이 실험에서는 α-Al2O3 지지체 위에 진공 코팅(vacuum coating)과 딥 코팅(dip-coating) 기법을 사용하여 GO/γ -Al2O3 중간층을 형성하였고, 무전해도금 방식을 통해 Pd-Ag 수소 분리막을 제작하였다. Pd와 Ag는 각각 무전해도금을 통해 지지체 표면에 증착되었으며, 합금화를 위해 도금 과정 중 H2 분위기 하에서 500°C에서 18 h 동안 열처리를 진행하였다. 제 조된 분리막의 표면과 단면은 SEM을 통해 분석되었으며, Pd-Ag 분리막의 두께는 1.88 μm, GO/γ-Al2O3 중간층을 가진 Pd-Ag 분리막의 두께는 1.07 μm로 측정되었다. EDS 분석을 통해 Pd-77%, Ag-23%의 조성으로 합금이 형성된 것을 확인하 였다. 기체투과 실험은 H2 단일가스와 H2/N2 혼합가스를 이용하여 수행되었다. H2 단일가스 투과실험에서 450°C, 4 bar 조건 하에서 Pd 분리막의 최대 H2 플럭스는 0.53 mol/m²·s로, Pd-Ag 분리막의 경우 0.76 mol/m²·s로 측정되었다. H2/N2 혼합가스 실험에서 측정된 분리막의 separation factor는 450°C, 4 bar 조건에서 Pd 분리막이 2626, Pd-Ag 분리막이 13808로 나타났다.

A mid-story isolation system was proposed for seismic response reduction of high-rise buildings and presented good control performance. Control performance of a mid-story isolation system was enhanced by introducing semi-active control devices into isolation systems. Seismic response reduction capacity of a semi-active mid-story isolation system mainly depends on effect of control algorithm. AI(Artificial Intelligence)-based control algorithm was developed for control of a semi-active mid-story isolation system in this study. For this research, an practical structure of Shiodome Sumitomo building in Japan which has a mid-story isolation system was used as an example structure. An MR (magnetorheological) damper was used to make a semi-active mid-story isolation system in example model. In numerical simulation, seismic response prediction model was generated by one of supervised learning model, i.e. an RNN (Recurrent Neural Network). Deep Q-network (DQN) out of reinforcement learning algorithms was employed to develop control algorithm The numerical simulation results presented that the DQN algorithm can effectively control a semi-active mid-story isolation system resulting in successful reduction of seismic responses.

본 논문에서는 ~1.5 μm의 기공 크기를 가지는 고투과도 알파 알루미나 지지체 위에 도포된 서스펜션의 증발유도 자기조립 현상을 이용하여 중간층을 형성하는 새로운 코팅 방식을 소개한다. 새로운 코팅 방법으로 만들어진 중간층은 일반 적으로 사용되는 담지법으로 코팅된 중간층과 비교하여 표면거칠기와 불균일도가 낮아 코팅에 적합하였다. 복합막 지지체로 서의 평가를 위해 제조된 지지체는 감마 알루미나 복합막 제조에 사용되었다. 메조 기공을 가지는 감마 알루미나 복합막은 반복코팅 없이도 매크로 기공 크기의 결함이 존재하지 않았으며 일반적으로 널리 사용되는 100~200 nm의 기공 크기를 가지 는 지지체로부터 만들어진 같은 두께의 복합막과 비교하여 2.3배 이상의 높은 질소투과도를 보였다.

Spatial structure does not have columns and walls installed inside, so they have a large space. There are upper structure and substructure supporting them. The response of seismic loads to the upper structure may be increased or decreased due to the effects of the substructure. Therefore, in this study, the seismic response of the upper structure and the floor response spectrum of the substructure were compared and analyzed according to the height of the substructure in the spatial structure where the LRB was installed. As a result, the possibility of amplification of response was confirmed as seismic waves passed though the substructure, which is likely to increase the response of the upper structures.

