술폰화 폴리이미드는 클로로알칼리 전기분해, 양이온교환수지 및 연료전지용 고분자진해질막 등과 같은 많은 응용에 있어 유용한 재료로서 연구되어지고 있다. 그러나, 이러한 응용이 이루어지는 과정에 있어서 시간에 따라 연속적인 탈수공정이나 고분자의 분해에 따른 성능 감소 등이 보고되었다. 술폰화 고분자 분해의 주요 원인 중 하나로서 고분자 분자량의 감소 및 고분자 사슬의 절단으로 이끌어지는 가수분해를 들 수 있다. 따라서, 본 연구의 목적은 수화조건 하에서의 -SO3H와 연결된 이미드 사이클과 부가적인 에스테르 결합의 분해를 조사하는 데 있다. 사슬의 분리에 대해 가능한 정확한 정보를 얻고 이를 확인하기 위해서는 1H 및 13C NMR, FT-IR 분석을 이용했으며, 또한 보다 편리한 분석을 위해서 model compound를 사용하여 실험을 수행하였다. 결과적으로, 술폰화 폴리이미드의 수화안정성을 평가하기 위해서 프탈계 및 나프탈렌계 이미드 고리와 에스테르 결합을 갖는 model compound를 합성하였고, 제조된 model compound를 이용하여 80℃ 초순수 하에서 aging 실험을 수행하였고, lyophilization technique을 사용하여 반응을 중지시켰다. Aging된 product는 NMR, FT-IR spectroscopy를 이용하여 분석하였다.

There exists a structural problem for link structures in the unstable state. The primary characteristics of this problem are in the existence of rigid body displacements without strain, and in the possibility of the introduction of prestressing to change an unstable state into a stable state. When we make local linearized incremental equations in order to obtain knowledge about these unstable structures, the determinant of the coefficient matrices is zero, so that we face a numerically unstable situation. This is similar to the situation in the stability problem. To avoid such a difficult situation, in this paper a simple and straightforward method was presented by means of the generalized inverse for the numerical analysis of stability problem.

This study was carried on the oxidative stability and the real practice possibilities in cooking of fat replacer MCT. Nowadays, it was known that fats and oils had become causes for cardiac disease, obesity and cancer, so the new materials were needed for fat substitute that has less fat contents and low calories. The food industry concerned about fats and oils had been researched and developed new and various kinds of substitute fats. MCT(medium chain triglycerides) is one of the fat based fat substitutes used as fat replacers. The POV of com germ oil(CO), soybean oil(SO), shortening(ST), butter(BT), their blended oil with MCT 10-50%(w/w), and MCT were determined and oxidative stability by POV was compared MCT with those of them. MCT has shown higher oxidative stability than CO, SO, ST, BT, so oxidative stabilities in all kinds of blended oils become higher and higher by the increased substitution ratios. In case of bread, the volume of bread prepared with MCT(MCT bread) substituted for ST at 10-40% level(w/w) were increased a little comparing to that made of shortening(ST bread). But degree of gelatinization of MCT bread were a little lower than ST bread, at the substitute ratio above 40%, the degree of gelatinization were reduced greatly. These phenomena were sustained in 9 stored days. While baking losses of MCT breads were almost same as ST bread until 30% substitute ratio, and the appearances of MCT breads were similar to ST bread until 40% substitute ratio. Also rheological properties and color(Lab) of MCT breads had shown no different significantly from ST bread until 20% substitute ratio, but by the results of sensory evaluation, overall acceptance including appearance, color, flavor, taste, texture of MCT breads were recognized almost same as ST bread by panel until 40% substitute ratio. Depends on the above results, we can suggest that 30-40% of MCT will substitute for shortening in making bread in order to reduce fat and calories intake amounts.

