This study investigated the effects of revolution speed and ball size in planetary milling on the microstructure and dehydrogenation behavior of TiH2 powder. The particle size analysis showed that the large particles present in the raw powder were effectively refined as the revolution speed increased, and when milled at 500 rpm, the median particle size was 1.47 μm. Milling with a mixture of balls of two or three sizes was more effective in refining the raw powder than milling with balls of a single size. A mixture of 3 mm and 5 mm diameter balls was the optimal condition for particle refinement, and the measured median particle size was 0.71 μm. The dependence of particle size on revolution speed and ball size was explained by changes in input energy and the number of contact points of the balls. In the milled powder, the endothermic peak measured using differential thermal analysis was observed at a relatively low temperature. This finding was interpreted as the activation of a dehydrogenation reaction, mainly due to the increase in the specific surface area and the concentration of lattice defects.

PURPOSES : Carbon dioxide (CO2) is a cheaper and easier to installer fire suppressant than other extinguishing gases and is easy to install, but extinguishes fires by is suffocation. As a result, suffocation accidents continue to occur in facilities equipped with CO2 fire-extinguishing facilities, Emission standards have yet to be established. This study aims to address the issue. METHODS : To effectively remove CO2 emitted from installed systems, we reviewed and analyzed previous related research and existing international standards. RESULTS : In protected areas where CO2 fire-extinguishing systems are installed, emission facilities should discharge the emitted CO2 before it enters the protected spaces. CO2 sensors can determine whether safe entry is possible or whether respirators are required. CONCLUSIONS : This study presented a specific installation method for emission facilities capable of actively discharging CO2. Applying this method is expected to contribute to improving safety in facilities equipped with CO2 fire-extinguishing facilities.

본 실험에서는 외인성 효소 첨가제 및 혼합 세균 배양을 통한 고상발효(Solid-state fermentation, SSF)가 채종박(Rapeseed meal, RSM)의 체외건물소화율(In vitro dry matter digestibility, IVDMD) 및 단쇄지방산(Short chain fatty acid) 생성에 미치는 영향을 조사하기 위해 수행되었다. 외인성 효소 칵테일(첨가 및 미첨가) 및 RSM에 대한 SSF(발효 및 비발효)를 나타내는 2 x 2 요인 설계가 적용되었다. 3-step 돼지 소화율 모델을 적용하여 채종박의 건물 소화율을 분석하였으며, 72시간 대장발효 후 상층액을 수집하여 단쇄지방산 생성량을 분석한 후 칼로리 단위로 변환하여 가소화에너지 소화율을 분석하였다. 소장 (IVDMDh) 및 전장 (IVDMDt) 건물소화율에서는 고상발효된 채종박이 더 높게 나타났다 (각각 p < 0.01). 마찬가지로, 외인성 효소 첨가제 처리구에서 채종박의 소장 소화율(IVDMDh)이 증가하는 경향을 나타냈다(p = 0.06). Acetic acid 및 butyric acid의 생산은 대조구에 비해 고상발효 처리 시 유의하게 더 생산되었으며 (각각 p < 0.01), 이는 총 단쇄지방산의 생산 증가 경향을 나타냈다(p = 0.09). 에너지 소화율에서는 채종박의 고상발효 및 외인성 효소제 첨가가 유의적으로 높게 나타났다 ( p < 0.01). 그러므로 채종박의 고상발효 처리는 단백질 이용성을 비롯한 영양적 가치를 향상시키는데 효과적이라고 사료된다.

본 연구에서는 산화 방지 특성이 있는 가리워진 아민기를 함유한 산화 그래핀(hindered amine grafted graphene oxide, HA-GO)을 합성하여 이를 도입한 나피온(Nafion) 기반의 복합 막을 제조한 후 고분자 전해질 막 연료전지 시스템에 응용하였다. HA-GO는 4-아미노-2, 2, 6, 6-테트라메틸-4-피페리딘(4-amino-2, 2, 6, 6-tetramethyl piperidine)에 존재하는 아민 기와 GO 표면에 존재하는 에폭시기의 개환 반응을 통해 제조하였으며, 합성된 HA-GO의 함량을 달리한 복합 막을 제조하여 순수 Nafion 막과 성능 특성을 비교하였다. HA-GO가 첨가된 복합 막은 Nafion 단일 막에 비해 기계적 물성, 화학적 안정성 및 수소이온 전도 특성이 향상되었다. 특히 HA-GO의 산화 방지 특성으로 인해 HA-GO가 첨가된 복합 막은 펜톤 평가 (Fenton’s test) 이후 수소이온 전도도의 유지 특성이 Nafion 단일 막에 비해 큰 폭으로 향상된 것을 확인할 수 있었다.

