River estuaries are dynamic and productive ecosystems with high regional biodiversity. Environmental DNA (eDNA) has become a useful approach to assessing biodiversity in aquatic ecosystems. This study was conducted to investigate fish community characteristics and species diversity in two river estuary ecosystems, the Taehwa River and Changwon Stream. We further compared conventional and eDNA metabarcoding analyses of the fish communities. The conventional survey was performed in May, July, and October 2022, while the eDNA analysis was conducted only in May. We observed various fish species with different life histories, including carp, goby, and marine fish. We also found that migratory fish, such as dace Tribolodon hakonensis, sweetfish Plecoglossus altivelis, and eel Auguilla japonica, occurred in the Taehwa River, suggesting high river connectivity. Marine fish species were predominant in the Changwon Stream, as this river is located close to the sea. The diversity indices showed that the Taehwa River generally had higher species richness, evenness, and diversity values than the Changwon Stream. A total of 9-19 species were detected in the conventional survey for the three sites, whereas 11-18 species were found from eDNA analysis. The findings indicate that the sensitivity of eDNA was similar to or higher than that of the conventional method. Our study findings suggest the efficiency and efficacy of eDNA-based fish community monitoring, although with some shortcomings in applying the genetic marker to Korean fish, including no clear-cut distinction for Korean endemic species and/or genetically closely related species groups.

This study was performed to investigate antioxidant and anti-inflammatory activities of perilla(Perilla frutescens L.) seed, flower and leaf according to extraction condition. Perilla seed extracts(PSE), perilla flower extracts(PFE), perilla leaf extracts(PLE) was extracted by stirring extraction (STE, 25°C), shaking extraction (SHE, 80°C), and sonication assisted extraction(SAE, , 25°C) with 94% ethanol, 60% ethanol and distilled water, followed by analysis of total polyphenol and flavonoid and testing radical scavenging activities. The highest total polyphenol content (5.47, 9.36, 38.58 mg gallic acid equivalent/g), total flavonoid content(5.77, 8.62, 46.44 mg catechin equivalent/g), ABTS(10.68, 19.46, 63.56 mg trolox equivalent/g) and DPPH(6.51, 7.69, 79.73 mg trolox equivalent/g) radical scavenging activity of PSE, PFE and PLE was observed in the HWE with 60% ethanol,. Among the three extraction method, SHE provided the best results for yield, polyphenol, flavonoid content of perilla seed, flower, leaf in comparison to STE or SAE. SHE with 60% ethanol of perilla seed, flower, leaf more effectively inhibited secretion of nitric oxide(NO) and pro-inflammatory cytokine in RAW 264.7 macrophage exposed to LPS compared to other extraction solvent and method. Therefore, these extracts obtained from perilla seed, flower, leaf could be used antioxidant and anti-inflammatory ingredients in the food industry.

Mulberry fruit is a superior source of polyphenols, especially anthocyanin, and has a long history of use as an edible fruit and traditional medicine. The anthocyanin composition of mulberry fruit from 15 Korean cultivars was analyzed by ultra-performance liquid chromatography diode array detector with quadrupole time of flight/mass spectrometry (UPLC-DAD-QToF/MS) based on a cyanin internal standard. The four glycosides were identified by comparison with authentic standards and published reports. The major anthocyanin was cyanidin 3-O-glucoside (71.7%), followed by cyanidin 3-O-rutinoside (26.6%). The minor components (total of 1.7%) were pelargonidin 3-O-glucoside and pelargonidin 3-O-rutinoside. The total anthocyanin content (mg/100 g, dry weight) of mulberry fruit varied by cultivar and ranged from 471.5±4.0 (Su Hong) to 4,700.2±54.0 (Gwa Sang2). Among the 15 cultivars examined, Gwa Sang2 showed the highest level of cyanidin 3-O-glucoside (3,133.4±32.6), which was 9-fold higher than that of Su Hong (351.5±3.4). In conclusion, anthocyanin profiles, including pelargonidin 3-O-glucoside and pelargonidin 3-O-rutinoside, were reported for the first time from 15 Korean mulberry fruit cultivars. The results will contribute valuable information on pharmaceutical properties, breeding superior mulberry cultivars, and food industries.