Quality stability of the herb pill coated with edible oils containing rosemary was investigated. Herb pills were made of herb powders such as Panax ginseng, Cinnamomum cassia, Lycium chinense, Zyzyphus jujuba and Zingiber officinale. Rapeseed oil and lubriol were used as edible coating oil. After herb pills coated with edible oils with or without rosemary were stored at 40℃ for 180 days, the microbial viable cell counts and peroxide values(POV) of the herb pill were investigated. After 180 day storage, POVs of herb pills with only rapeseed oil or lubriol were 0.51 and 0.49 meq/kg, respectively. However, when rosemary was added in herb pills the POVs were decreased to 0.30 and 0.39 meq/kg, respectively. The addition of rosemary to the rapeseed oil and lubriol tended to decrease the microbial viable cell counts of the herb pill. The microbial viable cell counts of rapeseed oil and lubriol were 940 and 820CFU/g, respectively after 180 days of storage. However, these levels were suppressed to 720 and 640CFU/g by the resemary addition. On the other hand, the ginseng saponin content of herb pills was not affected by the rosemary addition during storage.

생 찐솔잎에 콩기름과 올리브유를 첨가하여 추출한 솔잎추출유의 저장기간에 따른 산패도를 측정하였고 솔잎추출유를 김에 발라 제조한 맛김에 대한 관능검사 결과는 다음과 같다. 1. 저장기간에 따른 중량변화 측정 결과, 콩기름은 14일째 생 찐 솔잎추출유는 21일째 생 찐 올리브유 솔잎추출유는 14일부터 중량이 서서히 증가하여 28일에 중량이 가장 크게 증가하는 것으로 나타났다. 2. TBARS 생성량도 저장기간 14일째 콩기름에 비해 콩기름에 생 찐 솔잎을 첨가할 경우 TBARS의 함량이 유의적으로 낮았고, 28일째 올리브유도 생 찐솔잎을 첨가할 경우 TBARS의 함량이 유의적으로 낮게 나타났다. 3. 지방산 산화의 2차 생성물은 aqueous layer에서 저장기간에 따라 감소하였고 특히 14일째에 다른 추출유에 비해 콩기름이 크게 감소한 것으로 나타났다. 한편 organic layer는 저장기간 14일째 콩기름에서 가장 크게 증가하였고 솔잎을 첨가할 경우 유의적으로 감소한 것으로 나타났다. 올리브유의 경우도 솔잎을 첨가한 올리브 솔잎 추출유에서 2차 생성물이 감소한 것으로 나타났다. 4. 제조된 생 찐 솔잎 추출유를 김에 발라 7점 기호척도법을 이용하여 관능검사를 실시한 결과 향, 맛 그리고 전반적인 기호도 모두 유의적인 차이가 나타나지 않아 솔잎추출유를 김에다 바를 경우 거부감을 주지 않는 것으로 조사되었다. 이상의 결과 솔잎에 콩기름과 올리브유를 첨가하여 추출한 솔잎추출유는 원유보다 산화에 대해 안정한 것으로 나타났고, 이를 이용한 맛김도 좋은 것으로 평가되어 솔잎추출유의 식품에 이용 가능성이 시사되었다.

The structural system that discreterized from continuous shells is frequently used to make a large space structures. As well these structures show the unstable phenomena when a load level over the limit load, and snap-through and bifurcation are most well known of it. For the collapse mechanism, rise-span ratio, element stiffness and load mode are main factor, which it give an effect to unstable behavior. In our real situation, most structures have semi-rigid joint that has middle characteristic between pin and rigid joint. So the knowledge of semi-rigid joint is very important problem of stable large space structure. And the instability phenemena of framed space structures show a strong non-linearity and very sensitive behavior according to the joint rigidity For this reason In this study, we are investigating to unstable problem of framed structure with semi-rigidity and to grasp the nonlinear instability behavior that make the fundamental collapse mechanism of the large space frame structures with semi-rigid joint, by proposed the numerical analysis method. Using the incremental stiffness matrix in chapter 2, we study instability of space structures.

