Hexagonal bolt, nut, fittings, and high-pressure valves with special alloy play an important role in many industrial products, for instance, such as semiconductor facilities, hydrogen stations and fuel cell electric vehicles. The purpose of this study is to investigate the structural stability of turning wheel using the reaction force of roller in variable hexagonal rolling die. As the results, the bearing groove had the possibility of damage in turning wheel, especially, in case of Bottom condition. Furthermore, the turning wheel showed structural instability by using safety factor but structural stability using strength, respectively, as a safety criterion.

Iron oxide (Fe2O3) nanoclusters exhibit significant potential in the biomedical and pharmaceutical fields due to their strong magnetic properties, stability in solutions, and compatibility with living systems. They excel in magnetic separation processes, displaying high responsiveness to external magnetic fields. In contrast to conventional Fe2O3 nanoparticles that can aggregate in aqueous solutions due to their ferrimagnetic properties, these nanoclusters, composed of multiple nanoparticles, maintain their magnetic traits even when scaled to hundreds of nanometers. In this study, we develop a simple method using solvothermal synthesis to precisely control the size of nanoclusters. By adjusting precursor materials and reducing agents, we successfully control the particle sizes within the range of 90 to 420 nm. Our study not only enhances the understanding of nanocluster creation but also offers ways to improve their properties for applications such as magnetic separation. This is supported by our experimental results highlighting their size-dependent magnetic response in water. This study has the potential to advance both the knowledge and practical utilization of Fe2O3 nanoclusters in various applications.

Hexagonal bolt, nut, fittings, and high-pressure valves with special alloy play an important role in many industrial products, for instance, such as semiconductor facilities, hydrogen stations and fuel cell electric vehicles. The purpose of this study is to predict the reaction force of roller in drawing system. Numerical analysis was conducted to obtain data for designing the turning wheel, which is key parts in drawing system, using the reaction force of roller. As the results, the reaction force of X axis direction was about 9~20 times larger than that of Z axis direction and the reaction force of Y axis direction was negligible. The maximum reaction force of roller was the case of 4 stage and the numerical results in this study could be helped for designing the mechanical parts of variable hexagonal rolling die.

We used the measurement data derived from a proton transfer reaction time-offlight mass spectrometry (PTR-ToF-MS) to ascertain the source profile of volatile organic compounds (VOCs) from 4 major industrial classifications which showed the highest emissions from a total of 26 industrial classifications of A industrial complex. Methanol (MOH) was indicated as the highest VOC in the industrial classification of fabricated metal manufacture, and it was followed by dichloromethane (DM), ethanol (EN) and acetaldehyde (AAE). In the industrial classification of printing and recording media, the emission of ethylacetate (EA) and toluene (TOL) were the highest, and were followed by acetone (ACT), ethanol (EN) and acetic acid (AA). TOL, MOH, 2-butanol (MEK) and AAE were measured at high concentrations in the classification of rubber and plastic manufacture. In the classification of sewage, wastewater and manure treatment, TOL was the highest, and it was followed by MOH, H2S, and ethylbenzene (EBZ). In future studies, the source profiles for various industrial classifications which can provide scientific evidence must be completed, and then specified mitigation plans of VOCs for each industrial classification should be established.

The development of heteroatoms doped inorganic nanocrystal-carbon composites (INCCs) has attained a great focus for energy applications (energy production and energy storage). A precise approach to fabricate the INCCs with homogenous distribution of the heteroatoms with an appropriate distribution of metal atoms remains a challenge for material scientists. Herein, we proposed a facile two-step route to synthesize INCC with doping of metal (α-Fe2O3) and non-metals (N, P, O) using hydrogel formed by treating hexachlorocyclotriphosphazene (HCCP) and 3, 4, 5-trihydroxy benzoic acid (Gallic acid). Metal oxide was doped using an extrinsic doping approach by varying its content and non-metallic doping by an intrinsic doping approach. We have fabricated four different samples (INCC-0.5%, INCC-1.0%, INCC-1.5%, and INCC-2.0%), which exhibit the uniform distribution of the N, P, O, and α-Fe2O3 in the carbon architecture. These composite materials were applied as anode material in water oxidation catalysis (WOC); INCC-1.5% electro-catalyst confirmed by cyclic voltammetry (CV) with a noticeable catholic peak 0.85 V vs RHE and maximal current density 1.5 mA.cm−2. It also delivers better methanol tolerance and elongated stability than RuO2; this superior performance was attributed due to the homogenous distribution of the α-Fe2O3 causing in promotion of adsorption of O2 initially and a greater surface area of 1352.8 m2/ g with hierarchical pore size distribution resulting higher rate of ion transportation and mass-flux.