Highly safe lithium-ion batteries (LIBs) are required for large-scale applications such as electrical vehicles and energy storage systems. A highly stable cathode is essential for the development of safe LIBs. LiFePO4 is one of the most stable cathodes because of its stable structure and strong bonding between P and O. However, it has a lower energy density than lithium transition metal oxides. To investigate the high energy density of phosphate materials, vanadium phosphates were investigated. Vanadium enables multiple redox reactions as well as high redox potentials. LiVPO4O has two redox reactions (V5+/V4+/V3+) but low electrochemical activity. In this study, LiVPO4O is doped with fluorine to improve its electrochemical activity and increase its operational redox potential. With increasing fluorine content in LiVPO4O1-xFx, the local vanadium structure changed as the vanadium oxidation state changed. In addition, the operating potential increased with increasing fluorine content. Thus, it was confirmed that fluorine doping leads to a strong inductive effect and high operating voltage, which helps improve the energy density of the cathode materials.

The key to invasive pest management lies in preemptive action. However, most current research using species distribution models is conducted after an invasion has occurred. This study modeled the potential distribution of the globally notorious sweet potato pest, the sweet potato weevil (Cylas formicarius), that has not yet invaded Korea using MaxEnt. Using global occurrence data, bioclimatic variables, and topsoil characteristics, MaxEnt showed high explanatory power as both the training and test areas under the curve exceeded 0.9. Among the environmental variables used in this study, minimum temperature in the coldest month (BIO06), precipitation in the driest month (BIO14), mean diurnal range (BIO02), and bulk density (BDOD) were identified as key variables. The predicted global distribution showed high values in most countries where the species is currently present, with a significant potential invasion risk in most South American countries where C. formicarius is not yet present. In Korea, Jeju Island and the southwestern coasts of Jeollanam-do showed very high probabilities. The impact of climate change under shared socioeconomic pathway (SSP) scenarios indicated an expansion along coasts as climate change progresses. By applying the 10th percentile minimum training presence rule, the potential area of occurrence was estimated at 1,439 km2 under current climate conditions and could expand up to 9,485 km2 under the SSP585 scenario. However, the model predicted that an inland invasion would not be serious. The results of this study suggest a need to focus on the risk of invasion in islands and coastal areas.

With the increasing demand for electronic products, the amount of multilayer ceramic capacitor (MLCC) waste has also increased. Recycling technology has recently gained attention because it can simultaneously address raw material supply and waste disposal issues. However, research on recovering valuable metals from MLCCs and converting the recovered metals into high-value-added materials remains insufficient. Herein, we describe an electrospinning (E-spinning) process to recover nickel from MLCCs and modulate the morphology of the recovered nickel oxide particles. The nickel oxalate powder was recovered using organic acid leaching and precipitation. Nickel oxide nanoparticles were prepared via heat treatment and ultrasonic milling. A mixture of nickel oxide particles and polyvinylpyrrolidone (PVP) was used as the E-spinning solution. A PVP/NiO nanowire composite was fabricated via Espinning, and a nickel oxide nanowire with a network structure was manufactured through calcination. The nanowire diameters and morphologies are discussed based on the nickel oxide content in the E-spinning solution.

High-entropy alloys (HEAs) are characterized by having five or more main elements and forming simple solids without forming intermetallic compounds, owing to the high entropy effect. HEAs with these characteristics are being researched as structural materials for extreme environments. Conventional refractory alloys have excellent hightemperature strength and stability; however, problems occur when they are used extensively in a high-temperature environment, leading to reduced fatigue properties due to oxidation or a limited service life. In contrast, refractory entropy alloys, which provide refractory properties to entropy alloys, can address these issues and improve the hightemperature stability of the alloy through phase control when designed based on existing refractory alloy elements. Refractory high-entropy alloys require sufficient milling time while in the process of mechanical alloying because of the brittleness of the added elements. Consequently, the high-energy milling process must be optimized because of the possibility of contamination of the alloyed powder during prolonged milling. In this study, we investigated the hightemperature oxidation behavior of refractory high-entropy alloys while optimizing the milling time.