Combat-armored vehicles were equipped with an automatic-fire-extinguishing system to ensure the safety of the crew and vehicle from fires on the vehicle. When a fire was occurred, the automatic-fire-extinguishing system automatically detects the fire through sensors and detection lines, sprays a fire extinguisher, and notifies the crew visually and audibly. Recently, there had been cases of automatic-fire-extinguishing systems malfunction on combat-armored vehicles. In this study, in order to resolve the automatic-fire-extinguisher's malfunction phenomenon, ground noise and inter-circuit noise generated from the fire detection line were identified, and the resistance connected on the circuit was revised to remove noise. As a result of resistance revision, the noises was eliminated and the electromotive force difference between input circuits was made constant, thereby improving the malfunction of the automatic-fire-extinguishing system. By applying the result, it was confirmed that the control device sensed a temperature similar to the actual temperature on actual vehicles, and it was confirmed that the automatic-fire-extinguishing system's malfunction phenomenon was not founded in the field vehicles after then.

Changes in contents of free sugars, amino acids, and fatty acids of legumes were analyzed for each phase of in vitro digestion. In addition, contents of resistant starch in raw and digested pulses were compared. Soybeans, kidney beans, cowpeas, and chickpeas were analyzed. An in vitro digestion model was used to analyze contents of nutrients using LC-MS and GC-MS. Stachyose in kidneybean, cowpea, and chickpea increased as the digestion phase progressed. In four types of legumes, raffinose slightly decreased or showed no significant difference between the Oral phase and the BBMV phase. Content of glucose, a monosaccharide, increased during the BBMV phase. During the digestion phase, levels of free amino acids and free fatty acids also increased. Content of resistant starch was reduced compared to that in the raw material. It was 0.01g/100 g food in soybean, 1.06 g/100 g food in red kidney bean, 0.77g/ 100g food in cowpea, and 0.76 g/100 g food in chickpea. It was confirmed that nutrients in the in vitro digestion model were liberated at each digestion phase with changes in the content of resistant starch. These results are expected to be used as fundamental data for obtaining bioavailability of nutrients.

Bioreactors are devices used by sewage treatment plants to process sewage and which produce active sludge, and sediments separated by solid-liquid are treated in anaerobic digestion tanks. In anaerobic digestion tanks, the volume of active sludge deposits is reduced and biogas is produced. After dehydrating the digestive sludge generated after anaerobic digestion, anaerobic digested wastewater, which features a high concentration of organic matters, is generated. In this study, the decomposition of organic carbon and nitrogen was studied by advanced oxidation process. Ozone-microbubble flotation process was used for oxidation pretreatment. During ozonation, the TOC decreased by 11.6%. After ozone treatment, the TOC decreased and the removal rate reached 80.4% as a result of the Ultra Violet-Advanced Oxidation Process (UV-AOP). The results with regard to organic substances before and after treatment differed depending on the organic carbon index, such as CODMn, CODCr, and TOC. Those indexes did not change significantly in ozone treatment, but decreased significantly after the UV-AOP process as the linkage treatment, and were removed by up to 39.1%, 15.2%, and 80.4%, respectively. It was confirmed that biodegradability was improved according to the ratio of CODMn to TOC. As for the nitrogen component, the ammonia nitrogen component showed a level of 3.2×102 mg/L or more, and the content was maintained at 80% even after treatment. Since most of the contaminants are removed from the treated water and its transparency is high, this water can be utilized as a resource that contains high concentrations of nitrogen.

