기질 고분자인 sulfonated PEEK (sPEEK)와 가교제(cross-linking reagent) 4,4'-ethyldianiline (EdAn), 그래프트제(grafting reagent) 2-phenylethylamine (PEA)을 용매 dimethylacetamide (DMAc)에 녹여 용매증발법을 이용하여 제막하였다. 이민화 반응(imination)과 술폰화(sulfonation) 과정을 거쳐 최종 이온교환막인 cross-linked and grafted sPEEK (CG-sPEEK)막을 제조하였다. FT-IR 분석을 통해 술폰화 및 이민화 반응여부를 확인할 수 있었다. Proton conductivity와 water uptake, volume change를 측정하여 상용화된 Nafion115와 비교함으로써 이온교환막으로서의 활용가능성을 평가하였다. 제조된 CG-sPEEK막의 proton conductivity (0.17 S/cm) 값이 Nafion115 (0.10 S/cm) 보다 우수하게 나타나 이온교환막으로서의 적용가능성을 보여주었다. 다만 높은 water uptake (130%)는 CG-sPEEK의 치수안정성을 위해서 저감시킬 필요가 있다.

Odors were produced in the reactor where contained the swine excreta sampled from the pigery and were analyzed the major odor materials based on the odor contribution index. The container hoggery where six pens were separated was set up in S-myun, Gyeonggi-do, Korea: one was control group, the other were experimental group. Sixty weaners were raised and their excreta were sampled every week to the test of the effect of feed type probiotics. Some probiotics showed very effective deodorizing activity during the whole experimental periods. All products had positive effects on the reducing odor intensities after 4 to 5 week periods. The odor contribution analysis represented the main odor compounds were trimethylamine and volatile sulfur compounds such as hydrogen sulfide, mercaptane, and dimethyl sulfide.

Nano-sized Y2O3 powders were prepared via a sol-gel method starting with Y(NO3)3·6H2O (Yttrium(III) nitrate hexahydrate) and water with ethanol as a cosolvent. Y2O3 is an important rare earth oxide and has been considered for use in nuclear applications, such as ceramic materials, due to its excellent optical and refractory characteristics. It has been used as a chemically stable substrate, a crucible material for melting reactive metals, and a nozzle material for jet casting molten rare earth-iron magnetic alloys. Oxalic acid (C2H2O4) has been adopted as a chelating agent in order to control the rate of hydrolysis and polycondensation, and ammonia was added in order to adjust the base condition. The synthesized Y2O3 powder was characterized using TG/DTA, XRD, FE-SEM, BET and Impedance Analyzer analyses. The powder changed its properties in accordance with the pH conditions of the catalyst. As the pH increases according to the FE-SEM, the grain grew and it showed that the pore size decreased while confirming the effect of the grain size. The nano-material Y2O3 powders demonstrated that the surface area was improved with the addition of oxalic acid with ammonium hydroxide.

The industrial manufacturing of YSZ products can be summarized as a three step process: a) hydrolysis of zirconyl chloride and mixing of other solutions, b) precipitation, and c) calcination. The addition of ammonia or OH- is essential in the precipitation process. However, a strong agglomeration was observed in the results of an ammonia or OH- addition. Thus, it is necessary to disperse the powders smoothly in order to improve the mechanical strength of YSZ. In this study, YSZ was synthesized using the urea stabilizer and hydrothermal method. YSZ powders were synthesized using a hydrothermal method with Teflon Vessels at 180˚C for 24 h. The mole ratio of urea to Zr was 0, 0.5, 1, and 2. The crystal phase, particle size, and morphologies were analyzed. Rectangular specimens (33 mm×8 mm×1±0.5 mm) for three-point bend tests were used in the mechanical properties evaluation. The crystalline of YSZ powders observed a tetragonal phase in the sample with a ratio of Zr:urea = 1:2 addition and a hydrothermal reaction time of 24 h. The average primary particle size of YSZ was measured to be 9 nm to 11 nm. The agglomerated particle size was measured from 15 nm to 30 nm. The three-point bending strength of the YSZ samples was 142.47 MPa, which is the highest value obtained for the Zr:urea = 1:2 ratio addition YSZ sample.

