Soy sauce, a basic ingredient in Asian cuisine, is made of fermented soybeans, salt, water, and barley or wheat flour. The sensory characteristics of soy sauce are not only determined through its main ingredients but also by various flavor compounds produced during the fermentation process. This study was conducted to identify the sensory attributes of five different commercial soy sauce samples that differ in Meju types (traditional Meju or modified Meju) and usage types. Thirty three sensory attributes, including appearance (1), odor (16), flavor (14), and mouthfeel (2) attributes, were generated and evaluated by eight trained panelists. The collected data were analyzed by analysis of variance and principal component analysis. There were significant differences in the intensities of all sensory attributes among the soy sauce samples. Soy sauce made with traditional Meju had high intensity of fermented fish, beany, musty odors and salt, Cheonggukjang, fermented fish flavors. Whereas two soy sauces made with modified Meju were strong in alcohol, sweet, Doenjang, roasted soybean flavors. Two soy sauces for soup made with modified Meju had medium levels of briny, sulfury, fermented odors and bitter, chemical flavors and biting mouthfeel characteristic.

The most general photocatalyst, TiO2 and WO3, are acknowledged to be ineffective in range of visible light. Therefore, many efforts have been directed at improving their activity such as: band-gap narrowing with non-metal element doping and making composites with high specific surface area to effectively separate electrons and holes. In this paper, the method was introduced to prepare a photo-active catalyst to visible irradiation by making a mixture with TiO2 and WO3. In the TiO2-WO3 composite, WO3 absorbs visible light creating excited electrons and holes while some of the excited electrons move to TiO2 and the holes remain in WO3. This charge separation reduces electron-hole recombination resulting in an enhancement of photocatalytic activity. Added Ag plays the role of electron acceptor, retarding the recombination rate of excited electrons and holes. In making a mixture of TiO2-WO3 composite, the mixing route affects the photocatalytic activity. The planetary ball-mill method is more effective than magnetic stirring route, owing to a more effective dispersion of aggregated powders. The volume ratio of TiO2(4) and WO3(6) shows the most effective photocatalytic activity in the range of visible light in the view point of effective separation of electrons and holes.

알칼리 수전해용 격막으로 사용하기 위해 음이온교환막을 제작하였다. 음이온교환막은 PVC (polyvinyl chloride)를 출발물질로 하여 클로로메틸화 및 아민화에 의해 제작하였다. 제작한 막은 막 특성(막 저항, 이온교환용량)을 평가하였다.제작한 음이온교환막의 1M NaOH수용액에서의 최저 막 저항은 2.9 Ω·cm2를 나타냈다. 이 막은 2.17 meq./g-dry-membrane의 이온교환용량과 43.4%의 함수율을 보였다. 제작한 음이온교환막의 막 특성을 시판의 막 특성과 비교 평가하였다. 1M NaOH수용액에서의 막 저항은 AHT>IOMAC>Homemade membrane>AHA>APS=AFN의 순으로 저항 값이 높았다. 이온교환용량은 Homemade membrane>AFN>APS>AHT>AHA>IOMAC의 순으로 높은 값을 가졌다.

This research presents a preparation method of dental components by metal injection molding process (MIM process) using titanium scrap. About 20 μm sized spherical titanium powders for MIM process were successfully prepared by a novel dehydrogenation and spheroidization method using in-situ radio frequency thermal plasma treatment. The effects of MIM process parameters on the mechanical and biological properties of dental components were investigated and the optimum condition was obtained. After sintering at 1250oC for 1 hour in vacuum, the hardness and the tensile strength of MIMed titanium components were 289 Hv and 584 MPa, respectively. Prepared titanium dental components were not cytotoxic and they showed a good cell proliferation property.