본 연구는 과체중과 정상체중의 비글견 사이에서 미네랄 소화율의 차이를 평가하기 위해 수행되었다. 중성화 된 건강한 비글견 11마리(47.7개월령 ±0.14)의 Body condition score (BCS)를 기준으로 Normal BCS 그룹(BCS≤5, n=5)과 High BCS 그룹(BCS ≥6, n=6)의 두 그룹에 배치하였다. 시험사료는 반려견의 영양소 요구량을 충족하도록 제조하여 개체 별 에너지요구량에 맞춰 일일 2회에 나누어 14일 동안 급여하였다. 미네랄의 외관상 전장 소화율은 0.5% 산화크롬(Cr2O3)을 이용한 지시제법을 이용하여 평가되었다. 사료와 분변 내 Macro 미네랄(K, Mg, P, Na, Ca)과 Micro 미네랄(Se, Fe, Zn, Cu, Mn)의 함량은 유도결합플라즈마 분광광도계를 이용하여 분석하였다. 체중과 BCS는 Normal BCS 그룹 보다 High BCS 그룹이 유의하게 높았으며(p<0.01), 시험기간 동안 두 그룹 내 각각의 체중과 BCS는 통계적으로 유의한 변화는 관찰되지 않았다(p>0.05). 미네랄 소화율을 평가한 결과, Macro 미네랄 중에서는 마그네슘, 인, 칼슘의 소화율이 High BCS 그룹에서 높은 경향으로 관찰되었으며(p<0.1), Micro 미네랄 중에서는 High BCS 그룹에서 망간의 소화율이 유의하게 높았고(p<0.05), 셀레늄과 아연의 소화율은 높은 경향(p<0.1)을 나타내었다. 또한, 통계적인 유의성과 관계없이 분석한 모든 미네랄 지표에서 High BCS 그룹이 Normal BCS 그룹보다 높은 소화율의 결과를 보여 주었다. 본 연구의 결과는 비글견에서 과체중 또는 비만이 미네랄 소화율의 변화를 유도할 잠재적 가능성을 보여주었다.

This study established the optimal conditions of noodles by varying the amount of modified starch treated with octenyl succinic anhydride in wheat starch. It investigated the digestibility and quality characteristics of the produced noodles. The color difference of the noodles added with octenyl-succinic anhydride (OSA)-modified starch increased as the amount of OSA-modified starch added increased but decreased after cooking. The cooking characteristics of noodles added with OSA-modified starch showed increased weight, water absorption, and turbidity but reduced volume. In the extensibility of noodles, the noodles with 10 and 20% OSA-modified starch showed the most similar values to the control. The digestibility of noodles with OSA-modified starch added showed a higher RS content as the amount of OSA-modified starch added increased. However, it is considered that an optimal addition level of 20% of modified starch is suitable for the formation of noodle texture. As a result of this study, it is thought that OSA-modified starch, with its low digestibility, could be utilized not only in noodles but also as a low-calorie food ingredient that can replace wheat flour.

본 연구는 위장 단계의 소화과정에 관여하는 Gastric lipase (GL)를 반려견을 위한 정적 체외 소화모델(Static in vitro digestion model)에 적용을 검토하기 위하여 실시되었다. GL의 첨가가 체외 소화과정 동안 건물(Dry matter; DM), 조단백질(Crude protein; CP) 그리고 조지방(Ether extracts; EE) 소화율에 미치는 영향을 평가하였다. GL은 위장 소화단계에서 첨가되었다. 위장(39℃, 2 hr.)과 소장(39℃, 4 hr.) 소화 후에 비소화 분획을 분리하였다. 그리고 실험사료와 분리된 비소화 분획에서 DM, CP 그리고 EE 수준을 측정하고 각각의 소화율을 계산하였다. 위장과 소장 소화단계에서 측정된 DM, CP 그리고 EE 소화율은 Control과 GL 그룹 사이에서 통계적으로 유의한 차이는 관찰되지 않았다(p>0.05). 결과적으로 우리의 체외 소화모델에서 GL의 첨가는 DM, CP 그리고 EE의 소화율에는 영향을 미치지 않는 것으로 나타났다. 따라서 이와 같은 결과는 정적 체외 소화모델을 이용한 소화율의 평가에 있어서 GL의 역할은 다소 제한적일 수 있다는 것을 시사한다.

