To lower the cost of MIM products, the gate and runner materials and green parts with defects are usually recycled. It is necessary to understand what causes the recycled products to deteriorate. The results show that the viscosity of the 1R (recycled once) feedstock was slightly lower than that of the fresh material. However, as the number of recyclings increased, the viscosity increased, while the density decreased, and more defects were noticed duri ng solvent debinding. These deteriorations were mainly caused by the increase of the melting point of the backbone binder and the oxidation of the filler or paraffin wax.
More and more applications or demands for machine parts etc are expected for AISI 440C (hereinafter referred to as "440C") Stainless Steel because of its characteristic features, i.e. high-strength as well as high-corrosion resistance. This research has enabled us to obtain sintered products with good quality even under a wide range of temperature by utilizing the pinning effect of NbC, improving the relevant sintering feature of 440C Stainless Steel in the MIM method.
To understand the effect of powder characteristics on the thermal debinding behavior, PIM parts produced with powders with different particle sizes and particle shapes were examined to determine their weight losses during thermal debinding. The results show that the average diameter of the pore channel in the compact increased when the temperature increased and when coarse powders were used. However, the weight loss rates did not increase proportionally with the pore size. This suggests that the different powders that are frequently used in PIM parts do not affect the thermal debinding rate significantly. This is because the pore size is much larger than the mean free path of the decomposed gas molecules. Thus, the diffusion rates of the gases are not rate-controlling in thermal debinding. The controlling mechanism of the thermal debinding rate is the decomposition of the backbone binder in the PIM parts.
This paper describes a Plasma Assisted Debinding and Sintering (PADS) equipment, which has been designed to process Metal Injection Molded (MIM) components. The use of a hybrid system combining a glow discharge with a conventional heating system makes debinding and sintering of MIM components, in the same heating cycle, a feasible industrial process. Characteristics as density, carbon content and mechanical properties are similar to traditionally processed MIM materials. The reduction of energy and gas consumption and shorter lead-times are economic advantages of PADS system. The clean environment of PADS is also an ecological advantage.
In this paper, rheological characteristics of Metal Injection Moulding (MIM) feedstock using locally binder of palm stearin are presented. The feedstock consisted of 316L-grade stainless steel powder with three different particle sizes and the binders comprise palm stearin and polyethylene. The viscosity of MIM feedstock at different temperatures and shear rates was measured and evaluated. Results showed that, the feedstock containing palm stearin exhibited suitable rheological properties and suitable to produce a homogeneous feedstock that is favorable for injection molding process.
In this present investigation, Metal Injection Moulding (MIM) of M2 High Speed Steel (HSS) parts using a wax-High Density Polyethylene (HDPE) binder is shown. The elimination of organic binder was carried out by thermal debinding under inert atmosphere. In order to keep carbon in the sample that could improve the sintering process, incomplete debinding was performed between 450 and . The specimens were sintered at temperatures between 1210 and in high vacuum atmosphere, obtaining the 98% of the theoretical density. In the samples with higher residual carbon content, the sintering window was extended up to 20 degrees and the optimum temperature was lower.
Powder injection molding (PIM) is a suitable technology for the fabrication of complex shape titanium and its alloys, and has a great potential in many applications. This paper dealt with the injection molding of hydride dehydrogenization (HDH) titanium powder, spheroidized HDH titanium powder and gas atomized titanium powder. Rheological and thermalgravimetric behaviors were compared between the feedstocks of the three powders, and a tentative application of Ti PIM to eye frame temple and bridge was briefed.
The global metal injection moulding industry is getting mature. The technology is on its way to grow from a niche technology to a widely accepted manufacturing process. This paper addresses the latest technological trends in MIM. Challenges in materials development as well as the current limits of the technology are discussed. Trends in processing like 2-component injection moulding and micro injection moulding are presented. The European MIM market situation is described and some key factors for business success are addressed. In the discussion of future business opportunities best practice examples are included.
Aluminum Alloys with a content of 22 wt.-% were spray formed. This alloy features by a low density and is therefore a superior material for leightweight applications. The main problem in spray forming of this type of alloy was the occurance of high porosities. First process optimizations have been performed to decrease porosity under a certain level, so that it can be closed by an extrusion process
In this study, the plasma sprayed and coatings have been investigated for applications of microelectronic components. The plasma sprayed coatings had a well-defined splatted lamellae microstructure, intersplat pores and a higher amount of microcracks within the splats. The plasma sprayed coating had a relatively lower hardness of 300-400Hv, compared to 650-800Hv for coating, and would be readily damaged by mechanical attacks such as erosion, wear and friction. For a reactive ion etching against F-containing plasmas, however, the coating had a much higher resistance than the coating because of the reduced erosion rate of by-products.