4 mol% Yttria-stabilized zirconia (4YSZ) coatings with 200 μm thick are fabricated by Electron Beam Physical Vapor Deposition (EB-PVD) for thermal barrier coating (TBC). 150 μm of NiCrAlY based bond coat is prepared by conventional APS (Air Plasma Spray) method on the NiCrCoAl alloy substrate before deposition of top coating. 4 mol% YSZ top coating shows typical tetragonal phase and columnar structure due to vapor phase deposition process. The adhesion strength of coating is measured about 40 MPa. There is no delamination or cracking of coatings after thermal cyclic fatigue and shock test at 850oC.

Fe foam with above 90% porosity and 2 millimeter pore size was successfully fabricated by a slurry coating process. In this study, the binder contents were controlled to produce the Fe foam with different pore size, strut thickness and porosity. Firstly, the slurry was prepared by uniform mixing with Fe powders, distilled water and polyvinyl alcohol(PVA) as initial materials. After slurry coating on the polyurethane(PU) foam the sample was dried at 80oC. The PVA and PU foams were then removed by heating at 700oC for 3 hours. The debinded samples were subsequently sintered at 1250oC with holding time of 3 hours under hydrogen atmosphere. The three dimensional geometries of the obtained Fe foams with open cell structure were investigated using X-ray micro CT(computed tomography) as well as the pore morphology, size and phase.

본 연구에서는 metal organic frameworks (MOFs)의 한 종류인 MIL-100(Fe)을 이용하여 혼합기질막(mixed matrix membranes, MMMs)을 제조하였다. MIL-100(Fe)의 함량을 고분자 대비 0∼30 wt%까지 변화시키면서 첨가된 MOF의 함량에 따른 기체의 투과 특성을 살펴보았다. H2, CO2, O2, N2, CH4의 기체 투과도는 MIL-100(Fe) 첨가량이 증가함에 따라 투과도가 증가하는 경향을 보여주었으며, 상대적으로 큰 입자크기를 가진 SF6의 투과도는 MIL-100(Fe)의 첨가량이 증가함에 따라 투과도가 감소하였다. 이상 선택도는 N2/SF6의 경우 폴리이미드막 대비 약 40% 증가하였으며, 이를 통해 N2/SF6 분리에 적합한 분리막임을 확인할 수 있었다.

Microstructural and mechanical properties of Ni-YSZ fabricated using SPS processing have been investigated at various sintering temperatures. Our study shows samples to be applied as a SOFC anode have the proper porosity of 40% and high hardness when processed at 1100ºC. These results are comparable to the values obtained at 100- 200ºC higher sintering temperature reported by others. This result is important because when the fabrication processes are performed above 1100ºC, the mechanical property starts to decrease drastically. This is caused by the fast grain coarsening at the higher temperature, which initiates a mismatch between thermal expansion coefficients of Ni and YSZ and induces cracks as well.

본 연구의 목적은 활성탄의 CO2 흡착능을 향상시키기 위하여 화학적 전처리 방법을 개발하는 것이다. 다양한 방법과 이론이 존재하지만 이번 연구에서는 아미노화와 분해를 비교하여 흡착능을 비교하기로 하였다. 본 연구에서는 4가지 유형의 활성탄 입자를 원료 물질과 크기에 따라 준비하였고, 수산화칼륨으로 전처리하여 열처리 및 아민화과정을 거 친 후, CO2 흡착능을 비교 평가하였다. 실험결과, 단순 열처리과정만 적용할 때는 600℃ 가 가장 우수하였고, 800℃에서 아민화시킨 시료가 1.4 mmol/g의 가장 좋은 흡착능을 보 였다. 400～600℃에서 아민화를 시킨 시료는 처리온도와 비례하는 선택도를 보여주었다. 분해시간 또한 흡착능과 정비례하는 관계가 나타났다.