본 연구는 소맥 위주 사료에 xylanase 효소제의 첨가가 육성돈의 사양성적, 영양소 소화율, 혈액성상, 분 중 휘발 성 지방산 및 암모니아성 질소 농도에 미치는 영향을 알 아보기 위하여 실시하였다. 총 192두(4처리, 8반복, 반복당 6두)의 육성돈(25.14±0.11 kg)을 공시하여 xylanase 첨가수 준(0, 0.0125, 0.025, 0.0375%)으로 6주간 사양시험을 실시 하였다. xylanase의 첨가수준이 증가함에 따라 전체 사양 구간에서의 일당증체량(ADG), 일일사료섭취량(ADFI) 및 사료요구율(FCR)이 유의적으로 개선되는 효과를 나타냈 다(p<005). 영양소 소화율에 있어서, xylanase 첨가수준이 증가함에 따라 phase Ⅰ에서는 건물 및 에너지, phase Ⅱ 에서는 조단백질 소화율이 유의적으로 개선되었으며, 또 한 육성돈의 혈중 GLU 농도는 사료 내 xylanase의 첨가 수준이 증가함에 따라 유의적으로 증가하는 효과를 보였 다(p<0.05). 반면에, 휘발성 지방산 및 암모니아성 질소 농 도에서 xylanase의 유의적인 첨가효과는 나타나지 않았다 (p>0.05). 결론적으로, 소맥 위주의 사료 내 xylanase의 첨 가는 육성돈의 사양성적, 영양소 소화율 및 혈중 GLU 농 도를 증가시키는데 긍정적인 효과를 보였으며, 육성돈 사 료내 소맥을 주원료로 사용할 경우 xylanse의 적정 첨가 수준은 0.0375%으로 사료된다.

This study aims to measure sedimentation status change with the changes in internal pressure for dry chemical extinguishers of various use periods and analyze the suitability of the fire extinguishers' performance criteria. When the internal pressure of the fire extinguisher is 0%, 2 out of 10 new dry chemical powders for the 5 elapsed years were noted to be suitable, including 3 recycled dry chemical powders with 5 elapsed years that were found eligible. One out of 10 new dry chemical powders for 10 elapsed years was shown as suitable. Also, one new dry chemical powder for 13 elapsed years was suitable. When the internal pressure of the fire extinguisher was 50%, all 10 out of 10 new dry chemical powders for 5 years, recycled one with 5 elapsed years, and a new one with 10 elapsed years were found to be suitable, while 9 new dry chemical powders for 13 years were shown as suitable. When the internal pressure of the fire extinguisher was normal, new ones with 5 elapsed years, recycled ones with 5 elapsed years, new ones with 10 elapsed years, and new ones with 13 elapsed years were all 10 out of 10 samples noted as suitable. In summarizing the experiment results, it was found that the sedimentation status, one of the fire extinguisher's physical properties experiments, affects the fire extinguisher's performance criteria rather than the change with use periods.

In vitro digestibility and protein digestibility corrected amino acid scores (PDCAAS) were investigated to verify the availability of protein in various Rhizopus oligosporus fermented products of domestic soybean (Glycine max L.) cultivars. Danbaegkong (DBK), Daepung (DP), Daewonkong (DWK), Saedanbaek (SDB), Seonyu (SY), and Cheongja4ho (CJ4) were used as raw samples, which were fermented using commercially available Rhizopus oligosporus for 48 h. All cultivars showed increased crude protein content after fermentation. The crude protein content of DBK and SDB was significantly higher than that of the other samples (55.12% in DBK and 54.22% in SDB) (p<0.001). CJ4 had the highest alanine content of 28.88 mg/g (p<0.001), and no significant difference in cysteine content was detected among the cultivars. In most of the fermented samples, the in vitro digestibility was 0.9 or higher, indicating high protein in the fermented samples. However, it is considered that restrictions on digestion are low. In DWK, the amino acid content and PDCAAS, which together indicate protein quality, were 0.917 and 0.855, respectively, confirming that it was the best cultivar to provide the raw material for fermentation. In conclusion Rhizopus oligosporus fermented soybean products can be considered a prospective source of protein with high utility value.

