated life. The accrual rate for each ELG is based on the estimated life of that ELG. The vintage accrual rate for a specific year is the weighted average ELG accrual rate for that calendar year. In this paper, we illustrate the calculations of vintage accrual rates for each of the calendar years by the ELG depreciation systems.

Excellent electron transport properties with enhanced light scattering ability for light harvesting have made well-ordered one dimensional TiO2 nanotube(TNT) arrays an alternative candidate over TiO2 nanoparticles in the area of solar energy conversion applications. The principal drawback of TNT arrays being activated only by UV light has been addressed by coupling the TNT with secondary materials which are visible light-triggered. As well as extending the absorption region of sunlight, the introduction of these foreign components is also found to influence the charge separation and electron lifetime of TNT. In this study, a novel method to fabricate the TNT-based composite photoelectrodes employing visible responsive CuInS2 (CIS) nanoparticles is presented. The developed method is a square wave pulse-assisted electrochemical deposition approach to wrap the inner and outer walls of a TNT array with CIS nanoparticles. Instead of coating as a dense compact layer of CIS by a conventional non-pulsed-electrochemical deposition method, the nanoparticles pack relatively loosely to form a rough surface which increases the surface area of the composite and results in a higher degree of light scattering within the tubular channels and hence a greater chance of absorption. The excellence coverage of CIS on the tubular TiO2 allows the construction of an effective heterojunction that exhibits enhanced photoelectrochemical performance.

국내산 고구마를 이용하여 고품질의 고구마 막걸리를 개발하기 위해 다양한 방법의 고구마 막걸리 제조 방법 선정과 믹스쳐 디자인을 이용한 고구마 막걸리의 최적 배합비를 산출하였다. 엿기름 첨가 유무에 따른 혼합당화, 분리당화발효법을 이용하여 고구마 막걸리를 제조한 결과, 동시당화발효를 이용하여 고구마 막걸리를 제조하는 것이 적합함을 확인하였다. 최적의 고구마 막걸리 배합비를 구하기 위하여 쌀, 고구마, 물 세 가지 재료 요인으로 mixture design을 이용하여 다양한 배합비를 결정한 후, 고구마 막걸리를 제조하였다. 또한 제조된 고구마 막걸리의 선호도, 총 폴리페놀 함량, DPPH 라디칼소거능을 측정하여 통계적 모델링과 분석을 하였고, trace plot 및 contour plot을 이용하여 각 재료의 함량이 반응값에 미치는 영향을 확인할 수 있었다. 프로그램에 의해 예측된 고구마 막걸리의 최적 배합비는 15.11(쌀) : 44.89(고구마) : 40(물)이었으며, 이 배합비에 따른 반응값의 예상치는 선호도 6.17, 총 폴리페놀 함량이 414.95 ㎎ GAE/ℓ, DPPH 라디칼 소거능은 38.02%로 예측되었다. 최적배합비를 바탕으로 일반고구마, 호박고구마, 자색고구마를 이용하여 고구마 막걸리를 제조한 결과, 호박고구마 막걸리의 알코올 함량이 5.83%로 가장 높게 나타났으며, 총 폴리페놀 함량과 DPPH 라디칼 소거능은 자색고구마 막걸리>호박고구마 막걸리>일반고구마 막걸리의 순서로 높게 나타났다.