Aluminum alloys, known for their high strength-to-weight ratios and impressive electrical and thermal conductivities, are extensively used in numerous engineering sectors, such as aerospace, automotive, and construction. Recently, significant efforts have been made to develop novel aluminum alloys specifically tailored for additive manufacturing. These new alloys aim to provide an optimal balance between mechanical properties and thermal/ electrical conductivities. In this study, nine combinatorial samples with various alloy compositions were fabricated using direct energy deposition (DED) additive manufacturing by adjusting the feeding speeds of Al6061 alloy and Al-12Si alloy powders. The effects of the alloying elements on the microstructure, electrical conductivity, and hardness were investigated. Generally, as the Si and Cu contents decreased, electrical conductivity increased and hardness decreased, exhibiting trade-off characteristics. However, electrical conductivity and hardness showed an optimal combination when the Si content was adjusted to below 4.5 wt%, which can sufficiently suppress the grain boundary segregation of the α- Si precipitates, and the Cu content was controlled to induce the formation of Al2Cu precipitates.

PURPOSES : This study is to initiated to estimate the impact of mixed traffic flow on expressway section according to the market penetration rate(MPR) of automated vehicles(AVs) using a enhanced intelligent driver model(EIDM). METHODS : To this end, microscopic traffic simulation and EIDM were used to implement mixed traffic flow on basic expressway section and simulation network was calibrated to understand the change of impact in mixed traffic flow due to the MPR of AVs. Additionally, MOEs of mobility aspects such as average speed and travel time were extracted and analyzed. RESULTS : The result of the impact of mobility MOEs by MPR and level of service indicated that 100% MPR of AVs normally affect positive impact on expressway at all level of service. However, it was analyzed that improvements in the level of service from LOS A to C are minimal until the MPR of AVs reaches 75% or higher. CONCLUSIONS : This research shows that impact of MPR of AVs using EIDM of mixed traffic flow on basic expressway. Increasing MPR of AVs affects positive impact on expressway at all level of services. However, MPR from 25% to 75% of AVs in LOS A to C shows minimal impacts. Therefore, to maximize the effectiveness of AVs, appropriate traffic operation and management strategies are necessary.

PURPOSES : Demonstrated performance degradation of LiDAR for vehicle and pedestrian dummy in rainy and foggy road conditions. METHODS : In real-scale rain and fog road conditions, adjust the distance between LiDAR and the measurement target from 10m to 70m (in 10m interval), measure LiDAR NPC (number of point cloud) and intensity, and compare the resulting numerical values. RESULTS : LiDAR's NPC and Intensity showed statistically significant differences by overall weather condition (normal, rain, fog), and the values were found to be larger in the order of normal>rainfall>fog. In the case of vehicles, sunder rain conditions, NPC and intensity are recognized even at 70m as in normal conditions, but under fog conditions, NPC and intensity are measured only up to 30m. In the case of pedestrians, the reflective area size is smaller than that of vehicles, so they are recognized only up to 30m in rainy conditions, and NPC and intensity are measured only up to 20m in fog conditions. CONCLUSIONS : It was confirmed that LiDAR performance deteriorates in rain and fog compared to normal.