We studied on the preparation and evaluation of O/W type microemulsion containing "wax, liquid paraffine and quaternary ammonium salt". And also it was obtained to stability of microemulsions by mono ethylene glycol(MEG) addition. The microemulsions were generally prepared at 96~97℃ by the phase inversion method. We used polyoxyethylene(20) sorbitan monooleate(POE(20)SMO) and distearyl dimethyl ammonium chloride(D.D.A.C.) as the emulsifiers at microemulsion preparation. From the results, we could get best condition for microemulsion preparation, in case of oil phase, montanic ester wax ; 1.1wt%, paraffine wax ; 1.1wt%, liquid paraffine ; 3.1wt%, propylene glycol ; 0.6wt% and ethylene glycol monobutyl ether ; 0.6wt%, when the ratio(wt%) of D.D.A.C. and POE(20)SMO were 2 : 3. And also we could obtained that the distributed particle size of the final microemulsions were about 8±1.5nm and the mean particle size was 7±0.5nm. We got following results from final microemulsions that the percent of transmittance; 96~98% at 700nm. And the microemulsion blended with MEG of 5~15wt% showed smaller particle size and more stable distribution than non-containing MEG.

형질전환 동물의 유선에서 특이적으로 인간 TPO가 발현되도록 고안된 pBT-L 외래유전자가 삽입되어 한 계통으로 확립된 형질전환 생쥐에서 이 유전자가 장기 세대까지 안정적으로 전이되고, 또한 발현 수준도 지속적으로 유지되는지를 조사 하였다 이를 위해 제 5세대의 수컷 pBT-L 형질전환 생쥐를 실험에 공시하였고, 제 10세대까지의 전이율과 인간 TPO의 발현수준을 분석하였다. 제 8세대 생쥐의 계대 번식에 의한 자손 중 51.3±18.98%가 형질전환 생쥐로 판명되었다. 또한 제9세대에서 외래 유전자의 전이율은 43.8±18.98%이었고, 제 10세대에서는 71.4±26.98%의 전이율을 나타내었다. 이러한 결과로 pBT-L 형질전환 생쥐는 그 외래유전자의 유전적 손상이 없이 장기 세대까지 안정적으로 전이되는 것으로 판단된다. 제 9세대외 10세대의 3마리의 암컷 형질전환 생쥐로 부터 유즙내 인간 TPO의 발현 수준을 분석하였을때, 그 농도는 모두 평균 1.1 mg/ml의 수준에서 측정되었다. 이러한 수준은 제 2세대의 것과 유사한 결과로 pBT-L 형질전환 생쥐에서 인간 TPO 유전자의 발현은 최소한 10세대까지 지속적으로 유지된다는 것을 알 수 있었고, 더 긴 장기 세대까지도 발현 수준이 유지될 것으로 추정된다. 이러한 연구결과는 계통으로 확립된 형질전환동물에 부여된 새로운 유전형질은 장기 세대까지 유전될 수 있음을 보여주는 것이다.

시판 국산 및 외국계열사 이유식의 아미노산 및 지방산 조성을 비교, 분석하고, 이들 이유식의 개봉 후 산패 진행 정도를 조사하였다. 시판 이유식의 탄수화물 함량은 61 ~ 70%, 단백질은 14 ~ 16%, 조지방은 8 ~ 15% 조회분은 2.5 ~ 3.2% 정도로 단백질과 탄수화물의 함량이 전체 77 ~ 85%를 차지하였다. 필수아미노산 중에서는 leucine (1460.2 ~ 1954.3 mg)이 가장 많았으며, 이어서 valine (928.9 ~ 1201.7 mg/100g), isoleucine (758.1 ~ 1033.9 mg/100g), lysine 9798.7 ~ 1081.4 mg/100g), phenylalanine (722.8 ~ 937.8 mg/100g), 의 순이었다. 국산 H, M, S사 및 외국계열사 이유식의 linoleic acid 과 linolenic acid 비율은 각각 15.4 : 1, 13.1 : 1, 39.8 : 1 및 M, S 사 및 외국계열사 이유식의 과산화물가는 각각 13.9 meq/kg oil, 1.1 meq/kg oil, 5.4 meq/kg oil 및 14.8 meq/kg oil이었다.