Instead of using expensive platinum, carbon anodes could potentially be utilized in the process of reducing oxides in LiCl-Li2O molten salt at a high cell potential. However, this high potential leads to the generation of a mixture of anodic gases containing toxic and corrosive gases such as chlorine (Cl2), oxygen (O2), carbon monoxide (CO), and carbon dioxide (CO2). To better understand this gas mixture, we conducted real-time analyses of the gases generated on the carbon anode during the TiO reduction reaction in the molten salt at 650°C, using a MAX-300-LG gas analyzer. Our results indicate that the ratio of CO/O2/CO2/Cl2 in the gas mixture is significantly influenced by the composition of the salt, and that removing the sources of oxygen ions in the salt increases the likelihood of generating toxic and corrosive Cl2 gas.

Transition metal oxides formed by a single or heterogeneous combination of transition metal ions and oxygen ions have various types of crystal structures, which can be classified as layered structures and non-layered structures. With non-layered structures, it is difficult to realize a two-dimensional structure using conventional synthesis methods. In this study, we report the synthesis of cobalt oxide into wafer-scale nanosheets using a surfactant-assisted method. A monolayer of ionized surfactant at the water-air interface acts as a flexible template for direct cobalt oxide crystallization below. The nanosheets synthesized on the water surface can be easily transferred to an arbitrary substrate. In addition, the synthesizing morphological and crystal structures of the nanosheets were analyzed according to the reaction temperatures. The electrochemical properties of the synthesized nanosheets were also measured at each temperature. The nanosheets synthesized at 70 °C exhibited higher catalytic properties for the oxygen evolution reaction than those synthesized at other temperatures. This work suggests the possibility of changing material performance by adjusting synthesis temperature when synthesizing 2D nanomaterials using a wide range of functional oxides, resulting in improved physical properties.

Liquid metal extraction (LME), a pyrometallurgical recycling method, is popular owing to its negligible environmental impact. LME mainly targets rare-earth permanent magnets having several rare-earth elements. Mg is used as a solvent metal for LME because of its selective and eminent reactivity with rare-earth elements in magnets. Several studies concerning the formation of Dy-Fe intermetallic compounds and their effects on LME using Mg exist. However, methods for reducing these compounds are unavailable. Fe reacts more strongly with B than with Dy; B addition can be a reducing method for Dy-Fe intermetallic compounds owing to the formation of Fe2B, which takes Fe from Dy-Fe intermetallic compounds. The FeB alloy is an adequate additive for the decomposition of Fe2B. To accomplish the former process, Mg must convey B to a permanent magnet during the decomposition of the FeB alloy. Here, the effect of Mg on the transfer of B from FeB to permanent magnet is observed through microstructural and phase analyses. Through microstructural and phase analysis, it is confirmed that FeB is converted to Fe2B upon B transfer, owing to Mg. Finally, the transfer effect of Mg is confirmed, and the possibility of reducing Dy-Fe intermetallic compounds during LME is suggested.