이 연구에서는 목재의 효율적인 이용과 그 이용확대를 목적으로, 가문비나무를 이용한 직교형 적층재를 제작하였고, 동적탄성계수에 미치는 섬유직각방향라미나의 연륜경각의 영향을 조사하였다. 또한, 동적탄성계수로부터 정적 휨 강도성능을 예측하였다. 3층 모두가 섬유직각방향라미나로 구성된 평행형적층재(P⊥타입)의 동적탄성계수는 연륜경각의 영향이 현저히 나타났고, 연륜경각 90∘에서 가장 높은 값을 나타내었고, 45∘에서 가장 낮은 값을 나타내었다. 중층에 섬유방향라미나를 배열하는 것에 의해 동적탄성계수는 현저히 향상되었다. 표층에 섬유직각방향라미나로 구성된 직교형 적층재 (C⊥타입)의 경우, 동적탄성계수는 연륜경각 90∘>0∘>45∘의 순이었으나, 연륜경각에 의한 차이는 평행형 적층재에 비해 현저히 감소하였다. 중층에 섬유직각방향라미나를 배열한 직교형 적층재 (C∥ 타입)의 경우, 동적탄성계수는 P⊥타입 및 C⊥타입과 역으로 연륜경각 45∘에서 가장 높은 값을 나타내었고, 그 값은 P∥ 타입보다 약간 적은 값을 나타내는 것이 확인되었다. 동적탄성계수와 정적 휨강도성능과의 상관회귀의 결과로부터 평행형 및 직교형 적층재의 정적 휨 강도성능이 동적탄성계수로부터 예측 가능한 것이 확인되었다. 단 C⊥타입의 경우, 충분한 시험편의 개수로 상관회귀를 실시할 필요가 있었다.

A powder in sheath rolling method was applied to the fabrication of a carbon nano tube (CNT) reinforced aluminum composite. A 6061 aluminum alloy tube with outer diameter of 31 mm and wall thickness of 2 mm was used as a sheath material. A mixture of pure aluminum powder and CNTs with a volume content of 5% was filled in the tube by tap filling and then processed to an 85% reduction using multi-pass rolling after heating for 0.5 h at 400˚C. The specimen was then further processed at 400˚C by multi-pass hot rolling. The specimen was then annealed for 1 h at various temperatures that ranged from 100 to 500˚C. The relative density of the 5vol%CNT/Al composite fabricated using powder in sheath rolling increased with increasing of the rolling reduction, becoming about 97% after hot rolling under 96 % total reduction. The relative density of the composite hardly changed regardless of the increasing of the annealing temperature. The average hardness also had only slight dependence on the annealing temperature. However, the tensile strength of the composite containing the 6061 aluminum sheath decreased and the fracture elongation increased with increasing of the annealing temperature. It is concluded that the powder in sheath rolling method is an effective process for fabrication of CNT reinforced Al matrix composites.

현대사회가 발전 할수록 대량산업화와 도시화가 심화되어 건축물의 초고층화 및 대형화가 증가하고 있으며, 안전적인 건축물 보다는 건물 및 제조사업장의 시각적인 디자인에 치우쳐 화재하중이 높은 건축자재의 내·외장재 및 고급스러운 장식물을 사용함으로써 그 위험뿐 만 아니라 화재발생시 대규모 인명 및 재산상의 피해를 가져오게 된다. 그리고 제조사업장화재는 화재로 인한 직접적인 손실 즉 물적 손실은 물론 생산중단으로 인한 간접적인 손실은 실로 측정하기가 어렵다. 지금까지 발생한 제조사업장화재의 발화요인별 분석은 부주의, 전기적, 미상 순으로 인한 화재가 가장 많고 발화열원은 작동기기, 담뱃불(라이터), 마찰․전도․복사등이 주요 원인이 되고 있고 대형화제 취약시설로는 공장 및 창고로 나타나고 있다. 소방방재청의 통계자료를 살펴보면 2012년 화재 발생현황 중 발화요인에 대한 화재별 장소 건수를 검토 한 결과 비주거의 화재발생 16,009건 중 5,758건으로 (36%)부주의이고, 주거에도 화재발생 10,715건 중 5,560건으로 51.9%의 부주의로 가장 높은 것으로 나타났다. 그러므로 제조사업장의 사소한 부주의로 발생하는 화재를 예방하기 위해서는 소방안전관리자의 처우개선과 기업활동규제완화의 겸직 허용을 재검토 하여야 하며 , 소방안전관라자의 실무능력 강화를 위한 소방안전관리 실무교육과정을 이론적 교육 보다는 현장 실습위주로 할 필요가 있다. 이를 위해서는 소방안전관리자에 대한 법정 실무교육 횟수를 확대하여 현행 2년에 1회 에서 1년에 1회로 하고, 실무교육에 있어서도 우수송방안전관리 업체를 선정하여 화재예방에 대한 구체적인 업무를 활성화 하고, 문제 발생요소들을 분석하여 실습을 통한 소방안전관리자의 실무교육을 실시해야 할 것이다. 이러한 전문 소방안전관리자로 소방대상물의 소방교육 및 훈련을 성실히 수행 해야 할 것 이다. 한순간의 부주의로 인하여 화재가 발생하면 돌이킬 수 없는 수백명의 생명을 앗아가고, 수백억원대의 재산피해를 줄이기 위해서는 소방안전관리자의 역량을 넓히고 화재예방 업무를 최우선적으로 수행해야 할 것이다. 화재예방을 위해 소방안전관리자의 업무개선 및 전문교육을 활성화 하여 업무능력을 향상 시켜 화재발생시 초기진압에 신속하고 정확하게 대처해야 한다는 것이 전문적인 화재예방 대책 일 것이다.

