In this work, the dispersion behavior of particles in binary aluminum (Al)-copper (Cu) cast alloy was investigated with respect to Cu contents of 20 (hypoeutertic), 33 (eutectic) and 40 (hypereutectic) wt.%. In cases of hypo and hypereutectic compositions, SEM images revealed that the primary Al and phases were grown up at the beginning, respectively, and thereafter the eutectic phase was solidified. In addition, it was found that some of particles can be dispersed into the primary Al phase, but none of them are is observed inside the primary 6 phase. This different dispersion behavior of particles is probably due to the difference in the val- ues of specific gravity between particles and primary phases. At eutectic composition, particles were well dispersed in the matrix since there is few primary phases acting as an impediment site for particle dispersion during solidification. Based on the experimental results, it is concluded that particles are mostly dispersed into the eutectic phase in binary Al-Cu alloy system.

Mg-4.3Zn-0.7Y (at%) alloy powders were prepared using an industrial scale gas atomizer, followed by warm extrusion. The powders were almost spherical in shape. The microstructure of atomized powders and those extruded bars was examined using Scanning Electron Microscopy (SEM), Energy Dispersive X-ray Spectroscope (EDS) and X-ray Diffractometer (XRD). The grain size of the powders was coarsen as the initial powder size increased. After the extrusion, the grain size became fine due to the severe plastic deformation during the extrusion with the ratio of 10:1. Both the ultimate strength and elongation were enhanced with the decrease of initial particle size.

본고에서는 고유한 원자구조에 기인한 우수한 특성으로 인해 구조재료 및 기능재료로서 그 활용이 기대되고 있는 벌크 아몰퍼스 소재에 있어 온간압출, 온간압연, 방전 플라즈마 소결(Spark Plasma Sintering)등 과냉각액체온도구간에서의 점성유동을 이용한 고화성형 공정의 최근 기술동향에 대해 간략히 소개했다.

In the development of new hydrogen absorbing materials for a next generation of metal hydride electrodes for rechargeable batteries, metastable Mg-Ni-based compounds find currently special attention. Amor phous-nanocrystalline and alloys were produced by mechanical alloying and melt-spinning and characterized by means of XRD, TEM and DSC. On basis of mechanically alloyed Mg-Ni-Y powders, complex hydride electrodes were fabricated and their electrochemical behaviour in 6M KOH (pH=14,8) was investigated. The electrodes made from powders, which were prepared under use of a SPEX shaker mill, with a major fraction of nanocrystalline phase reveal a higher electrochemical activity far hydrogen reduction and a higher maximum discharge capacity (247 mAh/g) than the electrodes from alloy powder with predominantly amorphous microstructure (216 mAh/g) obtained when using a Retsch planetary ball mill at low temperatures. Those discharge capacities are higher that those fur nanocrystalline electrodes. However, the cyclic stability of those alloy powder electrodes was low. Therefore, fundamental stability studies were performed on and ribbon samples in the as-quenched state and after cathodic hydrogen charging by means of anodic and cathodic polarisation measurements. Gradual oxidation and dissolution of nickel governs the anodic behaviour before a passive state is attained. A stabilizing effect of higher fractions of yttrium in the alloy on the passivation was detected. During the cathodic hydrogen charging process the alloys exhibit a change in the surface state chemistry, i.e. an enrichment of nickel-species, causing preferential oxidation and dissolution during subsequent anodization. The effect of chemical pre-treatments in 1% HF and in solution on the surface degradation processes was investigated. A HF treatment can improve their anodic passivation behavior by inhibiting a preferential nickel oxidation-dissolution at low polarisation, whereas a treatment has the opposite effect. Both pre-treatment methods lead to an enhancement of cathodically induced surface degradation processes.

Lanthanum oxide was introduced to molybdenum powder by liquid-liquid doping and liquid-solid doping respectively. Mo alloys were prepared by powder metallurgy technology. The size distribution and feature of dopant particles and the fractographs of Mo alloys were investigated by TEM and SEM respectively. The results indicated that liquid-liquid doping method is favorable for refining and dispersing particles uniformly in matrix. Fracture toughness of Mo alloys prepared by liquid-liquid doping showed better results than that of liquid-solid doping. Furthermore, the influences of the size distribution of on properties of Mo alloys was discussed by dislocation pile-up theory.

Mg-Zn-RE alloys had a novel lond period stacking ordered (LPO) structure. Their rapidly solidified powder metallurgy (RS P/M) alloys exhibited a combination of high strength and god ductility (tensile yield strength above 550 MPa and elongation above 5%). The LPO Mg-Zn-RE RS P/M alloys had high elevated temperature strength (tensile yield strength above 380 MPa at 473 K) and exhibited a high-strain-rate superplasticity at higher temperatures. In Japan, a national project for developing high strength LPO Mg-Zn-RE RS P/M alloys has started at 2003 for 5 years, which is founded by the Ministry of Economy, Trade and Industry (METI) of Japan. In the national project, project targets in materials performances have been achieved. The developed LPO Mg-Zn-RE RS P/M alloys exhibited higher tensile yield strength, fatigue strength and corrosion resistance than high strength aluminum alloys of extra-super-duralumin (7075-T6).