Carbon dots (CDs) were synthesized from phloroglucinol (PG) by simple heat treatment at 220–230 °C in the atmosphere without catalysts and solvents. PG-CDs heated at 220–230 °C could be completely dissolved in environmentally friendly water and exhibited a photoluminescence (PL) peak at 485 nm with 85 nm of the full width at half maximum (FWHM). The water-soluble polymer-dot-like PG-CDs were estimated to be 1.6–3.2 nm in size, and exhibited a wide range of PL wavelength at 370–630 nm. Since the PG-CDs are water-soluble materials, PG-CDs could be homogeneously mixed with a polymer such as polyvinylpyrrolidone (PVP) in water as a solvent, and PG-CDs/PVP films were prepared. The films exhibited PL characteristics that convert ultraviolet light at 350 nm to visible light above 400 nm. Thus, using PG as the raw material which has widely been produced industrially, the water-soluble fluorescent PG-CDs/PVP films could be prepared at a low cost by environmentally friendly methods.

Carbon dots (CDs) with tunable fluorescence emissions have been developed from a wide range of small organic molecules with various bottom-up syntheses. However, most of them were prepared under high temperatures and high pressures with long reaction times and tedious purification processes. In addition, previously reported carbon dots frequently displayed excitation-dependent emissions, which restrict their further applications. Herein, we present a simple and rapid microwaveassisted solvothermal synthesis of multicolour carbon dots with excitation-independent emissions. In ethylene glycol, the green (G)-CDs emitting at 537 nm with a quantum efficiency (QY) of 15% were obtained by using a single precursor of phloroglucinol, and blue (B)- and yellow (Y)-CDs emitting at 436 nm and 557 nm with QYs of 55% and 28% were derived with additives of o- and m-phenylenediamine, respectively. Analyses of their chemical structures and optical processes suggest that highly polymeric carbon dots were uniformly formed from the small molecules and their fluorescences were predominantly originated from rapid direct recombination. Furthermore, emissions at different wavelengths were mainly attributed to different degrees of oxidation (13.9%, 15.2% and 16.4% oxygen in B-, G- and Y-CDs, respectively) and different proportions of pyrrolic nitrogen (10.4% and 1.40% in B- and Y-CDs, respectively). To demonstrate the application feasibility, the obtained carbon dots were utilized for ion detection and anti-counterfeiting. Based on static quenching of the carbon dots’ fluorescence, micro amounts of ferric ion in water samples were detected selectively and reproducibly. Moreover, the anti-counterfeiting pattern constructed by the carbon dots emitted fluorescence under ultraviolet illumination, but concealed perfectly under daylight. This achievement is of great potential for developing multicolour carbon dots of high qualities.

In this paper, we presented a hybrid composite of graphene quantum dots (GQDs)-modified three-dimensional graphene nanoribbons (3D GNRs) composite linked by Fe3O4 and CoO nanoparticles through reflux and ultrasonic treatment with GQDs, denoted as 3D GQDs-Fe3O4/CoO@GNRs (3D GFCG). In this hybrid, the 3D GNRs framework strengthened the electrical conductivity and the synergistic effects between GQDs and 3D GFCG enhanced the oxygen reduction reaction (ORR) activity of the nanocomposite. The results imply that decorating GQDs with other electro-catalysts is an effective strategy to synergistically improve their ORR activity.

Considering the non-linear behavior of structure and soil when evaluating a nuclear power plant's seismic safety under a beyond-design basis earthquake is essential. In order to obtain the nonlinear response of a nuclear power plant structure, a time-domain SSI analysis method that considers the nonlinearity of soil and structure and the nonlinear Soil-Structure Interaction (SSI) effect is necessary. The Boundary Reaction Method (BRM) is a time-domain SSI analysis method. The BRM can be applied effectively with a Perfectly Matched Layer (PML), which is an effective energy absorbing boundary condition. The BRM has a characteristic that the magnitude of the response in far-field soil increases as the boundary interface of the effective seismic load moves outward. In addition, the PML has poor absorption performance of low-frequency waves. For this reason, the accuracy of the low-frequency response may be degraded when analyzing the combination of the BRM and the PML. In this study, the accuracy of the analysis response was improved by adjusting the PML input parameters to improve this problem. The accuracy of the response was evaluated by using the analysis response using KIESSI-3D, a frequency domain SSI analysis program, as a reference solution. As a result of the analysis applying the optimal PML parameter, the average error rate of the acceleration response spectrum for 9 degrees of freedom of the structure was 3.40%, which was highly similar to the reference result. In addition, time-domain nonlinear SSI analysis was performed with the soil's nonlinearity to show this study's applicability. As a result of nonlinear SSI analysis, plastic deformation was concentrated in the soil around the foundation. The analysis results found that the analysis method combining BRM and PML can be effectively applied to the seismic response analysis of nuclear power plant structures.