A hybrid mid-story seismic isolation system with a smart damper has been proposed to mitigate seismic responses of tall buildings. Based on previous research, a hybrid mid-story seismic isolation system can provide effective control performance for reduction of seismic responses of tall buildings. Structural design of the hybrid mid-story seismic isolation system is generally performed after completion of structural design of a building structure. This design concept is called as an iterative design which is a general design process for structures and control devices. In the iterative design process, optimal design solution for the structure and control system is changed at each design stage. To solve this problem, the integrated optimal design method for the hybrid mid-story seismic isolation system and building structure was proposed in this study. An existing building with mid-story isolation system, i.e. Shiodome Sumitomo Building, was selected as an example structure for more realistic study. The hybrid mid-story isolation system in this study was composed of MR (magnetorheological) dampers. The stiffnessess and damping coefficients of the example building, maximum capacity of MR damper, and stiffness of isolation bearing were simultaneously optimized. Multi-objective genetic optimization method was employed for the simultaneous optimization of the example structure and the mid-story seismic isolation system. The optimization results show that the simultaneous optimization method can provide better control performance than the passive mid-story isolation system with reduction of structural materials.

A seismic isolation system is one of the most effective control devices used for mitigating the structural responses due to earthquake loads. This system is generally used as a type of base isolation system for low- and mid-rise building structures. If the base isolation technique is applied to high-rise buildings, a lot of problems may be induced such as the movement of isolation bearings during severe wind loads, the stability problem of bearings under large compression forces. Therefore, a mid-story isolation system was proposed for seismic protection of high-rise buildings. Residence-commerce complex buildings in Korea have vertical irregularity because shear wall type and frame type structures are vertically connected. This problem can be also solved by the mid-story isolation system. An effective analytical method using super elements and substructures was proposed in this study. This method was used to investigate control performance of mid-story isolation system for residence-commerce complex buildings subjected to seismic loads. Based on numerical analyses, it was shown that the mid-story isolation system can effectively reduce seismic responses of residence-commerce complex tall buildings.

In this study, the seismic response is investigated by using a relatively low-rise building under torsion-prone conditions and three seismic loads with change of the location of the seismic isolation system. LRB (Lead Rubber Bearing) was used for the seismic isolator applied to the analytical model. Fixed model without seismic isolation system was set as a basic model and LB models using seismic isolation system were compared. The maximum story drift ratio and the maximum torsional angle were evaluated by using the position of the seismic layer as a variable. It was confirmed that the isolation device is effective for torsional control of planar irregular structures. Also, it was shown that the applicability of the midstory seismic isolation system. Numerical analyses results presented that an isolator installed in the lower layer provided good control performance for the maximum story drift ratio and the maximum torsional angle simultaneously.

A base isolation system is widely used to reduce seismic responses of low-rise buildings. This system cannot be effectively applied to high-rise buildings because the initial stiffness of the high-rise building with the base isolation system maintains almost the same as the building without the base isolation system to set the yield shear force of the base isolation system larger than the design wind load. To solve this problem, the mid-story isolation system was proposed and applied to many buildings. The mid-story isolation system has two major objectives; first to reduce peak story drift and second to reduce peak drift of the isolation story. Usually, these two objectives are in conflict. In this study, a hybrid mid-story isolation system for a tall building is proposed. A MR (magnetorheological) damper was used to develop the hybrid mid-story isolation system. An existing building with mid-story isolation system, that is “Shiodome Sumitomo Building” a high rise building having a large atrium in the lower levels, was used for control performance evaluation of the hybrid mid-story isolation system. Fuzzy logic controller and genetic algorithm were used to develop the control algorithm for the hybrid mid-story isolation system. It can be seen from analytical results that the hybrid mid-story isolation system can provide better control performance than the ordinary mid-story isolation system and the design process developed in this study is useful for preliminary design of the hybrid mid-story isolation system for a tall building.