The object of this study is to feasibility assesment for co-digestion efficiency of food waste recycling wastewater(FWR) with thermal hydrolysis process dehydration cake (THP Sludge). As a result of THP pre-treatment experimental conditions to 160oC and 30 minutes, the solubility rate(conversion rate of TCOD to SCOD) of the THP sludge increased by 34%. And the bio-methane potential in the THP sludge increased by about 1.42 times from 0.230 to 0.328 m3 CH4/kg VS compared to the non-pre-treatment. The substrates of the co-digestion reactor were FWR and THP sludge at a 1:1 ratio. Whereas, only FWR was used as a substrate in the digestion reactor as a control group. The experimental conditions are 28.5 days of hydraulic retention time(HRT) and 3.5 kg VS/m3-day of organic loading rate(OLR). During the 120 days operation period, the co-digestion reactor was able to operate stably in terms of water quality and methane production, but the FWR digestion reactor deteriorated after 90 days, and methane production decreased to 0.233 m3 CH4/kg VS, which is 67% of normal condition. After 120 days of the experiment, organic loading rate(OLR) of co-digestion reactor was gradually increased to 4.5 kg VS/m3-day and operated for 80 days. Methane production during 80 days was evaluated to be good at the level of 0.349 m3 CH4/kg VS. As a result of evaluating the dehydration efficiency of the sludge before/after 150-180oC THP using a filter press, it was confirmed that the moisture content of the sludge treated before THP at 180oC was 75% and improved by 8% from 83-85% level. Therefore, it is expected that the co-digestion reactor of FWR and THP sludge will ensure stable treatment water quality and increase bio-methane production and reduction effect of dehydration sludge volume.

본 연구는 사일리지 발효제 첨가가 볏짚 사일리지에서 곰팡이 독소 및 in situ 섬유소 소화율에 미치는 영향을 평가하고자 실시 하였다. 사일리지 발효제로 L. plantarum 단일제 및 L. plantarum 과 S. cerevisiae의 혼합제를 첨가하였을 때 사일리지의 발효 및 섬유소 분해에 영향을 주었을 뿐만 아니라 곰팡이독소 감소에도 영향을 주었다. 시험 시료에서 곰팡이독소 중 ochratoxin A 및 zearalenone만 발견되었다. Ochratoxin A 및 zearalenone는 대조구에서 각각 38.11±2.22 및 633.67±50.30 ug/kg 수준으로 발효제 첨가로 감소 경향이 나타났고, 혼합제에서만 각각 27.78±2.28 및 392.72± 25.04 ug/kg 수준으로 유의적 차이를 보였다(p<0.05). pH는 대조 구에 비하여 단일제 및 혼합제에서 낮았고(p<0.05), lactic acid는 대조구(8.18±0.93 mM)에 비하여 단일제(11.73±0.31 mM)가 높았고, 혼합제(16.01±0.88 mM)에서 가장 높은 수준을 나타내었다 (p<0.05). Acetic acid와 propionic acid는 발효제 첨가에 따라 유 의적으로 낮아짐을 발견하였다(p<0.05). 그리고 total VFA도 발 효제 첨가가 대조구에 비하여 낮았다(p<0.05). NDF 및 ADF의 반추위 in situ 분해율은 배양기간 동안 혼합제가 가장 높은 수준 의 분해율을 유지하였고, 다음으로 단일제가 높았으며, 대조구가 가장 낮은 수준을 유지하였다. 그리고 이들 NDF 및 ADF 분해율 은 각각 배양 12 및 24시간 이후 모든 시간대에서 실험구간 유의 차를 나타내었다(p<0.05). 이상의 연구 결과는 볏짚 사일리지 제조에서 사일리지 발효제 사용은 발효 및 섬유소 분해에 영향을 주었을 뿐만 아니라 곰팡 이독소 감소에도 영향을 주었다. 그리고 곰팡이독소 감소는 L. plantarum 단일제보다 L. plantarum과 S. cerevisiae 혼합제의 효능이 더 크게 나타났다. 따라서 사일리지 조제를 위한 발효제로 L. plantarum과 L. plantarum 첨가제의 사용은 사일리지의 품질 과 안정성을 더 증진할 것으로 사료 된다.