This paper is written following an analysis of occurrence trend of industrial disaster in manufacturing industry. One of major reason of industrial accident is unsafe action caused by lack of work supervision. so we have surveyed the understanding level of supervisors for industrial safety and their education of industrial safety which is forced by industrial law. We have got the result that the supervisor’s education is necessary to prevent industrial disaster but it’s not fit for their own workplace for various reasons from the survey and analysis. I would like to suggest effective solutions. The institute of education should train that they can execute safety and health works themselves by classification of the industrial category, company scale and located region. Also, government should endow supervisors with authority and responsibility for the activation of education system. Finally, government should support the expense of education to medium and small-sized enterprises especially, and they should be interested in the attendance and execution of education. They will achieve the goal to prevent industrial disasters in manufacturing industry through the enforcement of effective supervisor system as per the remark mentioned above.

Graphene oxide powders prepared by two different drying processes, freeze drying and spray drying, were studied to compare the effect of the drying method on the physical properties of graphene oxide powder. The graphene oxide dispersion was prepared from graphite by chemical delamination with the aid of sulfuric acid and permanganic acid, and the dispersion was further washed and re-dispersed in a mixed solvent of water and isopropyl alcohol. A freeze drying method can feasibly minimize damage to the sample, but it requires a long process time. In contrast, spray drying is able to remove a solvent in a relatively short time, though this process requires exposure to a high temperature for a rapid evaporation of the solvent. The powders prepared by freeze drying and spray drying were characterized and compared by Raman spectroscopy, X-ray diffraction, field-emission scanning electron microscopy, transmission electron microscopy, and by an elemental analysis. The graphene oxide powders showed similar chemical compositions; however, the morphologies of the powders differed in that the graphene oxide prepared by spray drying had a winkled morphology and a higher apparent density compared to the powder prepared by freeze drying. The graphene oxide powders were reduced at 900˚C in an atmosphere of N2. The effect of the drying process on the properties of the reduced graphene oxide was examined by SEM, TEM and Raman spectroscopy.