As the number of high-rise buildings increases, a mid-story isolation system has been proposed for high-rise buildings. Due to structural problems, an appropriate isolation layer displacement is required for an isolation system. In this study, the mid-story isolation system was designed and the seismic response of the structure was investigated by varying the yield strength and the horizontal stiffness of the seismic isolation system. To do this, a model with an isolation layer at the bottom of 15th floor of a 20-story building was used as an example structure. Kobe(1995) and Nihonkai-Chubu(1983) earthquake are used as earthquake excitations. The yield strength and the horizontal stiffness of the seismic isolation system were varied to determine the seismic displacement and the story drift ratio of the structure. Based on the analytical results, as the yield strength and horizontal stiffness increase, the displacement of the isolation layer decreases. The story drift ratio decreases and then increases. The displacement of the isolation layer and the story drift ratio are inversely proportional. Increasing the displacement of the isolation layer to reduce the story drift ratio can cause the structure to become unstable. Therefore, an engineer should choose the appropriate yield strength and horizontal stiffness in consideration of the safety and efficiency of the structure when a mid-story isolation system for a high-rise building is designed.

Base isolation system is generally used for low-rise buildings. For high-rise buildings subjected to earthquake loads, a mid-story isolation system was proposed and applied to practical engineering. In this study, seismic responses of high-rise buildings considering the installation story of the mid-story isolation system were evaluated. To do this, the 20-story and 30-story building were used as example structures. Historical earthquakes such as Kobe (1995), Northridge (1994) and Loma Prieta (1989) earthquakes were employed applied as earthquake excitations. The installation location of the mid-story isolation system was changed from the bottom of the 1st floor to the bottom of the top floor. The seismic responses of the example building were investigated by changing the location of the isolation layer. Based on the analytical results, when the seismic isolation system is applied, story drift ratio and acceleration response are reduced compared to the case without the isolation system. When the isolation layer is located on the lower part of the building, it is most effective. However, in that case, the possibility that the structure is unstable increases. Therefore, an engineer should consider both structural efficiency and safety when a mid-story isolation system for a high-rise building is designed.

본 연구에서는 기공의 크기가 큰 다공성 지지체를 3~4 μm, 150 nm의 크기를 갖는 α-알루미나 입자를 물과 실 리카-지르코니아 용액에 각각 분산시키는 방법으로 표면 개질을 하였다. 3~4 μm 크기의 알루미나 입자가 분산된 용액을 이 용하여 금속 지지체 및 알루미나 지지체에 코팅하였을 때, 코팅횟수가 증가할수록 지지체의 표면의 큰 기공이 감소하였고, 여 기에 150 nm 크기의 알루미나 입자가 분산된 용액으로 추가 코팅을 하면 작은 크기의 알루미나 입자가 기공 사이사이에 들 어가면서 지지체를 좀 더 매끄럽게 개질하는 역할을 하는 것을 확인하였다. 특히 실리카-지르코니아 용액을 분산매로 하여 표면 개질을 한 경우, 알루미나 입자가 실리카-지르코니아 층에 촘촘하게 박힌 모양으로 고정이 되어 지지체 개질에 효과적 임을 확인하였다. 이러한 방법으로 제조된 실리카-지르코니아 분리막의 기체투과도는 상온에서 각각 1.8 - 8.4 × 10-4 mol⋅m-2 ⋅s-1⋅Pa-1, 3.3 - 5.0 × 10-5 mol⋅m-2⋅s-1⋅Pa-1이며 수소/질소 선택도는 Knudsen 분포를 보였다. 표면 개질된 지지체에 다양 한 분리층을 형성하는 방법으로 무기 분리막 응용에 이용할 수 있을 것으로 예상된다.