Slipping during various kinds of movement often leads to potentially dangerous incidents of falling. The purpose of this paper was to review some of the research performed in the field including such topics as rating scales for balance, kinematics and kinetics of slipping, adaptation to slippery conditions, postural and balance control, and protective movement during falling. Controlling slipping and fall injuries requires a multifaceted approach. Environmental conditions (state of floor surface, tidiness, lighting, etc), work task (walking, carrying, pushing, lifting, etc), and human behavior (anticipation of hazards, adaptation to risks, risk taking, etc) must be accounted for in the assessment of slip and fall-related risks. Future directions of research must deal with modeling of basic tribophysical, biomechanical, and postural control process involved in slipping and falling.

최근에 개발훤 플로로혐 재철의 RGP 콘태트렌즈에서도 렌즈를 착용하고 관리함에 따라 변수 변화가 나타날 수 있어 본 연구에서는 일반세척액， 마모제가 함유된 세척액 및 얄콜성분이 함유된 세척액옳 사용하여 세척회수에 따라 렌즈의 변수변화를 측정하 였으며， 콘택트렌즈 착용자의 렌즈를 수집하여 렌즈변수와 관리방법 동에 따른 변수 변화를 조사하였다. 플로로펌 재질의 RGP 콘택트렌즈를 각각의 세척액으로 5회， 15회， 30회， 50 회， 100 회， 150회 맞 200회 세척한 후 굴절력， 베이스커브， 중심두께 및 직경을 측정한 결파 렌즈의 변수에 변화가 없는 것으로 나타났으며， 콘택트렌즈 착용자가 착용한 렌즈에서 는 손가락으로 세척한 경우 (-) 도수가 증가하는r 경향이 나타났고 중심두께가 O.l2mm 이하인 앓은 렌즈의 경우에는 베이스커브에 변화가 관창되었다. 또한 착용한 콘택트렌 즈에서는 대부분 표변 긁혐 현상과 단백질 침전물이 관찰되어 콘택트렌즈 관리 상태가 나쁜 것으로 판단되었다. 따라서 플로로펌 재질의 RGP 콘택트렌즈의 경우 중심두께가 앓거나 잘못된 방법으 로 렌즈롤 관리하면 렌즈 변행이 유발될 수 있으며 이를 방지하기 위해서는 콘택트렌 즈 착용자에 대한 올바른 관리 교육이 펼요하다고 생각된다.

The structure system that is discreterized by continuous shells is usually used to make a large space structures and these structures show the collapse mechanisms that are captured at over the limit load, and snap-through and bifurcation are most well known of it. For the collapse mechanism, rise-span ratio, element stiffness and load mode are main factor, which it give an effect to unstable behavior. Moreover, resist force of structure can be reduced by initial condition and initial imperfection significantly. In order to investigate the instability of shell structures, the finite deformation theory can be applied and it becomes a nonlinear mathematics in which use equation of tangential stiffness incrementally. With an initial imperfection, using simple example and Flow Truss Dome, the buckling characteristics of space truss is main purpose of this paper, and unstable behavior is studied by proposed the numerical method. Also, by using MIDAS, this research work analyzes displacements and inner forces as the design load of model, and the ratio of buckling load of design load is investigated.

The isoflavone as a derivatives of flavone is colorless crystalline compounds. It acts on synthesis of fibronectine, collagen III, collagen I in human normal fibroblast by same biological activity to animal hormone. In this study, we tried to search and demonstrate system content rate of dermal translocation system for cosmetics using microemulsion containing isoflavone. The results of microemulsion stability test by centrifugation, storage in incubator and circulation chamber showed that separation of phase did not appear after 30 days. By the skin flexibility test, it has confirmed efficiency and effect as cosmetics materials. As the result, the microemulsion showed that skin flexibility factor improved up to 7.6%. We could confirm that O/W type microemulsion was stable system.