고온성 유산균인 Bacillus coagulans KM-1 균주를 이용하여 속성멸치액젓을 제조하였고 시판멸치액젓과 일반성분, 칼슘, 총질소, 아미노질소, 유리아미노산, 히스타민 등의 이화학적 품질특성을 비교하였다. 조단백질함량은 시판멸치액젓과 속성멸치액젓 각각 8.7 g/100 g, 10.95 g/100 g으로 속성멸치액젓이 더 높게 나타났으며 칼슘함량에서도 속성멸치액젓이 45.52 mg/100 g으로 시판멸치액젓 보다 높았고 유의적인 차이(p<0.05)를 보였다. 또한 총질소, 아미노질소에서도 시판멸치액젓은 1,380±13.92 mg/100g, 906.63±8.45 mg/100 g을 보인 반면 속성멸치액젓에서는 각각 1,750±15.88 mg/100 g, 1,251.15±12.72 mg/100 g로 더 높은 것으로 확인되었다. 핵산관련물질 총량은 시판멸치액젓과 속성멸치액젓 각각 201.85 mg/100 g, 212.11 mg/100 g를 보였으며 분해가 진행됨에 따라 hypoxanthine(Hx)의 함량은 시판멸치액젓 175.22 mg/100 g, 속성멸치액젓은 171.46 mg/ 100 g으로 핵산관련물질 중 가장 높게 측정되었으나 유의적인 차이(p<0.05)는 없었다. 유리아미노산 총량은 시판멸치액젓이 6983.8mg/100 g인 반면 속성멸치액젓은 9535.6 mg/100 g으로 높게 나타났으며 주요 아미노산으로 glutamic acid, hydroxyproline, citrulline, arginine, valine, leucine, proline, isoleucine으로 확인되었다. 히스타민의 측정에서 속성멸치액젓이 95.80±8.85 mg/kg으로 시판멸치액젓의 비해 5배 정도 낮게 나타났고 유의적인 차이(p<0.05)를 보였다. 대장균은 두 액젓 모두 음성으로 나타났다.

The purpose of this study was to investigate the antioxidative effects of Mori Cortex Radicis powder and to determine the optimal mixing ratio of Mori Cortex Radicis powder and water in the preparation of bread. The optimal sensory composite recipe was determined by producing bread with different levels of Mori Cortex Radicis powder and water. The analysis was performed using response surface methodology and a sensory evaluation was performed with the data. Ten experimental recipes, including two with reference points in the composition, were selected. In terms of the antioxidative effects of Mori Cortex Radicis powder, the IC50 for total phenolic content and DPPH free radical scavenging activity were 149.56 GAE/g dry powder and 137.77 /mL respectively. Measurement results of the mechanical properties showed differences in volume (p〈0.05), baking loss (p〈0.05), yellowness (p〈0.01), lightness (p〈0.01), redness (p〈0.01), hardness (p〈0.01) and springiness (p〈0.05). The sensory measurements showed significant values for color (p〈0.05), appearance (p〈0.05), flavor (p〈0.01), taste (p〈0.01), and overall quality (p〈0.01). Overall, based on numerical and graphical methods, the optimal formulation was determined to be 21.16 g of Mori Cortex Radicis powder and 372.47 g of water.

본 논문에서는 Pebax-2533 판형 분리막을 1-프로판올과 n-부탄올 혼합용매를 이용하여 용해, 건조하여 제조하였고 time-lag 장치를 이용하여 CO2, N2 투과특성을 평가하였다. 제조된 분리막은 평가조건에 따라서 130-288 barrer의 CO2 투 과율을 가졌으며, CO2/N2 투과선택도는 5-8이었다. Time-lag 장치의 주입부 압력이 증가함에 따라서, 투과온도가 낮아짐에 따라서, 그리고 혼합용매의 n-부탄올 양이 증가함에 따라서 CO2 투과도는 감소하였다. 이러한 실험 자료는 Pebax-2533 분리 막의 CO2 투과율이 CO2 용해에 매우 의존할 것이라 예측과 달리, CO2 용해뿐만 아니라 CO2 확산도 매우 중요한 단계임을 의미하였다.

In this study, porous titanium samples were manufactured by space holder methods using two kinds of urea and sodium chloride space holders. Three-dimensional pore structures were obtained by a computed-tomography (CT) tech- nique and utilized for finite element analysis in order to investigate the mechanical properties. The CT-based finite ele- ment analyses were in better agreement with the experimental results than unit cell model-based analyses. Both the experimental and CT-based results showed the same tendency that the elastic modulus decreased with increasing the porosities. The total porosity of the bulk body plays a key role in determining the elastic modulus of porous materials.