이 연구 논문은 기후 변화에 대한 전 세계적인 우려와 온실 가스 배출 감소를 위한 필수적인 요구에 대응하여 마 이크로기공 고분자(PIM-1)의 이용을 탐구한 것이다. 연구는 PIM-1 막을 이산화탄소(CO2) 가스 분리 막으로 사용하는 현대적 인 소재로서의 응용에 집중하고 있다. 연구는 PIM-1 막의 합성, 분자량 제어, 그리고 제각각의 특성 분석 기술을 통해 포괄적 인 통찰을 제공하며, 이러한 특성 분석 기술을 통해 PIM-1의 고유한 교차결합 및 강성 구조에서 비롯된 내재적 다공성이 특 히 이산화탄소의 선택적 투과에 활용되고 있다. 논문은 PIM-1의 가교된 구조로부터 비롯된 내재적 다공성이 특히 이산화탄 소의 선택적 투과에 활용되고 있다. 논문은 PIM-1의 튜닝 가능한 화학적 특성을 강조하며, 가스 분리 막의 맞춤 및 최적화를 가능케 하는 특성에 대한 이해를 제시하고 있다. 분자량을 통제함으로써 고분자량(H-PIM-1) 막은 낮은 분자량 대비 더 뛰어 난 CO2 투과성과 선택성을 나타내며, 이를 통해 PIM-1 막의 특성을 조절하는 데 분자량의 중요성을 강조하고 있다. 연구 결 과는 PIM-1 막 특성을 조절하는 데 분자량이 중요한 역할을 하는 것을 강조하며, 이는 기후 변화의 긴급한 글로벌 도전에 대 응하기 위한 효율적이고 선택적인 CO2 포집을 위한 차세대 막 기술의 발전에 기여하고 있다.

Dissolved organic matter (DOM) is a key component in the biogeochemical cycling in freshwater ecosystem. However, it has been rarely explored, particularly complex river watershed dominated by natural and anthropogenic sources, such as various effluent facility and livestock. The current research developed a new analytical method for TOC/TN (Total Organic Carbon/Total Nitrogen) stable isotope ratio, and distinguish DOM source using stable isotope value (δ13C-DOC) and spectroscopic indices (fluorescence index [FI] and biological index [BIX]). The TOC/TN-IR/MS analytical system was optimized and precision and accuracy were secured using two international standards (IAEA-600 Caffein, IAEA-CH-6 Sucrose). As a result of controlling the instrumental conditions to enable TOC stable isotope analysis even in low-concentration environmental samples (<1 mgC L-1), the minimum detection limit was improved. The 12 potential DOM source were collected from watershed, which includes top-soils, groundwater, plant group (fallen leaves, riparian plants, suspended algae) and effluent group (pig and cow livestock, agricultural land, urban, industry facility, swine facility and wastewater treatment facilities). As a result of comparing characteristics between 12 sources using spectroscopic indices and δ13C-DOC values, it were divided into four groups according to their characteristics as a respective DOM sources. The current study established the TOC/TN stable isotope analyses system for the first time in Korea, and found that spectroscopic indices and δ13C-DOC are very useful tool to trace the origin of organic matter in the aquatic environments through library database.

In this study, the performances of H2S, NH3, and HCl sensors for real-time monitoring in small emission facilities (4, 5 grades in Korea) were evaluated at high concentration conditions of those gases. And the proper approach for the collection of reliable measurement data by sensors was suggested through finding out the effect on sensor performances according to changes in temperature and humidity (relative humidity, RH) settings. In addition, an assessment on sensor data correction considering the effects produced by environmental settings was conducted. The effects were tested in four different conditions of temperature and humidity. The sensor performances (reproducibility, precision, lower detection limit (LDL), and linearity) were good for all three sensors. The intercept (ADC0) values for all three sensors were good for the changes of temperature and humidity conditions. The variation in the slope value of the NH3 sensor showed the highest value, and this was followed by the HCl, H2S sensors. The results of this study can be helpful for data collection by enabling the more reliable and precise measurements of concentrations measured by sensors.