The oxygen evolution reaction (OER) is very sluggish compared to the hydrogen evolution reaction (HER). Considering this difference is essential when designing and developing a cost-effective and facile synthesis method for a catalyst that can effectively perform OER activity. The material should possess a high surface area and more active sites. Considering these points, in this work we successfully synthesized sheets of cobalt phosphate hydrate (CP) and sulphurated cobalt phosphate hydrate (CPS) material, using simple successive ionic layered adsorption and reaction (SILAR) methods followed by sulfurization. The CP and CPS electrodes exhibited overpotentials of 279 mV with a Tafel slope of 212 mV dec1 and 381 mV with a Tafel slope of 212 mV dec1, respectively. The superior performance after sulfurization is attributed to the intrinsic activity of the deposited well-aligned nanosheet structures, which provided a substantial number of electrochemically active surface sites, speeded electron transfer, and at the same time improved the diffusion of the electrolyte.

Environmental issues such as global warming due to fossil fuel use are now major worldwide concerns, and interest in renewable and clean energy is growing. Of the various types of renewable energy, green hydrogen energy has recently attracted attention because of its eco-friendly and high-energy density. Electrochemical water splitting is considered a pollution-free means of producing clean hydrogen and oxygen and in large quantities. The development of non-noble electrocatalysts with low cost and high performance in water splitting has also attracted considerable attention. In this study, we successfully synthesized a NiCo2O4/NF electrode for an oxygen evolution reaction in alkaline water splitting using a hydrothermal method, which was followed by post-heat treatment. The effects of heat treatment on the electrochemical performance of the electrodes were evaluated under different heat-treatment conditions. The optimized NCO/NF-300 electrode showed an overpotential of 416 mV at a high current density of 50 mA/cm2 and a low Tafel slope (49.06 mV dec-1). It also showed excellent stability (due to the large surface area) and the lowest charge transfer resistance (12.59 Ω). The results suggested that our noble-metal free electrodes have great potential for use in developing alkaline electrolysis systems.

Interests in molten salt reactor (MSR) using a fast spectrum (FS) have been increased not only for having a high power density but for burning the high-level waste generated from nuclear power plants. For developing the FS-MSR technologies, chloride-based fuels are considered due to the advantage of higher solubility of actinides and lanthanides over fluoride-based salts. Despite significant progress in development of MSR technology, the manufacturing technology for production of the fuel is still insufficiently understood. One of the option to prepare the MSR fuel is to use products from pyroprocessing where oxide form of spent nuclear fuel is reduced into metal form and useful elements can be collected via electrochemical methods in molten salt system at high temperature. In order to chlorinate the products into chloride form, previous study used NH4Cl to chlorinate U metal into UCl3 in an airtight reactor. It was found that the U metal was completely chlorinated into chloride forms; however, impurities generated by the reaction of NH4Cl and reactor wall were found in the product. Therefore, in this work, the air tight reactor was re-deigned to avoid the reaction of reactor wall by insertion of Al2O3 crucible inside of the reactor. In addition, the reactor size was increased to produce UCl3 over 100 g. Using the newly designed reactor, U metal chlorination experiments using NH4Cl chlorinating agent were performed to confirm the optimal experimental conditions. The detailed results will be further discussed.