PURPOSES: The objective of this study is to investigate the effect of asphalt and geotextile interlayer on the fracture behavior of unbonded concrete overlay through a laboratory composite beam test. METHODS: In order to evaluate the effect of interlayer materials on the fracture behavior of unbonded concrete overlay, a laboratory test of composite beam was conducted with different types of interlayer. The test results of the composite beam using two types of geotextile interlayer with different thicknesses were compared to the test results of the composite beam using the tradition type of asphalt interlayer. The unbonded concrete overlay on the existing concrete pavement without interlayer was set for the control condition. RESULTS AND CONCLUSION : Overall, the laboratory composite beam test results did show the effect of asphalt and geotextile interlayer on the fracture behavior of composite concrete beams. The three-layer geotextile interlayer and HMA layer both increase the peak load when the first macrocrack occurs in the top concrete beam, while the HMA interlayer causes the smallest load drop percentage after the first macrocrack. The three-layer geotextile did show better performance than the single-layer geotextile through the greater peak load and smaller load drop percentage. It indicates that the thickness of geotextile interlayer will affect the fracture behavior of unbonded concrete overlay and the thicker geotextile interlayer is recommended.

In this study, chemical bath deposited (CBD) indium sulfide buffer layers were investigated as a possible substitution for the cadmium sulfide buffer layer in CIGS thin film solar cells. The performance of the In2S3/CIGS solar cell dramatically improved when the films were annealed at 300˚C in inert gas after the buffer layer was grown on the CIGS film. The thickness of the indium sulfide buffer layer was 80 nm, but decreased to 60 nm after annealing. From the X-ray photoelectron spectroscopy it was found that the chemical composition of the layer changed to indium oxide and indium sulfide from the as-deposited indium hydroxide and sulfate states. Furthermore, the overall atomic concentration of the oxygen in the buffer layer decreased because deoxidation occurred during annealing. In addition, an In-thin layer was inserted between the indium sulfide buffer and CIGS in order to modify the In2S3/CIGS interface. The In2S3/CIGS solar cell with the In interlayer showed improved photovoltaic properties in the Jsc and FF values. Furthermore, the In2S3/CIGS solar cells showed higher quantum efficiency in the short wavelength region. However, the quantum efficiency in the long wavelength region was still poor due to the thick buffer layer.

In high-efficiency Cu(In,Ga)Se2 solar cells, Na is doped into a Cu(In,Ga)Se2 light-absorbing layer from sodalime-glass substrate through Mo back-contact layer, resulting in an increase of device performance. However, this supply of sodium is limited when the process temperature is too low or when a substrate does not supply Na. This limitation can be overcome by supplying Na through external doping. For Na doping, an NaF interlayer was deposited on Mo/glass substrate. A Cu(In,Ga)Se2 absorber layer was deposited on the NaF interlayer by a three-stage co-evaporation process As the thickness of NaF interlayer increased, smaller grain sizes were obtained. The resistivity of the NaF-doped CIGS film was of the order of 103Ω·cm indicating that doping was not very effective. However, highest conversion efficiency of 14.2% was obtained when the NaF thickness was 25 nm, suggesting that Na doping using an NaF interlayer is one of the possible methods for external doping.

TiAlN films were deposited on WC-5Co substrates with different buffer layers by D.C. magnetron sputtering. The films were evaluated by microstructural observations and measuring of preferred orientation, hardness value, and adhesion force. As a process variable, various buffer layers were used such as TiAlN single layer, TiAlN/TiAl, TiAlN/TiN and TiAlN/CrN. TiAlN coating layer showed columnar structures which grew up at a right angle to the substrates. The thickness of the TiAlN coating layer was about 1.8μm, which was formed for 200 minutes at 300˚. XRD analysis showed that the preferred orientation of TiAlN layer with TiN buffer layer was (111) and (200), and the specimens of TiAlN/TiAl, TiAlN/CrN, TiAlN single layer have preferred orientation of (111), respectively. TiAlN single layer and TiAlN/TiAl showed good adhesion properties, showing an over 80N adhesion force, while TiAlN/TiN film showed approximately 13N and the TiAlN/CrN was the worst case, in which the layer was destroyed because of high internal residual stress. The value of micro vickers hardness of the TiAlN single layer, TiAlN/TiAl and TiAlN/TiN layers were 2711, 2548 and 2461 Hv, respectively.