Dispersion-strengthened copper with was produced by ball-milling and spark plasma sintering (SPS).Ball-milling was performed at a rotation speed of 300rpm for 30 and 60min in Ar atmosphere by using a planetary ball mill (AGO-2). Spark-plasma sintering was carried out at for 5min under vacuum after mechanical alloying. The hardness of the specimens sintered using powder ball milled for 60min at 300rpm increased from 16.0 to 61.8 HRB than that of specimen using powder mixed with a turbular mixer, while the electrical conductivity varied from 93.40% to 83.34%IACS. In the case of milled powder, hardness increased as milling time increased, while the electrical conductivity decreased. On the other hand, hardness decreased with increasing sintering temperature, but the electrical conductiviey increased slightly

In order to obtain specific magnetic properties, it is of paramount importance to increase the alloy density of components fabricated by powder metallurgy. An alternative to increase the density of alloys such as Fe-49Co-2V would be the use of elemental Fe and Co instead of the pre-alloyed powder. Trying to give some insight on the industrial application of this strategy, this paper investigates the replacement of more conventional pre-alloyed Fe-49Co-2V powders with elemental Fe and Co. A previous analysis shows that it is possible to achieve higher densities and leads to a noticeable improvement in some important magnetic properties.

TZM alloy having elongated coarse-grain structure was developed by three-step internal nitriding treatment at 1423 to 1873 K in and subsequent recrystallization treatment at 2173 K in vacuum. Some specimens were subjected to re-nitriding treatment at 1873 K for 16 h. After the recrystallization treatment, aspect ratio (L/W) of grains for rolling direction was about 50 at the maximum. Yield stress obtained at 1773 K after re-nitriding treatment was about 6 times as large as that of recrystallized specimen. Re-nitriding was very effective in the improvement in strength of TZM alloy having elongated coarse-grain structure.

In order to overcome the recrystallization embrittlement and irradiation embrittlement of Mo, which are major problems for its fusion applications, internally nitrided Mo alloys were prepared by a novel multi-step internal nitriding. Neutron irradiation was performed in the Japan Material Testing Reactor (JMTR). After irradiation, nitrided Mo alloys exhibited ower ductile-brittle transition temperature than irradiated TZM. These results suggested that multi-step internal nitriding was effective to the improvement in the embrittlement by irradiation. Transmission electron microscope observation revealed that TiN particles precipitated by nitriding acted as a sink for irradiation-induced defects.

Internally nitrided dilute W-Ti alloy specimens having a heavily deformed surface microstructure were prepared by a multi-step internal nitriding at 1573-2073 K. Primary nitriding below their recrystallization temperature induced a precipitation of ultrafine TiN particles. After secondary and tertiary nitriding, those precipitates grew into rod-like TiN with a length of 20-60 nm. The recrystallization temperature after nitriding was elevated above 2073 K. The yield strength at 1773 K obtained from nitrided W-0.5 mass% Ti alloy was about 5 times as large as that of the recrystallized specimen. DBTT of the nitrided alloys was about 373 K.

Hopkinson bar dynamic test under strain rates ranging from 2000 to 8000 at room temperature revealed that the flow stress of tungsten heavy alloys depended strongly on the strain, strain rate, and the content of molybdenum. The variation of flow stress was caused by the competition between work hardening and heat softening in the materials at different strain rates. The high temperature strength of the matrix phase was increased by the addition of molybdenum, which enhanced the strength of the tungsten heavy alloys in high strain rate test.

Rapidly solidified ribbon-consolidation processing was applied for preparation of high strength bulk Mg-Zn-Gd alloys. Mg alloys have been used in automotive and aerospace industries. Rapid solidification (RS) process is suitable for the development of high strength Mg alloys, because the process realizes grain-refinement, increase in homogeneity, and so on. Recently, several nanocrystalline Mg-Zn-Y alloys with high specific tensile strength and large elongation have been developed by rapidly solidified powder metallurgy (RS P/M) process. Mg-Zn-Y RS P/M alloys are characterized by long period ordered (LPO) structure and sub-micron fine grains. The both additions of rare earth elements and zinc remarkably improved the mechanical properties of RS Mg alloys. Mg-Zn-Gd alloy also forms LPO structure in -Mg matrix coherently, therefore, it is expected that the RS Mg-Zn-Gd alloys have excellent mechanical properties. In this study, we have developed high strength RS Mg-Zn-Gd alloys with LPO structure and nanometer-scale precipitates by RS ribbon-consolidation processing. and and bulk alloys exhibited high tensile yield strength (470 MPa and 525 MPa and 566 MPa) and large elongation (5.5% and 2.8% and 2.4%).

Fabrication of bulk alloy has been performed through the consolidation of rapidly solidified ribbons. The bulk alloy exhibited excellent mechanical properties, high tensile yield strength of 530 MPa, and large elongation of 3 %. Microstructure of the alloy was characterized by equiaxed fine grains that consist of -Mg, long period ordered (LPO) structure phase, and -type cubic compound. The strengthening of the alloys may be due to fine grains with LPO structure phase and -type compound.

Compositional dependence of corrosion behavior of rapidly solidified Mg-rich Mg-Zn-Y alloys in NaCl aqueous solution has been investigated. Mg-Zn-Y ternary alloys containing small amounts of Zn exhibited low corrosion rate, although the (at. %) binary alloy showed severe corrosion with violet evolution of hydrogen. The alloy with highest corrosion-resistance was , its corrosion rate was about 1 mm year-1 in 0.17 M (1.0 wt. %) NaCl solution. alloy exhibited passive region in anodic polarization curves when immersed in NaCl solution. Rapidly solidification and small amount of Zn addition may bring about an increase in electrochemical homogeneity of Mg-Zn-Y alloys, resulting in enhancement of corrosion resistance.