Cold spraying is a fairly new coating technique, which within the last decade attracted serious attention of research groups and spray companies. As compared to thermal spraying, the low process temperatures in cold spraying result in unique coating properties, which promise new applications. Since particles impact with high kinetic energy in the solid state, new concepts to describe coating formation are requested to enable the full potential of this new technology. The present contribution gives a brief review of current models concerning bonding, supplying a description of the most influential spray parameters and consequences for new developments. With respect to spray forming by cold cold spraying, microstructures and thick, further machineable structures are presented.
Nozzle geometry influences gas dynamics making sprayed particle behavior one of the most important parameters in cold spray process. Gas flows at the entrance convergent section of the nozzle takes place at relatively high temperature and are subsonic. Thus, this region is a very suitable environment for heating spray particle. In this study, numerical simulation and experiments were conducted to investigate the effect of nozzle contour, entrance geometry of nozzle and powder injection position at nozzle on the cold spray process. The process changes were observed through numerical simulation studies and the results were used to find a correlation with coating properties.
Metal/diamond binary composite coatings on Al substrate without grit blasting were deposited by cold spray process with insitu powder preheating. Microstructural characterization of the as-sprayed coatings with different diamond size, strength and with/without Ti coating on diamond was carried out by OM and SEM. The assessment of basic properties such as tensile bond strength and hardness of the coatings, and the deposition efficiency was also carried out. Particular attention on the composite coatings was on the diamond fracture phenomenon during the cold spray deposition and the interface bonding between the diamond and the Fe-based metal matrix.
NiTiZrSiSn bulk metallic glass powder was produced using inert gas atomization and then was sprayed onto a SS 41 mild steel substrate using the kinetic spraying process. Through this study, the effects of thermal energy of in-flight particle and crystallization degree by powder preheating temperature were evaluated. The deformation behavior of bulk metallic glass is very interesting and it is largely dependent on the temperature. The crystalline phase formation at impact interface was dependent on the in-flight particle temperature. In addition, variations in the impact behavior need to be considered at high strain rate and in-flight particle temperature.
This paper investigates the characteristic of single-layered and multi-layered compacts made by selective laser sintering using titanium powder (TILOP45 and TILOP150, Sumitomo Titanium Corp.) There were few defects in smooth surface of laser sintered specimen in vacuum as compared to the laser sintered specimen in argon. Maximum tensile strength of singlelayered compact was about 200MPa. Multi-layered compacts show the density of around 75% and the adhesive bonding was not observed between layers, resulted in 70MPa of maximum bending strength and 50MPa of maximum tensile strength.
A new approach to sintering loose packed, coarse aluminum alloy powder to full or near full density is presented. A controlled amount of water vapor is introduced into the sintering atmosphere, which disru pts the oxide film and allows metallurgical contact between particles. In addition, supersolidus liquid phase sintering is used to sinter the part to full density. Since the method is particularly applicable to uncompacted powders, it is potentially useful for sintering aluminum powder preforms manufactured by 3DPrinting and powder injection molding.
Direct Metal Laser Sintering (DMLS) has been utilized for prototype manufacturing of functional metal components for years now. During this period the surface quality, mechanical properties, detail resolution and easiness of the process have been improved to the level suitable for direct production of complex metallic components for various applications. The paper will present the latest DMLS technology utilizing EOSINT M270 laser sintering machine and EOSTYLE support generation software for direct and rapid production of complex shaped metallic components for various purposes. The focus of the presentation will be in rapid manufacturing of customized biomedical implants and surgical devices of the latest stainless steel, titanium and cobalt-chromium-molybdenum alloys. In addition to biomedical applications, other application areas where complex metallic parts with stringent requirements are being needed will be presented.
It is known that powder characteristics including particle size and distribution, particle shape, and chemical composition are important parameters which influence direct laser sintering of metal powders. In this paper, we introduce a first order kinetics model for densification of steel powders during laser sintering. A densification coefficient (K) is defined which express the potential of different powders to be laser-sintered to a high density dependent on their particle characteristics.