This study investigated the influence of sodium bicarbonate (NaHCO3) and progesterone on acrosome reaction and proportion of polyunsaturated fatty acid (PUFA) composition boar sperm. The sperm were diluted with semen extender and incubated with NaHCO3 and progesterone at 38℃, 5% CO2 for 6 h. Plasma membrane integrity and acrosome reaction were analyzed using SYBR14/propidium iodide (PI) and FITC-PNA/PI doubling staining method, and proportion of PUFA was analyzed using gas chromatography. In results, Plasma membrane integrity was significantly decreased in 50 mM NaHCO3 group and acrosome reaction was significantly increased by over the 100 mM NaHCO3 group compared to control group (p < 0.05). In addition, progesterone significantly increased decreased plasma membrane integrity at 100 mM progesterone and acrosome reaction at over the 5.0 µM progesterone (p < 0.05), but there was no difference among the 5.0 to 100 µM groups. PUFAs were significantly decreased in 100 mM NaHCO3 and 50 µM progesterone treatments compared to control group. In summary NaHCO3 and progesterone induce acrosome reaction and reduce PUFA composition in boar sperm, therefore, the results maybe help to understand basically knowledge for the acrosome reaction and PUFA composition in boar sperm.

Streaming media is an emerging mode of video playback. It compress a series of multimedia data and transmit the data in real time through the Internet. And It has become an important part of people's daily entertainment and leisure. These streaming media platforms(Including OTT platforms) are full of enormous Intellectual Property(IP). Although there are some original IP, most of them are derived from Chinese classical culture and refreshed vigorously. Owing to digitalization, paper publications gradually broken the restrictions of physical forms and evolved to multiple digital forms in the world. In the thriving contemporary cultural industry, the needs for traditional classics are gradually surpassing that for the pure humanistic value, and thus the culture industry value of them are focused on. Xiyouji is the crystallization of the collective wisdom and imagination of the ancient folk, which has been active in people's daily life with various forms of popular cultural products, such as speech and opera, since the ancient time. Therefore, Xixingji is selected in to this paper as the study object, so as to discuss how the original work is effectively untilized in Xixingji to create the magnificent script and storylines and how Christopher Vogler's narratological theory is adopted to analyze the storytelling and character in animation Xixingji, and also to investigate the market reaction of Xixingji in China and South Korea.

The radical reaction position was calculated by varying the calculation level for ACEL and ANT, which are detected with the highest frequency and concentration in PAHs pollution sites. The results of each calculation level were compared and evaluated with the existing literature. HF, B3LYP, B3LYP-D, and MP2 were used as the method for each level used for calculation. Except for HF, the MK charge by B3LYP, B3LYP-D, and MP2 was consistent with the experimental results. It was found that the dispersion effect was negligible in the calculation of ACEL and ANT because the calculation results by the B3LYP and B3LYP-D methods were the same. In particular, it was found that the MK charge calculation result by MP2 agrees well with the product/PAH ratio obtained as a result of the experiment. Considering the calculation cost, it would be preferable to use B3LYP to predict the radical reaction site of ACEL and ANT. However, considering the product/PAH ratio, it takes more time to calculate, but it is judged that it is better to use the MP2.

The ovary undergoes substantial physiological changes along with estrus phase to mediate negative/positive feedback to the upstream reproductive tissues and to play a role in producing a fertilizable oocyte in the developing follicles. However, the disorder of estrus cycle in female can lead to diseases, such as cystic ovary which is directly associated with decline of overall reproductive performance. In gene expression studies of ovaries, quantitative reverse transcription polymerase chain reaction (qPCR) assay has been widely applied. During this assay, although normalization of target genes against reference genes (RGs) has been indispensably conducted, the expression of RGs is also variable in each experimental condition which can result in false conclusion. Because the understanding for stable RG in porcine ovaries was still limited, we attempted to assess the stability of RGs from the pool of ten commonly used RGs (18S, B2M, PPIA, RPL4, SDHA, ACTB, GAPDH, HPRT1, YWHAZ, and TBP) in the porcine ovaries under different estrus phase (follicular and luteal phase) and cystic condition, using stable RG-finding programs (geNorm, Normfinder, and BestKeeper). The significant (p < 0.01) differences in Ct values of RGs in the porcine ovaries under different conditions were identified. In assessing the stability of RGs, three programs comprehensively agreed that TBP and YWHAZ were suitable RGs to study porcine ovaries under different conditions but ACTB and GAPDH were inappropriate RGs in this experimental condition. We hope that these results contribute to plan the experiment design in the field of reproductive physiology in pigs as reference data.