This study deals with the high frequency induction hardening (HF at 850℃, 120kHz & 50kW condition) SM45C steel. (1) The HF specimen, which was tempered at 150℃, did not show any tempering effect. A brittle fracture occurred at rounded area of the tensile specimen. AE (acoustic emission) amplitude distribution showed between 45dB and 60dB. (2) A slip and fracture occurred at the hole area of the HF specimen which was tempered at 300℃. As they pass the yield point, the AE energy is increased intermittently and AE amplitude distribution exists between 70dB and 85dB. In addition, after imposing the maximum tensile load, AE signals showed high amplitude and energy distribution. The AE amplitude showed between 45dB and 70dB. (3) A brittle fracture occurred at HF specimen which was tempered at 450℃ as if it is torn in the direction of 45° on parallel area over the both sides of the tensile specimen, which lead to several peak appeared in AE energy. It was found that the AE amplitude was relatively low and the AE energy was high.

본 연구의 목적은 중온화 첨가제(LEADCAP®)를 사용한 중온 아스팔트 바인더의 노화 방법에 따른 물성 변화 특성을 평가하고자 하였다. 아스팔트 바인더의 노화 거동을 모사하기 위해 단기노화인 RFTO를 실시하였으며, 햇빛에 의한 자연 노화 거동을 알아보기 위해 자외선 경화기를 이용하여 자외선에 의한 열화거동을 모사하였다. 이러한 열화 중온 아스팔트 바인더의 역학적인 물성과 유변동학적인 특성을 시험하기 위해서 만능시험기(UTM)과 동적전단유동기를 이용하여 직접인장력과 유변동학적인 거동을 평가하였다. 또한, 열분석 장비를 이용하여 온도에 따른 중온 아스팔트 바인더의 특성을 평가하여, 자외선 노출에 따른 열화가 발생하여도 온도에 따른 물성 변화가 많이 발생하지 않음을 발견하였다. 70℃에서 중온화 첨가제가 첨가한 단기노화 중온 아스팔트 바인더의 경우, PG 등급에서의 고온 등급의 기준값을 만족함을 알 수 있었다. 또한 저온에서 중온 아스팔트 바인더의 인장 특성을 평가한 결과, 인장강도 향상과 함께 인장력이 증가됨을 알 수 있었다.

Negative temperature coefficient (NTC) materials have been widely studied for industrial applications, such assensors and temperature compensation devices. NTC thermistor thick films of Ni1+xMn2-xO4+δ (x=0.05, 0, −0.05) werefabricated on a glass substrate using the aerosol deposition method at room temperature. Resistance verse temperature (R-T)characteristics of the as-deposited films showed that the B constant ranged from 3900 to 4200 K between 25oC and 85oCwithout heat treatment. When the film was annealed at 600oC 1h, the resistivity of the film gradually decreased due tocrystallization and grain growth. The resistivity and the activation energy of films annealed at 600oC for 1 h were 5.203, 5.95,and 4.772KΩ·cm and 351, 326, and 299meV for Ni0.95Mn2.05O4+δ, NiMn2O4, and Ni1.05Mn1.95O4+δ, respectively. The annealingprocess induced insulating Mn2O3 in the Ni deficient Ni0.95Mn2.05O4+δ composition resulting in large resistivity and activationenergy. Meanwhile, excess Ni in Ni1.05Mn1.95O4+δ suppressed the abnormal grain growth and changed Mn3+ to Mn4+, givinglower resistivity and activation energy.