Industrial complex areas are an important factor that contributes to economic development. However, these areas also produce a significant amount of noxious air pollutants. In particular, PM10 emitted from industrial complex areas can lead to detrimental effects on human health. This study was conducted to survey environmental conditions and measure the concentration of PM10 in indoor and outdoor living spaces in Yeosu and Gwangyang. In Yeosu, the level of PM10 concentration in indoor living spaces was measured at 49.38 μg/m3, while the outdoor level was measured at 43.60 μg/m3. In Gwangyang, the PM10 concentration in indoor living spaces was measured at 20.08 μg/m3 while the outdoor measurement came to 18.14 μg/m3. When analyzing the percentage of those who were highly concerned with environmental pollution among a survey group of 200 people, Yeosu City had a rate of 76.5%, while Gwangyang City had a comparable rate of 73%. When looking at the time-activity patterns of residents in both locations, Yeosu residents spend more than 80.0% of their time inside their living spaces, while Gwangyang residents spend more than 70.0% of time inside their living spaces. These high rates are largely due to the fact that most of the residents of these areas are elderly. In both Yeosu and Gwangyang, it was found that 40% of residents use TV and radio rather than newspapers or handouts to obtain information about environmental pollution problems in their area.

본 논문은 중국 사찰 채화의 시대별 전개 양상, 독자성과 보편성 등을 파악 하며 한국과 중국의 단청과 채화를 비교・분석한 것이다. 중국 채화는 송대에 편찬된 『영조법식(營造法式)』에 의해 정형화되었고, 명・청대는 채화의 전성기 를 이루었다. 고려시대 단청은 중국과 차별화된 이른바 한국적인 특색을 나타 내었고, 조선시대에는 명・청과 정치, 경제, 문화 등 여러 방면으로 교류하면서 사찰 단청의 형식과 문양 등에서 보편성과 특수성을 띠게 되었다. 명・청 사찰 채화와 조선시대 사찰 단청의 머리초[조두], 금문(錦紋), 별지화[잡화], 단독문 등을 통해 공통점과 독자적인 특징을 살펴보았다. 머리초・금문・단독문은 한 부재에 반복적으로 사용되는 도안화된 장식문이고, 별지화는 부재별로 다양한 도상이 사용된 회화적 장식화이다. 한국 단청과 중국 채화의 유사한 문양 가운 데 네 종류를 선별해 조선시대 단청과 명・청대 채화를 비교하였다. 이를 통해 양국 단청[채화]의 차이점과 공통점 그리고 국가별 독자성을 파악할 수 있었다.

2015년부터 2022년도까지 6개목(딱정벌레목, 노린재목, 나비목, 벌목, 파리목, 총채벌레목) 곤충들에 대해서 식물검역현장 검출실적과 국내 보고된 미기록종을 분석하였다. 해당기간 동안 국경검역에서 6개목 곤충은 총 45,084건이 검출되었다. 같은 기간 국내에서는 총 545종이 미기록종 으로 보고되었으며, 이중 9종은 국경검역에서도 검출된 것으로 확인되었다. 검역현장에서는 딱정벌레목, 총채벌레목, 노린재목이 높은 검출률을 보 였으며, 국내 미기록종 중에서는 벌목이 176종으로 가장 많이 보고되었다. 본 연구를 통해 침입압력(국경검역 검출)과 실제 침입(국내 미기록종 발 견) 사이에 비동시성이 확인되었다. 향후 보다 장기적인 분석이 필요할 뿐만 아니라 지속적인 식물검역시스템 개선이 필요할 것으로 판단된다.

PURPOSES : In this study, the basis for improving the maintenance method of road pavement in Jeju Island, where deterioration is accelerating, was presented through field construction and analysis of various combinations of maintenance methods. METHODS : Construction was performed on Jeju Island's Aejo Road, which has high traffic and frequent early damage, using various asphalt mixtures mainly applied in Jeju Island, with different maintenance cross-sections depending on the level of repair. The quality and performance of the asphalt mixture collected during construction were evaluated, and MEPDG was used to analyze the service life according to the type and maintenance level of the mixture. RESULTS : While the mixture for the surface layer satisfied the quality standards and had excellent rutting and moisture resistance performance, the asphalt mixture for the intermediate and base layer did not satisfy the quality standards such as air voids, so it was judged that quality control was necessary during production. The section repaired to the base layer was found to be advantageous for the integrated behavior of the pavement and had the best structural integrity. As a result of predicting the service life, the estimated life of the section where only the surface layer was repaired was analyzed to be approximately 7 years, the section where the intermediate layer was repaired was 14.5 years, and the section where the entire section up to the base layer was repaired was analyzed to be 18 years. CONCLUSIONS : In Jeju Island, where deterioration is accelerating, it was analyzed that when establishing a maintenance plan, it is necessary to consider repairing the middle and base floors in order to secure the designed life of 10 years.

PURPOSES : The aim of this study is to investigate the enhancement of performance and the mix design method for asphalt mixtures utilizing ferronickel slag, an industrial by-product METHODS : To enhance the performance of FNS asphalt, waste tire powder (CR) was incorporated, and the characteristics of FNS asphalt aggregate, along with the impact of CR, were evaluated through the mix design process. RESULTS : CR is found to be suitable with a size of 30 mesh, and the optimal usage amount is determined to be 1±0.1% of the mixture weight, considering dense grade asphalt mixture. Volumetric design considering the swelling characteristics of CR is necessary, and a mixing design with a consistent tendency can be achieved only when an appropriate VMA is secured. CONCLUSIONS : The mix design for FNS-R asphalt mixture requires an increase of approximately 1% in VMA compared to conventional dense-graded asphalt mixtures to accommodate the swelling of CR. Additionally, FNS-R asphalt exhibits improved resistance to rutting comparable to modified asphalt and meets quality standards, including stripping resistance.

PURPOSES : Derive a road pavement design method using Geocells, aim to derive a road pavement design and construction method suitable for the characteristics of the Bangladesh region METHODS : To assess long-term performance during road construction in Southeast Asia using Geocells, field tests and numerical analysis are conducted to verify stability. RESULTS : A total of 12 displacement measurements were conducted during the field tests, confirming an average load of 15.75 kN and an average displacement of 0.542mm. Inverse analysis was performed to obtain the properties of Geocell combined with compacted soil. The numerical analysis results confirmed that the insertion of Geocell provides better stability compared to the case with only compacted soil. CONCLUSIONS : Based on field tests and numerical analysis, a road design plan suitable for the Southeast Asian environment was proposed. A preliminary test section was selected in the Comilla region of Bangladesh, and test construction has been completed. Subsequent evaluations of the structural performance by soil layer in the test construction area will be conducted to develop a Geocell road pavement method, taking into consideration the characteristics of the Bangladesh region.

PURPOSES : This study was conducted to evaluate the physical properties of the RAP 50 asphalt mixture containing polymer modified rejuvenator and warm-mix additive to improve the recycling rate of RAP and reduce CO2 emission. METHODS : Mix design of Polymer Modified Warm-mix Asphalt Mixture(RAP 50), and Hot Mix Asphalt Mixture(RAP 30) were produced and the properties of asphalt mixture such as Marshall Stability, ITS, Deformation Strength, TSR, and Dynamic Stability were compared between the two asphalt mixtures. RESULTS : The RAP 50 asphalt mixture showed superior or similar performances compared to the RAP 30 asphalt mixture in all the tests conducted. The results of the Marshall stability and dynamic stability in particular were 13,045N and 3,826 pass/mm, which were 11.37% and 76.7% greater than the RAP 30 asphalt mixture, which indicated that high plastic deformation resistance may be expected. CONCLUSIONS : The results obtained from laboratory tests on the two types of mixtures indicated that the use of polymer modified rejuvenator and warm-mix additive not only allows to increase the proportion of RAP but also improves its properties under lower temperature condition than RAP 30 asphalt mixture. Additionally, it was confirmed that plastic deformation resistance was high and moisture resistance and crack resistance were improved for a RAP 50 asphalt mixture.