The present study was carried out to evaluate the microstructural and mechanical properties of cross-roll rolled pure copper sheets, and the results were compared with those obtained for conventionally rolled sheets. For this work, pure copper (99.99 mass%) sheets with thickness of 5 mm were prepared as the starting material. The sheets were cold rolled to 90% thickness reduction and subsequently annealed at 400˚C for 30 min. Also, to analyze the grain boundary character distributions (GBCDs) on the materials, the electron back-scattered diffraction (EBSD) technique was introduced. The resulting cold-rolled and annealed sheets had considerably finer grains than the initial sheets with an average size of 100 μM. In particular, the average grain size became smaller by cross-roll rolling (6.5 μM) than by conventional rolling (9.8 μM). These grain refinements directly led to enhanced mechanical properties such as Vickers micro-hardness and tensile strength, and thus the values showed greater increases upon cross-roll rolling process than after conventional rolling. Furthermore, the texture development of<112>//ND in the cross-roll rolling processed material provided greater enhancement of mechanical properties relative to the case of the conventional rolling processed material. In the present study, we systematically discuss the enhancement of mechanical properties in terms of grain refinement and texture distribution developed by the different rolling processes.

The electro-deposition of compound semiconductors has been attracting more attention because of its ability torapidly deposit nanostructured materials and thin films with controlled morphology, dimensions, and crystallinity in a cost-effective manner (1). In particular, low band-gap A2B3-type chalcogenides, such as Sb2Te3 and Bi2Te3, have been extensivelystudied because of their potential applications in thermoelectric power generator and cooler and phase change memory.Thermoelectric SbxTey films were potentiostatically electrodeposited in aqueous nitric acid electrolyte solutions containingdifferent ratios of TeO2 to Sb2O3. The stoichiometric SbxTey films were obtained at an applied voltage of −0.15V vs. SCE usinga solution consisting of 2.4mM TeO2, 0.8mM Sb2O3, 33mM tartaric acid, and 1M HNO3. The stoichiometric SbxTey filmshad the rhombohedral structure with a preferred orientation along the [015] direction. The films featured hole concentrationand mobility of 5.8×1018/cm3 and 54.8cm2/V·s, respectively. More negative applied potential yielded more Sb content in thedeposited SbxTey films. In addition, the hole concentration and mobility decreased with more negative deposition potential andfinally showed insulating property, possibly due to more defect formation. The Seebeck coefficient of as-deposited Sb2Te3 thinfilm deposited at −0.15V vs. SCE at room temperature was approximately 118µV/K at room temperature, which is similarto bulk counterparts.

In case of general concrete, autogenous shrinkage is about 10% of the drying shrinkage. Therefore it was not considered significant to be a subject matter about managing the crack control and design. It was reported that cracks can be generated from the autogenous shrinkage. Because of the low W/B rate and the high unit binder of the high strength concrete. In this study, autogenous shrinkage and drying shrinkage are examined which is the main reason of the cracks of the high strength concrete based on the previous studies. Comparing the data from this study and previous studies, we developed the shrinkage reduced concrete using shrinkage reducing agent. The purpose of this study is to provide the data for reducing and managing the column shortening of the high strength concrete structures.

고온 무가습 조건에서 고분자 전해질 막의 수화성 및 수소이온 전도도 향상을 위해 sulfonated poly(aryl ether sulfone) 전해질 고분자에 sulfated ZrO2 (s-ZrO2)를 함침시킨 유-무기 복합막을 제조하였다. X-ray diffraction를 통해 s-ZrO2 의 구조적 특징과 입자크기를 확인하였으며 추가적으로 FT-IR 분석을 통해, s-ZrO2입자에 술폰산기가 화학적으로 결합되어 있음을 확인 할 수 있었다. 다양한 s-ZrO2 조성비를 가진 유-무기 복합막의 이점을 확인하기 위해서 이온교환능력, 함수율, 수소이온 전도도를 측정하였다. 실험결과, s-ZrO2의 조성비를 달리한 유-무기 복합막의 수소이온 전도도는, 5 wt% s-ZrO2를 함유한 유-무기 복합막의 경우에서, 상온 수화조건 뿐만 아니라 100℃ 이상의 무가습 조건에서 매우 높은 수소 이온 전도도를 나타내었다. 특히 120℃ 무가습 조건에서도 5 wt% s-ZrO2를 함유한 유-무기 복합막이 0.0018 S cm -1의 매우 높은 전도도를 나타냄으로써 100℃ 이상의 고온에서도 높은 수화도를 유지하는 유-무기 복합막의 제조가 가능하였다.